@article{oai:nagoya.repo.nii.ac.jp:00022899, author = {Naganawa, Yuki and Kawagishi, Mayu and Ito, Jun-ichi and Nishiyama, Hisao}, issue = {24}, journal = {ANGEWANDTE CHEMIE-INTERNATIONAL EDITION}, month = {Jun}, note = {The enantioselective desymmetrizing conjugate hydrosilylation of prochiral differently γ,γ-disubstituted cyclohexadienone derivatives 2 to furnish the corresponding cyclohexenones 4 with a remote chiral all-carbon quaternary center at the γ position is described. Chiral rhodium–bis(oxazolinyl)phenyl complexes 1 were effective catalysts for this transformation. This catalytic system was extended to the asymmetric transformation of spirocarbocyclic cyclohexadienones 5 to give the corresponding products 6 with high enantiomeric ratios.}, pages = {6873--6876}, title = {Asymmetric Induction at Remote Quaternary Centers of Cyclohexadienones by Rhodium-Catalyzed Conjugate Hydrosilylation}, volume = {55}, year = {2016} }