{"_buckets": {"deposit": "378025cb-9146-4338-a3ce-924040ce6da4"}, "_deposit": {"id": "23379", "owners": [], "pid": {"revision_id": 0, "type": "depid", "value": "23379"}, "status": "published"}, "_oai": {"id": "oai:nagoya.repo.nii.ac.jp:00023379"}, "item_10_biblio_info_6": {"attribute_name": "\u66f8\u8a8c\u60c5\u5831", "attribute_value_mlt": [{"bibliographicIssueDates": {"bibliographicIssueDate": "2016-11-14", "bibliographicIssueDateType": "Issued"}, "bibliographicIssueNumber": "47", "bibliographicPageEnd": "16804", "bibliographicPageStart": "16801", "bibliographicVolumeNumber": "22", "bibliographic_titles": [{"bibliographic_title": "CHEMISTRY-A EUROPEAN JOURNAL"}]}]}, "item_10_description_4": {"attribute_name": "\u6284\u9332", "attribute_value_mlt": [{"subitem_description": "A direct asymmetric alkynylation of ketones with new chiral CCN Rh catalysts containing N-heterocyclic carbene and oxazoline hybrid ligands is described. The catalytic reaction of fluoroalkyl-substituted ketones, ArCOCF2X (X=F, Cl, H), with aromatic and aliphatic alkynes yielded the corresponding chiral propargyl alcohols with high enantioselectivity. Control and kinetic experiments suggested a bis(alkynyl) Rh intermediate as the active species for the C\u2212C bond-forming step.", "subitem_description_type": "Abstract"}]}, "item_10_identifier_60": {"attribute_name": "URI", "attribute_value_mlt": [{"subitem_identifier_type": "DOI", "subitem_identifier_uri": "http://doi.org/10.1002/chem.201603754"}, {"subitem_identifier_type": "HDL", "subitem_identifier_uri": "http://hdl.handle.net/2237/25574"}]}, "item_10_publisher_32": {"attribute_name": "\u51fa\u7248\u8005", "attribute_value_mlt": [{"subitem_publisher": "Wiley"}]}, "item_10_rights_12": {"attribute_name": "\u6a29\u5229", "attribute_value_mlt": [{"subitem_rights": "\"This is the peer reviewed version of the following article: [J.-i. Ito, S. Ubukata, S. Muraoka, H. Nishiyama, Chem. Eur. J. 2016, 22, 16801.], which has been published in final form at [http://doi.org/10.1002/chem.201603754]. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Self-Archiving.\""}]}, "item_10_select_15": {"attribute_name": "\u8457\u8005\u7248\u30d5\u30e9\u30b0", "attribute_value_mlt": [{"subitem_select_item": "author"}]}, "item_10_source_id_7": {"attribute_name": "ISSN", "attribute_value_mlt": [{"subitem_source_identifier": "0947-6539", "subitem_source_identifier_type": "ISSN"}]}, "item_creator": {"attribute_name": "\u8457\u8005", "attribute_type": "creator", "attribute_value_mlt": [{"creatorNames": [{"creatorName": "Ito, Jun-ichi"}], "nameIdentifiers": [{"nameIdentifier": "69310", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Ubukata, Shino"}], "nameIdentifiers": [{"nameIdentifier": "69311", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Muraoka, Shun"}], "nameIdentifiers": [{"nameIdentifier": "69312", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Nishiyama, Hisao"}], "nameIdentifiers": [{"nameIdentifier": "69313", "nameIdentifierScheme": "WEKO"}]}]}, "item_files": {"attribute_name": "\u30d5\u30a1\u30a4\u30eb\u60c5\u5831", "attribute_type": "file", "attribute_value_mlt": [{"accessrole": "open_date", "date": [{"dateType": "Available", "dateValue": "2017-11-14"}], "displaytype": "detail", "download_preview_message": "", "file_order": 0, "filename": "Manuscript.pdf", "filesize": [{"value": "585.6 kB"}], "format": "application/pdf", "future_date_message": "", "is_thumbnail": false, "licensetype": "license_free", "mimetype": "application/pdf", "size": 585600.0, "url": {"label": "Manuscript.pdf \u30d5\u30a1\u30a4\u30eb\u516c\u958b\uff1a2017/11/14", "url": "https://nagoya.repo.nii.ac.jp/record/23379/files/Manuscript.pdf"}, "version_id": "77b106b2-f408-4509-953d-af39667b8215"}]}, "item_language": {"attribute_name": "\u8a00\u8a9e", "attribute_value_mlt": [{"subitem_language": "eng"}]}, "item_resource_type": {"attribute_name": "\u8cc7\u6e90\u30bf\u30a4\u30d7", "attribute_value_mlt": [{"resourcetype": "journal article", "resourceuri": "http://purl.org/coar/resource_type/c_6501"}]}, "item_title": "Enantioselective Direct Alkynylation of Ketones Catalyzed by Chiral CCN Pincer Rh(III) Complexes", "item_titles": {"attribute_name": "\u30bf\u30a4\u30c8\u30eb", "attribute_value_mlt": [{"subitem_title": "Enantioselective Direct Alkynylation of Ketones Catalyzed by Chiral CCN Pincer Rh(III) Complexes"}]}, "item_type_id": "10", "owner": "1", "path": ["320/321/322"], "permalink_uri": "http://hdl.handle.net/2237/25574", "pubdate": {"attribute_name": "\u516c\u958b\u65e5", "attribute_value": "2017-02-15"}, "publish_date": "2017-02-15", "publish_status": "0", "recid": "23379", "relation": {}, "relation_version_is_last": true, "title": ["Enantioselective Direct Alkynylation of Ketones Catalyzed by Chiral CCN Pincer Rh(III) Complexes"], "weko_shared_id": null}