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  1. B200 工学部/工学研究科
  2. B200a 雑誌掲載論文
  3. 学術雑誌

Enantioselective Direct Alkynylation of Ketones Catalyzed by Chiral CCN Pincer Rh(III) Complexes

http://hdl.handle.net/2237/25574
http://hdl.handle.net/2237/25574
41f96e43-46d6-4ed4-9305-8696b00273f8
名前 / ファイル ライセンス アクション
Manuscript.pdf Manuscript.pdf ファイル公開:2017/11/14 (585.6 kB)
Item type 学術雑誌論文 / Journal Article(1)
公開日 2017-02-15
タイトル
タイトル Enantioselective Direct Alkynylation of Ketones Catalyzed by Chiral CCN Pincer Rh(III) Complexes
言語 en
著者 Ito, Jun-ichi

× Ito, Jun-ichi

WEKO 69310

en Ito, Jun-ichi

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Ubukata, Shino

× Ubukata, Shino

WEKO 69311

en Ubukata, Shino

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Muraoka, Shun

× Muraoka, Shun

WEKO 69312

en Muraoka, Shun

Search repository
Nishiyama, Hisao

× Nishiyama, Hisao

WEKO 69313

en Nishiyama, Hisao

Search repository
アクセス権
アクセス権 open access
アクセス権URI http://purl.org/coar/access_right/c_abf2
権利
言語 en
権利情報 This is the peer reviewed version of the following article: [J.-i. Ito, S. Ubukata, S. Muraoka, H. Nishiyama, Chem. Eur. J. 2016, 22, 16801.], which has been published in final form at [http://doi.org/10.1002/chem.201603754]. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Self-Archiving.
抄録
内容記述 A direct asymmetric alkynylation of ketones with new chiral CCN Rh catalysts containing N-heterocyclic carbene and oxazoline hybrid ligands is described. The catalytic reaction of fluoroalkyl-substituted ketones, ArCOCF2X (X=F, Cl, H), with aromatic and aliphatic alkynes yielded the corresponding chiral propargyl alcohols with high enantioselectivity. Control and kinetic experiments suggested a bis(alkynyl) Rh intermediate as the active species for the C−C bond-forming step.
言語 en
内容記述タイプ Abstract
出版者
言語 en
出版者 Wiley
言語
言語 eng
資源タイプ
資源タイプresource http://purl.org/coar/resource_type/c_6501
タイプ journal article
出版タイプ
出版タイプ AM
出版タイプResource http://purl.org/coar/version/c_ab4af688f83e57aa
DOI
関連タイプ isVersionOf
識別子タイプ DOI
関連識別子 https://doi.org/10.1002/chem.201603754
ISSN
収録物識別子タイプ PISSN
収録物識別子 0947-6539
書誌情報 en : CHEMISTRY-A EUROPEAN JOURNAL

巻 22, 号 47, p. 16801-16804, 発行日 2016-11-14
著者版フラグ
値 author
URI
識別子 http://doi.org/10.1002/chem.201603754
識別子タイプ DOI
URI
識別子 http://hdl.handle.net/2237/25574
識別子タイプ HDL
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