{"created":"2021-03-01T06:31:56.322683+00:00","id":24033,"links":{},"metadata":{"_buckets":{"deposit":"f75effcd-903e-4e99-be56-2adbe887ac93"},"_deposit":{"id":"24033","owners":[],"pid":{"revision_id":0,"type":"depid","value":"24033"},"status":"published"},"_oai":{"id":"oai:nagoya.repo.nii.ac.jp:00024033","sets":["312:313:314"]},"author_link":["71340","71341","71342","71343","71344","71345","71346"],"item_10_biblio_info_6":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2017-02-15","bibliographicIssueDateType":"Issued"},"bibliographicPageEnd":"238","bibliographicPageStart":"230","bibliographicVolumeNumber":"335","bibliographic_titles":[{"bibliographic_title":"Journal of Photochemistry and Photobiology A: Chemistry","bibliographic_titleLang":"en"}]}]},"item_10_description_4":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"Five anthocyanins, namely, pelargonidin, cyanidin, delphinidin, petunidin and malvidin 3-O-glucosides, possessing different substitution patterns in the B-ring of the anthocyanidin chromophore were isolated from various plant materials. Dye-sensitized solar cells (DSSCs) were fabricated using the pure pigments, and then their cell colors and conversion efficiencies (η%) were compared. After optimization of the fabrication conditions, all the cells showed 0.6–1.4% conversion efficiency under AM 1.5. Among them, petunidin 3-O-glucoside provided the highest efficiency of 1.42% following the addition of deoxycholic acid (DCA) as an additive; however, removal of the glucosyl unit decreased the efficiency. The cell colors of cyanidin, delphinidin, and petunidin 3-O-glucosides appeared bluer with relatively high η% (>1%) values compared with those of pelargonidin and malvidin 3-O-glucosides. These phenomena may indicate that the former three pigments may attach to TiO2 through the catechol moiety of the B-ring of the chromophores. Time-dependent density functional theory (TD-DFT) calculations were performed on model systems consisting of anthocyanidin dyes on a (TiO2)38 cluster to characterize the photo-absorption properties of DSSCs.","subitem_description_language":"en","subitem_description_type":"Abstract"}]},"item_10_identifier_60":{"attribute_name":"URI","attribute_value_mlt":[{"subitem_identifier_type":"DOI","subitem_identifier_uri":"https://doi.org/10.1016/j.jphotochem.2016.12.005"},{"subitem_identifier_type":"HDL","subitem_identifier_uri":"http://hdl.handle.net/2237/26249"}]},"item_10_publisher_32":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"Elsevier","subitem_publisher_language":"en"}]},"item_10_relation_11":{"attribute_name":"DOI","attribute_value_mlt":[{"subitem_relation_type":"isVersionOf","subitem_relation_type_id":{"subitem_relation_type_id_text":"https://doi.org/10.1016/j.jphotochem.2016.12.005","subitem_relation_type_select":"DOI"}}]},"item_10_rights_12":{"attribute_name":"権利","attribute_value_mlt":[{"subitem_rights":"© 2017. This manuscript version is made available under the CC-BY-NC-ND 4.0 license http://creativecommons.org/licenses/by-nc-nd/4.0/","subitem_rights_language":"en"}]},"item_10_select_15":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_select_item":"author"}]},"item_10_source_id_7":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"1010-6030","subitem_source_identifier_type":"PISSN"}]},"item_1615787544753":{"attribute_name":"出版タイプ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_ab4af688f83e57aa","subitem_version_type":"AM"}]},"item_access_right":{"attribute_name":"アクセス権","attribute_value_mlt":[{"subitem_access_right":"open access","subitem_access_right_uri":"http://purl.org/coar/access_right/c_abf2"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Kimura, Yuki","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"71340","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Maeda, Takeshi","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"71341","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Iuchi, Satoru","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"71342","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Koga, Nobuaki","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"71343","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Murata, Yasujiro","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"71344","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Wakamiya, Atsushi","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"71345","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Yoshida, Kumi","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"71346","nameIdentifierScheme":"WEKO"}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2019-02-15"}],"displaytype":"detail","filename":"JPHOTOCHEM_2016_803_Revision1_V0.pdf","filesize":[{"value":"5.9 MB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"JPHOTOCHEM_2016_803_Revision1_V0.pdf ファイル公開：2019/02/15","objectType":"fulltext","url":"https://nagoya.repo.nii.ac.jp/record/24033/files/JPHOTOCHEM_2016_803_Revision1_V0.pdf"},"version_id":"d8a76b45-a38a-4afe-a4dd-513071c877e5"}]},"item_keyword":{"attribute_name":"キーワード","attribute_value_mlt":[{"subitem_subject":"Anthocyanin","subitem_subject_scheme":"Other"},{"subitem_subject":"Dye-sensitized solar cell","subitem_subject_scheme":"Other"},{"subitem_subject":"Natural pigment","subitem_subject_scheme":"Other"},{"subitem_subject":"Petunidin 3-O-glucoside","subitem_subject_scheme":"Other"},{"subitem_subject":"TD-DFT calculation","subitem_subject_scheme":"Other"},{"subitem_subject":"(TiO2)38 cluster","subitem_subject_scheme":"Other"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Characterization of dye-sensitized solar cells using five pure anthocyanidin 3-O-glucosides possessing different chromophores","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Characterization of dye-sensitized solar cells using five pure anthocyanidin 3-O-glucosides possessing different chromophores","subitem_title_language":"en"}]},"item_type_id":"10","owner":"1","path":["314"],"pubdate":{"attribute_name":"PubDate","attribute_value":"2017-05-09"},"publish_date":"2017-05-09","publish_status":"0","recid":"24033","relation_version_is_last":true,"title":["Characterization of dye-sensitized solar cells using five pure anthocyanidin 3-O-glucosides possessing different chromophores"],"weko_creator_id":"1","weko_shared_id":-1},"updated":"2023-01-16T04:28:19.603435+00:00"}