{"created":"2021-03-01T06:30:42.287770+00:00","id":22899,"links":{},"metadata":{"_buckets":{"deposit":"561c4c51-5da4-46c8-b1b0-beec8a4d4e4c"},"_deposit":{"id":"22899","owners":[],"pid":{"revision_id":0,"type":"depid","value":"22899"},"status":"published"},"_oai":{"id":"oai:nagoya.repo.nii.ac.jp:00022899","sets":["320:321:322"]},"author_link":["67384","67385","67386","67387"],"item_10_biblio_info_6":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2016-06-06","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"24","bibliographicPageEnd":"6876","bibliographicPageStart":"6873","bibliographicVolumeNumber":"55","bibliographic_titles":[{"bibliographic_title":"ANGEWANDTE CHEMIE-INTERNATIONAL EDITION","bibliographic_titleLang":"en"}]}]},"item_10_description_4":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"The enantioselective desymmetrizing conjugate hydrosilylation of prochiral differently γ,γ-disubstituted cyclohexadienone derivatives 2 to furnish the corresponding cyclohexenones 4 with a remote chiral all-carbon quaternary center at the γ position is described. Chiral rhodium–bis(oxazolinyl)phenyl complexes 1 were effective catalysts for this transformation. This catalytic system was extended to the asymmetric transformation of spirocarbocyclic cyclohexadienones 5 to give the corresponding products 6 with high enantiomeric ratios.","subitem_description_language":"en","subitem_description_type":"Abstract"}]},"item_10_identifier_60":{"attribute_name":"URI","attribute_value_mlt":[{"subitem_identifier_type":"DOI","subitem_identifier_uri":"http://doi.org/10.1002/anie.201601636"},{"subitem_identifier_type":"HDL","subitem_identifier_uri":"http://hdl.handle.net/2237/25079"}]},"item_10_publisher_32":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"Wiley","subitem_publisher_language":"en"}]},"item_10_relation_11":{"attribute_name":"DOI","attribute_value_mlt":[{"subitem_relation_type":"isVersionOf","subitem_relation_type_id":{"subitem_relation_type_id_text":"https://doi.org/10.1002/anie.201601636","subitem_relation_type_select":"DOI"}}]},"item_10_rights_12":{"attribute_name":"権利","attribute_value_mlt":[{"subitem_rights":"This is the peer reviewed version of the following article: [ANGEWANDTE CHEMIE-INTERNATIONAL EDITION. v.55, n.24, 2016, p.6873–6876], which has been published in final form at [http://doi.org/10.1002/anie.201601636]. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Self-Archiving.","subitem_rights_language":"en"}]},"item_10_select_15":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_select_item":"author"}]},"item_10_source_id_7":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"1433-7851","subitem_source_identifier_type":"PISSN"}]},"item_1615787544753":{"attribute_name":"出版タイプ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_ab4af688f83e57aa","subitem_version_type":"AM"}]},"item_access_right":{"attribute_name":"アクセス権","attribute_value_mlt":[{"subitem_access_right":"open access","subitem_access_right_uri":"http://purl.org/coar/access_right/c_abf2"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Naganawa, Yuki","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"67384","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Kawagishi, Mayu","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"67385","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Ito, Jun-ichi","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"67386","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Nishiyama, Hisao","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"67387","nameIdentifierScheme":"WEKO"}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2017-06-06"}],"displaytype":"detail","filename":"6322ACIE.PDF","filesize":[{"value":"1.1 MB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"6322ACIE.PDF ファイル公開:2017-06-06","objectType":"fulltext","url":"https://nagoya.repo.nii.ac.jp/record/22899/files/6322ACIE.PDF"},"version_id":"68d45dae-f359-4c1a-b8cc-d88c374ea239"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Asymmetric Induction at Remote Quaternary Centers of Cyclohexadienones by Rhodium-Catalyzed Conjugate Hydrosilylation","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Asymmetric Induction at Remote Quaternary Centers of Cyclohexadienones by Rhodium-Catalyzed Conjugate Hydrosilylation","subitem_title_language":"en"}]},"item_type_id":"10","owner":"1","path":["322"],"pubdate":{"attribute_name":"PubDate","attribute_value":"2016-11-22"},"publish_date":"2016-11-22","publish_status":"0","recid":"22899","relation_version_is_last":true,"title":["Asymmetric Induction at Remote Quaternary Centers of Cyclohexadienones by Rhodium-Catalyzed Conjugate Hydrosilylation"],"weko_creator_id":"1","weko_shared_id":-1},"updated":"2023-01-16T04:12:35.145710+00:00"}