{"created":"2021-03-01T06:31:02.557905+00:00","id":23206,"links":{},"metadata":{"_buckets":{"deposit":"8396c2b3-8111-4076-a67b-5eb811833481"},"_deposit":{"id":"23206","owners":[],"pid":{"revision_id":0,"type":"depid","value":"23206"},"status":"published"},"_oai":{"id":"oai:nagoya.repo.nii.ac.jp:00023206","sets":["320:321:322"]},"author_link":["68754","68755","68756","68757","68758"],"item_10_biblio_info_6":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2016-04","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"7","bibliographicPageEnd":"1067","bibliographicPageStart":"1061","bibliographicVolumeNumber":"27","bibliographic_titles":[{"bibliographic_title":"Synlett","bibliographic_titleLang":"en"}]}]},"item_10_description_4":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"Chiral supramolecular boron Lewis acid catalysts were prepared from chiral 3-phosphoryl-1,1′-bi-2-naphthols, (2-cyanophenyl)boronic acids, and tris(pentafluorophenyl)borane, bound through CN···B and PO···B coordination bonds. In particular, the coordinated tris(pentafluorophenyl)boranes increase the Lewis acidity of the active center in the manner of a Lewis acid assisted Lewis acid catalyst system. A possible cavity in these catalysts was highly suitable for several Diels–Alder probe reactions of acroleins with cyclic or acyclic dienes, which gave the corresponding adducts in good to high yields and high enantio­selectivities.","subitem_description_language":"en","subitem_description_type":"Abstract"}]},"item_10_identifier_60":{"attribute_name":"URI","attribute_value_mlt":[{"subitem_identifier_type":"DOI","subitem_identifier_uri":"http://doi.org/10.1055/s-0035-1561362"},{"subitem_identifier_type":"HDL","subitem_identifier_uri":"http://hdl.handle.net/2237/25400"}]},"item_10_publisher_32":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"Georg Thieme Verlag","subitem_publisher_language":"en"}]},"item_10_relation_11":{"attribute_name":"DOI","attribute_value_mlt":[{"subitem_relation_type":"isVersionOf","subitem_relation_type_id":{"subitem_relation_type_id_text":"https://doi.org/10.1055/s-0035-1561362","subitem_relation_type_select":"DOI"}}]},"item_10_select_15":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_select_item":"author"}]},"item_10_source_id_7":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"0936-5214","subitem_source_identifier_type":"PISSN"}]},"item_1615787544753":{"attribute_name":"出版タイプ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_ab4af688f83e57aa","subitem_version_type":"AM"}]},"item_access_right":{"attribute_name":"アクセス権","attribute_value_mlt":[{"subitem_access_right":"open access","subitem_access_right_uri":"http://purl.org/coar/access_right/c_abf2"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Hatano, Manabu","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"68754","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Hayashi, Kazushi","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"68755","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Sakamoto, Tatsuhiro","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"68756","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Makino, Yuma","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"68757","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Ishihara, Kazuaki","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"68758","nameIdentifierScheme":"WEKO"}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2017-04-01"}],"displaytype":"detail","filename":"Manuscript-revised.pdf","filesize":[{"value":"958.3 kB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"Manuscript-revised.pdf ファイル公開：2017/04/01","objectType":"fulltext","url":"https://nagoya.repo.nii.ac.jp/record/23206/files/Manuscript-revised.pdf"},"version_id":"011ed93b-c5fb-439e-a578-c4531cbbbfc8"}]},"item_keyword":{"attribute_name":"キーワード","attribute_value_mlt":[{"subitem_subject":"supramolecular catalysts","subitem_subject_scheme":"Other"},{"subitem_subject":"asymmetric catalysis","subitem_subject_scheme":"Other"},{"subitem_subject":"Diels–Alder reactions","subitem_subject_scheme":"Other"},{"subitem_subject":"Lewis acids","subitem_subject_scheme":"Other"},{"subitem_subject":"dienes","subitem_subject_scheme":"Other"},{"subitem_subject":"aldehydes","subitem_subject_scheme":"Other"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Enantioselective Diels–Alder Reaction Induced by Chiral Supramolecular Lewis Acid Catalysts Based on CN···B and PO···B Coordination Bonds","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Enantioselective Diels–Alder Reaction Induced by Chiral Supramolecular Lewis Acid Catalysts Based on CN···B and PO···B Coordination Bonds","subitem_title_language":"en"}]},"item_type_id":"10","owner":"1","path":["322"],"pubdate":{"attribute_name":"PubDate","attribute_value":"2017-01-17"},"publish_date":"2017-01-17","publish_status":"0","recid":"23206","relation_version_is_last":true,"title":["Enantioselective Diels–Alder Reaction Induced by Chiral Supramolecular Lewis Acid Catalysts Based on CN···B and PO···B Coordination Bonds"],"weko_creator_id":"1","weko_shared_id":-1},"updated":"2023-01-16T04:59:45.656429+00:00"}