{"created":"2021-03-01T06:30:47.888418+00:00","id":22984,"links":{},"metadata":{"_buckets":{"deposit":"80941c14-6402-490c-9ac2-a7ac9e460cbf"},"_deposit":{"id":"22984","owners":[],"pid":{"revision_id":0,"type":"depid","value":"22984"},"status":"published"},"_oai":{"id":"oai:nagoya.repo.nii.ac.jp:00022984","sets":["320:321:322"]},"author_link":["67882","67883","67884"],"item_10_biblio_info_6":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2016-04","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"8","bibliographicPageEnd":"684","bibliographicPageStart":"678","bibliographicVolumeNumber":"37","bibliographic_titles":[{"bibliographic_title":"MACROMOLECULAR RAPID COMMUNICATIONS","bibliographic_titleLang":"en"}]}]},"item_10_description_4":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"Highly extensible supramolecular elastomers are prepared from ABA triblock-type copolymers bearing glassy end blocks and a long soft middle block with multiple hydrogen bonds. The copolymer used is polystyrene-b-[poly(butyl acrylate)-co-polyacrylamide]-b-polystyrene (S-Ba-S), which is synthesized via reversible addition–fragmentation chain transfer (RAFT) polymerization. Tensile tests reveal that the breaking elongation (εb) increases with an increase in the middle block molecular weight (Mmiddle). Especially, the largest S-Ba-S with Mmiddle of 3140k, which is synthesized via high-pressure RAFT polymerization, achieves εb of over 2000% with a maximum tensile stress of 3.6 MPa, while the control sample without any middle block hydrogen bonds, polystyrene-b-poly(butyl acrylate)-b-polystyrene with Mmiddle of 2780k, is merely a viscous material due to the large volume fraction of soft block. Thus, incorporation of hydrogen bonds into the large molecular weight soft middle block is found to be beneficial to prepare supramolecular elastomers attaining high extensibility and sufficiently large stress generation ability simultaneously. This outcome is probably due to concerted combination of entropic changes and internal potential energy changes originating from the dissociation of multiple hydrogen bonds by elongation.","subitem_description_language":"en","subitem_description_type":"Abstract"}]},"item_10_identifier_60":{"attribute_name":"URI","attribute_value_mlt":[{"subitem_identifier_type":"DOI","subitem_identifier_uri":"http://doi.org/10.1002/marc.201500663"},{"subitem_identifier_type":"HDL","subitem_identifier_uri":"http://hdl.handle.net/2237/25168"}]},"item_10_publisher_32":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"Wiley","subitem_publisher_language":"en"}]},"item_10_relation_11":{"attribute_name":"DOI","attribute_value_mlt":[{"subitem_relation_type":"isVersionOf","subitem_relation_type_id":{"subitem_relation_type_id_text":"https://doi.org/10.1002/marc.201500663","subitem_relation_type_select":"DOI"}}]},"item_10_rights_12":{"attribute_name":"権利","attribute_value_mlt":[{"subitem_rights":"This is the peer reviewed version of the following article: [Hayashi, M., Noro, A. and Matsushita, Y. (2016), Highly Extensible Supramolecular Elastomers with Large Stress Generation Capability Originating from Multiple Hydrogen Bonds on the Long Soft Network Strands. Macromol. Rapid Commun., 37: 678–684], which has been published in final form at [http://doi.org/10.1002/marc.201500663]. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Self-Archiving.","subitem_rights_language":"en"}]},"item_10_select_15":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_select_item":"author"}]},"item_10_source_id_7":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"1022-1336","subitem_source_identifier_type":"PISSN"}]},"item_1615787544753":{"attribute_name":"出版タイプ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_ab4af688f83e57aa","subitem_version_type":"AM"}]},"item_access_right":{"attribute_name":"アクセス権","attribute_value_mlt":[{"subitem_access_right":"open access","subitem_access_right_uri":"http://purl.org/coar/access_right/c_abf2"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Hayashi, Mikihiro","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"67882","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Noro, Atsushi","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"67883","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Matsushita, Yushu","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"67884","nameIdentifierScheme":"WEKO"}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2017-04-20"}],"displaytype":"detail","filename":"manuscript.pdf","filesize":[{"value":"877.3 kB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"manuscript.pdf ファイル公開：2017/04/20","objectType":"fulltext","url":"https://nagoya.repo.nii.ac.jp/record/22984/files/manuscript.pdf"},"version_id":"ce2afc9c-e2f3-4731-baa2-8187fe26f7a5"}]},"item_keyword":{"attribute_name":"キーワード","attribute_value_mlt":[{"subitem_subject":"ABA triblock copolymers","subitem_subject_scheme":"Other"},{"subitem_subject":"high extensibility","subitem_subject_scheme":"Other"},{"subitem_subject":"high-pressure RAFT polymerization","subitem_subject_scheme":"Other"},{"subitem_subject":"large stress generation capability","subitem_subject_scheme":"Other"},{"subitem_subject":"supramolecular elastomers","subitem_subject_scheme":"Other"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Highly Extensible Supramolecular Elastomers with Large Stress Generation Capability Originating from Multiple Hydrogen Bonds on the Long Soft Network Strands","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Highly Extensible Supramolecular Elastomers with Large Stress Generation Capability Originating from Multiple Hydrogen Bonds on the Long Soft Network Strands","subitem_title_language":"en"}]},"item_type_id":"10","owner":"1","path":["322"],"pubdate":{"attribute_name":"PubDate","attribute_value":"2016-12-08"},"publish_date":"2016-12-08","publish_status":"0","recid":"22984","relation_version_is_last":true,"title":["Highly Extensible Supramolecular Elastomers with Large Stress Generation Capability Originating from Multiple Hydrogen Bonds on the Long Soft Network Strands"],"weko_creator_id":"1","weko_shared_id":-1},"updated":"2023-01-16T04:12:37.455309+00:00"}