{"created":"2021-03-01T06:30:52.200354+00:00","id":23049,"links":{},"metadata":{"_buckets":{"deposit":"cddc9e21-d2fd-4e84-ad4b-42e9ce502cbe"},"_deposit":{"id":"23049","owners":[],"pid":{"revision_id":0,"type":"depid","value":"23049"},"status":"published"},"_oai":{"id":"oai:nagoya.repo.nii.ac.jp:00023049","sets":["1939:1940:1941"]},"author_link":["68182","68183","68184"],"item_10_biblio_info_6":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2016-12","bibliographicIssueDateType":"Issued"},"bibliographicPageEnd":"412","bibliographicPageStart":"404","bibliographicVolumeNumber":"688B","bibliographic_titles":[{"bibliographic_title":"Journal of Alloys and Compounds","bibliographic_titleLang":"en"}]}]},"item_10_description_4":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"The dynamics of hydrogen-induced vacancies are the key for understanding various phenomena in metal–hydrogen systems under a high hydrogen chemical potential. In this study, a novel dry-electrolysis experiment was performed in which a hydrogen isotope was injected into a Pd cathode and time-resolved in situ monochromatic X-ray diffraction measurement was carried out at the Pd cathode. It was found that palladium-hydride containing vacancies forms multiple phases depending on the hydrogen chemical potential. Phase separation into vacancy-rich, vacancy-poor, and moderate-vacancy-concentration phases was observed when the input voltage was relatively low, i.e., ∼0.5 V. The moderate-vacancy-concentration phase may be attributed to Ca7Ge or another type of super-lattice Pd7VacH(D)8. Transition from the vacancy-rich to the moderate-vacancy-concentration phase explains the sub-micron void formations without high temperature treatment that were observed at the Pd cathode but have never been reported in previous anvil experiments.","subitem_description_language":"en","subitem_description_type":"Abstract"}]},"item_10_identifier_60":{"attribute_name":"URI","attribute_value_mlt":[{"subitem_identifier_type":"DOI","subitem_identifier_uri":"http://dx.doi.org/10.1016/j.jallcom.2016.07.176"},{"subitem_identifier_type":"HDL","subitem_identifier_uri":"http://hdl.handle.net/2237/25240"}]},"item_10_publisher_32":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"Elsevier","subitem_publisher_language":"en"}]},"item_10_relation_11":{"attribute_name":"DOI","attribute_value_mlt":[{"subitem_relation_type":"isVersionOf","subitem_relation_type_id":{"subitem_relation_type_id_text":"https://doi.org/10.1016/j.jallcom.2016.07.176","subitem_relation_type_select":"DOI"}}]},"item_10_rights_12":{"attribute_name":"権利","attribute_value_mlt":[{"subitem_rights":"© 2016. This manuscript version is made available under the CC-BY-NC-ND 4.0 license http://creativecommons.org/licenses/by-nc-nd/4.0/","subitem_rights_language":"en"}]},"item_10_select_15":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_select_item":"author"}]},"item_10_source_id_7":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"0925-8388","subitem_source_identifier_type":"PISSN"}]},"item_1615787544753":{"attribute_name":"出版タイプ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_ab4af688f83e57aa","subitem_version_type":"AM"}]},"item_access_right":{"attribute_name":"アクセス権","attribute_value_mlt":[{"subitem_access_right":"open access","subitem_access_right_uri":"http://purl.org/coar/access_right/c_abf2"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Fukada, Yoshiki","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"68182","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Hioki, Tatsumi","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"68183","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Motohiro, Tomoyoshi","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"68184","nameIdentifierScheme":"WEKO"}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2018-12-01"}],"displaytype":"detail","filename":"sav2_paper_riv_submit.pdf","filesize":[{"value":"2.7 MB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"sav2_paper_riv_submit.pdf ファイル公開：2018/12/01","objectType":"fulltext","url":"https://nagoya.repo.nii.ac.jp/record/23049/files/sav2_paper_riv_submit.pdf"},"version_id":"f48956d9-e234-4c8f-bb44-ae4689c833b4"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Multiple phase separation of super-abundant-vacancies in Pd hydrides by all solid-state electrolysis in moderate temperatures around 300 °C","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Multiple phase separation of super-abundant-vacancies in Pd hydrides by all solid-state electrolysis in moderate temperatures around 300 °C","subitem_title_language":"en"}]},"item_type_id":"10","owner":"1","path":["1941"],"pubdate":{"attribute_name":"PubDate","attribute_value":"2016-12-16"},"publish_date":"2016-12-16","publish_status":"0","recid":"23049","relation_version_is_last":true,"title":["Multiple phase separation of super-abundant-vacancies in Pd hydrides by all solid-state electrolysis in moderate temperatures around 300 °C"],"weko_creator_id":"1","weko_shared_id":-1},"updated":"2023-01-16T04:29:10.951738+00:00"}