{"created":"2021-03-01T06:31:24.655530+00:00","id":23541,"links":{},"metadata":{"_buckets":{"deposit":"11537552-6749-4b5e-a1f8-305e12b4a79d"},"_deposit":{"id":"23541","owners":[],"pid":{"revision_id":0,"type":"depid","value":"23541"},"status":"published"},"_oai":{"id":"oai:nagoya.repo.nii.ac.jp:00023541","sets":["336:695:696"]},"author_link":["69925","69926","69927","69928","69929","69930","69931","69932","69933"],"item_10_biblio_info_6":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2016-12-12","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"50","bibliographicPageEnd":"15636","bibliographicPageStart":"15633","bibliographicVolumeNumber":"55","bibliographic_titles":[{"bibliographic_title":"ANGEWANDTE CHEMIE-INTERNATIONAL EDITION","bibliographic_titleLang":"en"}]}]},"item_10_description_4":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"The Mo nitrogenase catalyzes the ambient reduction of N2 to NH3 at its M-cluster site. A complex metallocofactor with a core composition of [MoFe7S9C], the M-cluster, can be extracted from the protein scaffold and used to facilitate the catalytic reduction of CN−, CO, and CO2 into hydrocarbons in the isolated state. Herein, we report the synthesis, structure, and reactivity of an asymmetric M-cluster analogue with a core composition of [MoFe5S9]. This analogue, referred to as the Mo-cluster, is the first synthetic example of an M-cluster mimic with Fe and Mo positioned at opposite ends of the cluster. Moreover, the ability of the Mo-cluster to reduce C1 substrates to hydrocarbons suggests the feasibility of developing nitrogenase-based biomimetic approaches to recycle C1 waste into fuel products.","subitem_description_language":"en","subitem_description_type":"Abstract"}]},"item_10_identifier_60":{"attribute_name":"URI","attribute_value_mlt":[{"subitem_identifier_type":"DOI","subitem_identifier_uri":"http://doi.org/10.1002/anie.201608806"},{"subitem_identifier_type":"HDL","subitem_identifier_uri":"http://hdl.handle.net/2237/25738"}]},"item_10_publisher_32":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"Wiley","subitem_publisher_language":"en"}]},"item_10_relation_11":{"attribute_name":"DOI","attribute_value_mlt":[{"subitem_relation_type":"isVersionOf","subitem_relation_type_id":{"subitem_relation_type_id_text":"https://doi.org/10.1002/anie.201608806","subitem_relation_type_select":"DOI"}}]},"item_10_rights_12":{"attribute_name":"権利","attribute_value_mlt":[{"subitem_rights":"This is the peer reviewed version of the following article: [K. Tanifuji, N. Sickerman, C. C. Lee, T. Nagasawa, K. Miyazaki, Y. Ohki, K. Tatsumi, Y. Hu, M. W. Ribbe, Angew. Chem. Int. Ed. 2016, 55, 15633.], which has been published in final form at [http://doi.org/10.1002/anie.201608806]. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Self-Archiving.","subitem_rights_language":"en"}]},"item_10_select_15":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_select_item":"author"}]},"item_10_source_id_7":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"1433-7851","subitem_source_identifier_type":"PISSN"}]},"item_1615787544753":{"attribute_name":"出版タイプ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_ab4af688f83e57aa","subitem_version_type":"AM"}]},"item_access_right":{"attribute_name":"アクセス権","attribute_value_mlt":[{"subitem_access_right":"open access","subitem_access_right_uri":"http://purl.org/coar/access_right/c_abf2"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Tanifuji, Kazuki","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"69925","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Sickerman, Nathaniel","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"69926","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Lee, Chi Chung","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"69927","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Nagasawa, Takayuki","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"69928","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Miyazaki, Kosuke","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"69929","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Ohki, Yasuhiro","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"69930","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Tatsumi, Kazuyuki","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"69931","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Hu, Yilin","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"69932","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Ribbe, Markus W.","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"69933","nameIdentifierScheme":"WEKO"}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2017-12-12"}],"displaytype":"detail","filename":"ACIE2016.pdf","filesize":[{"value":"1.5 MB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"ACIE2016.pdf ファイル公開：2017/12/12","objectType":"fulltext","url":"https://nagoya.repo.nii.ac.jp/record/23541/files/ACIE2016.pdf"},"version_id":"dd3c4bfe-eb7d-44a1-83f5-05f4bfbfd183"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Structure and Reactivity of an Asymmetric Synthetic Mimic of Nitrogenase Cofactor","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Structure and Reactivity of an Asymmetric Synthetic Mimic of Nitrogenase Cofactor","subitem_title_language":"en"}]},"item_type_id":"10","owner":"1","path":["696"],"pubdate":{"attribute_name":"PubDate","attribute_value":"2017-03-21"},"publish_date":"2017-03-21","publish_status":"0","recid":"23541","relation_version_is_last":true,"title":["Structure and Reactivity of an Asymmetric Synthetic Mimic of Nitrogenase Cofactor"],"weko_creator_id":"1","weko_shared_id":-1},"updated":"2023-01-16T04:13:16.714014+00:00"}