{"created":"2021-03-01T06:30:42.223221+00:00","id":22898,"links":{},"metadata":{"_buckets":{"deposit":"e65d0d0a-ad61-40f4-b71f-041609b4f3e2"},"_deposit":{"id":"22898","owners":[],"pid":{"revision_id":0,"type":"depid","value":"22898"},"status":"published"},"_oai":{"id":"oai:nagoya.repo.nii.ac.jp:00022898"},"item_10_biblio_info_6":{"attribute_name":"\u66f8\u8a8c\u60c5\u5831","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2016-05-03","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"11","bibliographicPageEnd":"1594","bibliographicPageStart":"1885","bibliographicVolumeNumber":"35","bibliographic_titles":[{"bibliographic_title":"Organometallics"}]}]},"item_10_description_4":{"attribute_name":"\u6284\u9332","attribute_value_mlt":[{"subitem_description":"We describe the preparation and catalytic reactions of new CCN pincer Rh and Ru complexes containing NCH-oxazoline hybrid ligands. Oxazolinyl-phenyl-imidazolium derivatives (3) were suitable ligand precursors for the CCN pincer scaffold. C\u2013H bond activation of 3 with RhCl3\u00b73H2O in the presence of NEt3 yielded the desired CCN pincer Rh complexes 5 in 13\u201327% yields. The related CCN pincer Ru complexes 8\u201310 were synthesized in good yields by C\u2013H bond activation of p-cymene Ru complexes 7 in the presence of NaOAc in DMF. The chiral complexes 8 and 9 had two diastereomers according to the coordination of CO and OAc ligands. The CCN Rh complexes showed catalytic activity for conjugate reduction of ethyl \u03b2-methylcinnamate with hydrosilane, with moderate enantioselectivity. The CCN Ru complexes were found to be active in the hydrogenation of aromatic ketones. In particular, hydrogenation of 9-acetylanthracene took place at not only the C\u2550O bond but also the anthracene ring. The Ru complexes were also used as catalysts in the transfer hydrogenation of 9-acetylanthracene with 2-propanol; again, both the C\u2550O bond and the anthracene ring were hydrogenated.","subitem_description_type":"Abstract"}]},"item_10_identifier_60":{"attribute_name":"URI","attribute_value_mlt":[{"subitem_identifier_type":"DOI","subitem_identifier_uri":"http://doi.org/10.1021/acs.organomet.6b00239"},{"subitem_identifier_type":"HDL","subitem_identifier_uri":"http://hdl.handle.net/2237/25077"}]},"item_10_publisher_32":{"attribute_name":"\u51fa\u7248\u8005","attribute_value_mlt":[{"subitem_publisher":"ACS Publications"}]},"item_10_rights_12":{"attribute_name":"\u6a29\u5229","attribute_value_mlt":[{"subitem_rights":"\u201cThis document is the Accepted Manuscript version of a Published Work that appeared in final form in [Organic Letters], copyright \u00a9 American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see [http://pubs.acs.org/doi/abs/10.1021/acs.organomet.6b00239].\u201d"}]},"item_10_select_15":{"attribute_name":"\u8457\u8005\u7248\u30d5\u30e9\u30b0","attribute_value_mlt":[{"subitem_select_item":"author"}]},"item_10_source_id_7":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"0276-7333","subitem_source_identifier_type":"ISSN"}]},"item_creator":{"attribute_name":"\u8457\u8005","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Ito, Jun-ichi"}],"nameIdentifiers":[{"nameIdentifier":"67377","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Sugino, Kanae"}],"nameIdentifiers":[{"nameIdentifier":"67378","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Matsushima, Satoru"}],"nameIdentifiers":[{"nameIdentifier":"67379","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Sakaguchi, Hiroki"}],"nameIdentifiers":[{"nameIdentifier":"67380","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Iwata, Hiroshi"}],"nameIdentifiers":[{"nameIdentifier":"67381","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Ishihara, Takahiro"}],"nameIdentifiers":[{"nameIdentifier":"67382","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Nishiyama, Hisao"}],"nameIdentifiers":[{"nameIdentifier":"67383","nameIdentifierScheme":"WEKO"}]}]},"item_files":{"attribute_name":"\u30d5\u30a1\u30a4\u30eb\u60c5\u5831","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2017-05-03"}],"displaytype":"detail","filename":"OA.pdf","filesize":[{"value":"1.1 MB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"OA.pdf \u30d5\u30a1\u30a4\u30eb\u516c\u958b:2017-05-03","url":"https://nagoya.repo.nii.ac.jp/record/22898/files/OA.pdf"},"version_id":"96528cd2-4500-4ded-bc15-852823b677c2"}]},"item_language":{"attribute_name":"\u8a00\u8a9e","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"\u8cc7\u6e90\u30bf\u30a4\u30d7","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Synthesis of NHC-Oxazoline Pincer Complexes of Rh and Ru and Their Catalytic Activity for Hydrogenation and Conjugate Reduction","item_titles":{"attribute_name":"\u30bf\u30a4\u30c8\u30eb","attribute_value_mlt":[{"subitem_title":"Synthesis of NHC-Oxazoline Pincer Complexes of Rh and Ru and Their Catalytic Activity for Hydrogenation and Conjugate Reduction"}]},"item_type_id":"10","owner":"1","path":["320/321/322"],"pubdate":{"attribute_name":"\u516c\u958b\u65e5","attribute_value":"2016-11-22"},"publish_date":"2016-11-22","publish_status":"0","recid":"22898","relation_version_is_last":true,"title":["Synthesis of NHC-Oxazoline Pincer Complexes of Rh and Ru and Their Catalytic Activity for Hydrogenation and Conjugate Reduction"],"weko_creator_id":"1","weko_shared_id":null},"updated":"2021-03-01T14:47:29.789221+00:00"}