{"created":"2021-03-01T06:31:22.307798+00:00","id":23505,"links":{},"metadata":{"_buckets":{"deposit":"d6f73e66-1bfb-4b8a-b3cb-6285900f6520"},"_deposit":{"id":"23505","owners":[],"pid":{"revision_id":0,"type":"depid","value":"23505"},"status":"published"},"_oai":{"id":"oai:nagoya.repo.nii.ac.jp:00023505","sets":["336:695:696"]},"author_link":["69733","69734","69735","69736","69737","69738","69739"],"item_10_biblio_info_6":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2016-12-19","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"51","bibliographicPageEnd":"15825","bibliographicPageStart":"15821","bibliographicVolumeNumber":"55","bibliographic_titles":[{"bibliographic_title":"ANGEWANDTE CHEMIE-INTERNATIONAL EDITION","bibliographic_titleLang":"en"}]}]},"item_10_description_4":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"A square-planar Co4 amide cluster, Co4{N(SiMe3)2}4 (2), and an octahedral Co6 hydride cluster, Co6H8(PiPr3)6 (4), were obtained from metathesis-type amide to hydride exchange reactions of a CoII amide complex with pinacolborane (HBpin) in the absence/presence of PiPr3. The crystal structure of 4 revealed face-capping hydrides on each triangular [Co3] face, while the formal CoII2CoI4 oxidation state of 4 indicated a reduction of the cobalt centers during the assembly process. Cluster 4 catalyzes the hydrosilylation of 2-cyclohexen-1-one favoring the conjugate reduction. Generation of the catalytically reactive Co cluster species was indicated by a trapping experiment with a chiral chelating agent.","subitem_description_language":"en","subitem_description_type":"Abstract"}]},"item_10_identifier_60":{"attribute_name":"URI","attribute_value_mlt":[{"subitem_identifier_type":"DOI","subitem_identifier_uri":"http://doi.org/10.1002/anie.201608262"},{"subitem_identifier_type":"HDL","subitem_identifier_uri":"http://hdl.handle.net/2237/25698"}]},"item_10_publisher_32":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"Wiley","subitem_publisher_language":"en"}]},"item_10_relation_11":{"attribute_name":"DOI","attribute_value_mlt":[{"subitem_relation_type":"isVersionOf","subitem_relation_type_id":{"subitem_relation_type_id_text":"https://doi.org/10.1002/anie.201608262","subitem_relation_type_select":"DOI"}}]},"item_10_rights_12":{"attribute_name":"権利","attribute_value_mlt":[{"subitem_rights":"This is the peer reviewed version of the following article: [Y. Ohki, Y. Shimizu, R. Araake, M. Tada, W. M. C. Sameera, J.-I. Ito, H. Nishiyama, Angew. Chem. Int. Ed. 2016, 55, 15821.], which has been published in final form at [http://doi.org/10.1002/anie.201608262]. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Self-Archiving.","subitem_rights_language":"en"}]},"item_10_select_15":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_select_item":"author"}]},"item_10_source_id_7":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"1433-7851","subitem_source_identifier_type":"PISSN"}]},"item_1615787544753":{"attribute_name":"出版タイプ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_ab4af688f83e57aa","subitem_version_type":"AM"}]},"item_access_right":{"attribute_name":"アクセス権","attribute_value_mlt":[{"subitem_access_right":"open access","subitem_access_right_uri":"http://purl.org/coar/access_right/c_abf2"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Ohki, Yasuhiro","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"69733","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Shimizu, Yuki","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"69734","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Araake, Ryoichi","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"69735","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Tada, Mizuki","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"69736","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Sameera, W.M.C","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"69737","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Ito, Jun-Ichi","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"69738","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Nishiyama, Hisao","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"69739","nameIdentifierScheme":"WEKO"}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2017-12-19"}],"displaytype":"detail","filename":"manuscript-rev-final.pdf","filesize":[{"value":"1.2 MB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"manuscript-rev-final.pdf ファイル公開：2017/12/19","objectType":"fulltext","url":"https://nagoya.repo.nii.ac.jp/record/23505/files/manuscript-rev-final.pdf"},"version_id":"4c079224-e8fe-454b-9ba8-3c98e62b6122"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Co6H8(P^iPr3)6: A Cobalt Octahedron with Face-Capping Hydrides","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Co6H8(P^iPr3)6: A Cobalt Octahedron with Face-Capping Hydrides","subitem_title_language":"en"}]},"item_type_id":"10","owner":"1","path":["696"],"pubdate":{"attribute_name":"PubDate","attribute_value":"2017-03-14"},"publish_date":"2017-03-14","publish_status":"0","recid":"23505","relation_version_is_last":true,"title":["Co6H8(P^iPr3)6: A Cobalt Octahedron with Face-Capping Hydrides"],"weko_creator_id":"1","weko_shared_id":-1},"updated":"2023-01-16T04:13:16.053032+00:00"}