{"created":"2021-03-01T06:30:48.028706+00:00","id":22986,"links":{},"metadata":{"_buckets":{"deposit":"ef9f4f7e-8924-4935-b8b7-7142c99416eb"},"_deposit":{"id":"22986","owners":[],"pid":{"revision_id":0,"type":"depid","value":"22986"},"status":"published"},"_oai":{"id":"oai:nagoya.repo.nii.ac.jp:00022986","sets":["643:666:667"]},"author_link":["67890","67891","67892"],"item_10_biblio_info_6":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2016-04","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"10","bibliographicPageEnd":"1603","bibliographicPageStart":"1596","bibliographicVolumeNumber":"2016","bibliographic_titles":[{"bibliographic_title":"EUROPEAN JOURNAL OF INORGANIC CHEMISTRY","bibliographic_titleLang":"en"}]}]},"item_10_description_4":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"Tris(2-hydroxyaryl)methane ligands coordinate to main group and transition metals in a variety of modes. However, for aluminium, only trinuclear complexes have previously been reported. To investigate the possibility of also developing both mono- and dinuclear aluminium complexes, the reactions of Et3Al and tris(2-hydroxyaryl)methanes have been examined under various conditions. In this work, trialuminium complex 1b was formed by disproportionation of the initially generated monomeric complex 2′ (Al/ligand = 1:1) with Et3Al. This reaction allowed us to selectively synthesize aluminium complexes 1b, 2, 5, and 7 with different coordination modes. Furthermore, mononuclear complex 5b underwent rearrangement to yield the tris(aryloxy) complex 8 in C6D6 under the appropriate conditions.","subitem_description_language":"en","subitem_description_type":"Abstract"}]},"item_10_identifier_60":{"attribute_name":"URI","attribute_value_mlt":[{"subitem_identifier_type":"DOI","subitem_identifier_uri":"http://doi.org/10.1002/ejic.201501438"},{"subitem_identifier_type":"HDL","subitem_identifier_uri":"http://hdl.handle.net/2237/25170"}]},"item_10_publisher_32":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"Wiley","subitem_publisher_language":"en"}]},"item_10_relation_11":{"attribute_name":"DOI","attribute_value_mlt":[{"subitem_relation_type":"isVersionOf","subitem_relation_type_id":{"subitem_relation_type_id_text":"https://doi.org/10.1002/ejic.201501438","subitem_relation_type_select":"DOI"}}]},"item_10_rights_12":{"attribute_name":"権利","attribute_value_mlt":[{"subitem_rights":"This is the peer reviewed version of the following article: [Oishi, M., Ichinose, Y. and Nomura, N. (2016), Structural Diversity of Tris(2-hydroxy­aryl)methane-Derived Aluminium Complexes. Eur. J. Inorg. Chem., 2016: 1596–1603], which has been published in final form at [http://doi.org/10.1002/ejic.201501438]. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Self-Archiving.","subitem_rights_language":"en"}]},"item_10_select_15":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_select_item":"author"}]},"item_10_source_id_7":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"1434-1948","subitem_source_identifier_type":"PISSN"}]},"item_1615787544753":{"attribute_name":"出版タイプ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_ab4af688f83e57aa","subitem_version_type":"AM"}]},"item_access_right":{"attribute_name":"アクセス権","attribute_value_mlt":[{"subitem_access_right":"open access","subitem_access_right_uri":"http://purl.org/coar/access_right/c_abf2"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Oishi, Masataka","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"67890","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Ichinose, Yuri","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"67891","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Nomura, Nobuyoshi","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"67892","nameIdentifierScheme":"WEKO"}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2017-04-04"}],"displaytype":"detail","filename":"nomura.pdf","filesize":[{"value":"1.7 MB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"nomura.pdf ファイル公開:2017/04/04","objectType":"fulltext","url":"https://nagoya.repo.nii.ac.jp/record/22986/files/nomura.pdf"},"version_id":"88adbf9d-f46f-4572-8ba3-921c5c7f7b54"}]},"item_keyword":{"attribute_name":"キーワード","attribute_value_mlt":[{"subitem_subject":"Aluminum","subitem_subject_scheme":"Other"},{"subitem_subject":"Lewis acids","subitem_subject_scheme":"Other"},{"subitem_subject":"Brønsted acids","subitem_subject_scheme":"Other"},{"subitem_subject":"Ion pairs","subitem_subject_scheme":"Other"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Structural Diversity of Tris(2-hydroxy­aryl)methane-Derived Aluminium Complexes","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Structural Diversity of Tris(2-hydroxy­aryl)methane-Derived Aluminium Complexes","subitem_title_language":"en"}]},"item_type_id":"10","owner":"1","path":["667"],"pubdate":{"attribute_name":"PubDate","attribute_value":"2016-12-08"},"publish_date":"2016-12-08","publish_status":"0","recid":"22986","relation_version_is_last":true,"title":["Structural Diversity of Tris(2-hydroxy­aryl)methane-Derived Aluminium Complexes"],"weko_creator_id":"1","weko_shared_id":-1},"updated":"2023-01-16T04:12:38.103359+00:00"}