@article{oai:nagoya.repo.nii.ac.jp:00022905,
 author = {Omori, Hiroto and Hiroto, Satoru and Shinokubo, Hiroshi},
 issue = {12},
 journal = {Organic Letters},
 month = {Jun},
 note = {A novel synthetic protocol has been developed for free-base 10-azacorroles. Ni(0)-mediated homocoupling of nitrogen-bridged bisdipyrrin Zn(II) complexes afforded a series of free-base 5,15-diaryl-10-azacorroles in good yields. Pd(II) and Cu(II) complexes have been prepared through metalation of free-base 10-azacorroles. Optical and electrochemical properties of 10-azacorrole metal complexes can be tuned by meso-aryl substituents and central metals. Cyclic voltammetry and theoretical calculations elucidated that the central metals of 10-azacorroles significantly affected their electronic properties.},
 pages = {2978--2981},
 title = {Synthesis of Free-Base 10-Azacorroles},
 volume = {18},
 year = {2016}
}