@article{oai:nagoya.repo.nii.ac.jp:00022986,
 author = {Oishi, Masataka and Ichinose, Yuri and Nomura, Nobuyoshi},
 issue = {10},
 journal = {EUROPEAN JOURNAL OF INORGANIC CHEMISTRY},
 month = {Apr},
 note = {Tris(2-hydroxyaryl)methane ligands coordinate to main group and transition metals in a variety of modes. However, for aluminium, only trinuclear complexes have previously been reported. To investigate the possibility of also developing both mono- and dinuclear aluminium complexes, the reactions of Et3Al and tris(2-hydroxyaryl)methanes have been examined under various conditions. In this work, trialuminium complex 1b was formed by disproportionation of the initially generated monomeric complex 2′ (Al/ligand = 1:1) with Et3Al. This reaction allowed us to selectively synthesize aluminium complexes 1b, 2, 5, and 7 with different coordination modes. Furthermore, mononuclear complex 5b underwent rearrangement to yield the tris(aryloxy) complex 8 in C6D6 under the appropriate conditions.},
 pages = {1596--1603},
 title = {Structural Diversity of Tris(2-hydroxy­aryl)methane-Derived Aluminium Complexes},
 volume = {2016},
 year = {2016}
}