{"created":"2021-03-01T06:31:14.092111+00:00","id":23379,"links":{},"metadata":{"_buckets":{"deposit":"378025cb-9146-4338-a3ce-924040ce6da4"},"_deposit":{"id":"23379","owners":[],"pid":{"revision_id":0,"type":"depid","value":"23379"},"status":"published"},"_oai":{"id":"oai:nagoya.repo.nii.ac.jp:00023379"},"item_10_biblio_info_6":{"attribute_name":"\u66f8\u8a8c\u60c5\u5831","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2016-11-14","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"47","bibliographicPageEnd":"16804","bibliographicPageStart":"16801","bibliographicVolumeNumber":"22","bibliographic_titles":[{"bibliographic_title":"CHEMISTRY-A EUROPEAN JOURNAL"}]}]},"item_10_description_4":{"attribute_name":"\u6284\u9332","attribute_value_mlt":[{"subitem_description":"A direct asymmetric alkynylation of ketones with new chiral CCN Rh catalysts containing N-heterocyclic carbene and oxazoline hybrid ligands is described. The catalytic reaction of fluoroalkyl-substituted ketones, ArCOCF2X (X=F, Cl, H), with aromatic and aliphatic alkynes yielded the corresponding chiral propargyl alcohols with high enantioselectivity. Control and kinetic experiments suggested a bis(alkynyl) Rh intermediate as the active species for the C\u2212C bond-forming step.","subitem_description_type":"Abstract"}]},"item_10_identifier_60":{"attribute_name":"URI","attribute_value_mlt":[{"subitem_identifier_type":"DOI","subitem_identifier_uri":"http://doi.org/10.1002/chem.201603754"},{"subitem_identifier_type":"HDL","subitem_identifier_uri":"http://hdl.handle.net/2237/25574"}]},"item_10_publisher_32":{"attribute_name":"\u51fa\u7248\u8005","attribute_value_mlt":[{"subitem_publisher":"Wiley"}]},"item_10_rights_12":{"attribute_name":"\u6a29\u5229","attribute_value_mlt":[{"subitem_rights":"\"This is the peer reviewed version of the following article: [J.-i. Ito, S. Ubukata, S. Muraoka, H. Nishiyama, Chem. Eur. J. 2016, 22, 16801.], which has been published in final form at [http://doi.org/10.1002/chem.201603754]. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Self-Archiving.\""}]},"item_10_select_15":{"attribute_name":"\u8457\u8005\u7248\u30d5\u30e9\u30b0","attribute_value_mlt":[{"subitem_select_item":"author"}]},"item_10_source_id_7":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"0947-6539","subitem_source_identifier_type":"ISSN"}]},"item_creator":{"attribute_name":"\u8457\u8005","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Ito, Jun-ichi"}],"nameIdentifiers":[{"nameIdentifier":"69310","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Ubukata, Shino"}],"nameIdentifiers":[{"nameIdentifier":"69311","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Muraoka, Shun"}],"nameIdentifiers":[{"nameIdentifier":"69312","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Nishiyama, Hisao"}],"nameIdentifiers":[{"nameIdentifier":"69313","nameIdentifierScheme":"WEKO"}]}]},"item_files":{"attribute_name":"\u30d5\u30a1\u30a4\u30eb\u60c5\u5831","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2017-11-14"}],"displaytype":"detail","filename":"Manuscript.pdf","filesize":[{"value":"585.6 kB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"Manuscript.pdf \u30d5\u30a1\u30a4\u30eb\u516c\u958b\uff1a2017/11/14","url":"https://nagoya.repo.nii.ac.jp/record/23379/files/Manuscript.pdf"},"version_id":"77b106b2-f408-4509-953d-af39667b8215"}]},"item_language":{"attribute_name":"\u8a00\u8a9e","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"\u8cc7\u6e90\u30bf\u30a4\u30d7","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Enantioselective Direct Alkynylation of Ketones Catalyzed by Chiral CCN Pincer Rh(III) Complexes","item_titles":{"attribute_name":"\u30bf\u30a4\u30c8\u30eb","attribute_value_mlt":[{"subitem_title":"Enantioselective Direct Alkynylation of Ketones Catalyzed by Chiral CCN Pincer Rh(III) Complexes"}]},"item_type_id":"10","owner":"1","path":["320/321/322"],"pubdate":{"attribute_name":"\u516c\u958b\u65e5","attribute_value":"2017-02-15"},"publish_date":"2017-02-15","publish_status":"0","recid":"23379","relation_version_is_last":true,"title":["Enantioselective Direct Alkynylation of Ketones Catalyzed by Chiral CCN Pincer Rh(III) Complexes"],"weko_creator_id":"1","weko_shared_id":null},"updated":"2021-03-01T14:36:39.387207+00:00"}