@article{oai:nagoya.repo.nii.ac.jp:00023505,
 author = {Ohki, Yasuhiro and Shimizu, Yuki and Araake, Ryoichi and Tada, Mizuki and Sameera, W.M.C and Ito, Jun-Ichi and Nishiyama, Hisao},
 issue = {51},
 journal = {ANGEWANDTE CHEMIE-INTERNATIONAL EDITION},
 month = {Dec},
 note = {A square-planar Co4 amide cluster, Co4{N(SiMe3)2}4 (2), and an octahedral Co6 hydride cluster, Co6H8(PiPr3)6 (4), were obtained from metathesis-type amide to hydride exchange reactions of a CoII amide complex with pinacolborane (HBpin) in the absence/presence of PiPr3. The crystal structure of 4 revealed face-capping hydrides on each triangular [Co3] face, while the formal CoII2CoI4 oxidation state of 4 indicated a reduction of the cobalt centers during the assembly process. Cluster 4 catalyzes the hydrosilylation of 2-cyclohexen-1-one favoring the conjugate reduction. Generation of the catalytically reactive Co cluster species was indicated by a trapping experiment with a chiral chelating agent.},
 pages = {15821--15825},
 title = {Co6H8(P^iPr3)6: A Cobalt Octahedron with Face-Capping Hydrides},
 volume = {55},
 year = {2016}
}