{"created":"2021-03-01T06:31:56.655239+00:00","id":24038,"links":{},"metadata":{"_buckets":{"deposit":"a6c15d69-0b5c-4449-8745-cf127b6168c7"},"_deposit":{"id":"24038","owners":[],"pid":{"revision_id":0,"type":"depid","value":"24038"},"status":"published"},"_oai":{"id":"oai:nagoya.repo.nii.ac.jp:00024038","sets":["1903:1904:1905"]},"author_link":["71355","71356","71357"],"item_10_biblio_info_6":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2016-12-22","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"2","bibliographicPageEnd":"1107","bibliographicPageStart":"1101","bibliographicVolumeNumber":"7","bibliographic_titles":[{"bibliographic_title":"ACS Catalysis","bibliographic_titleLang":"en"}]}]},"item_10_description_4":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"In the presence of a neutral ruthenium catalyst, Cp*RuCl(cod), 1,5,10-enediynes bearing a styryl terminal underwent cycloisomerization to afford exocyclic 1,3-dienes with an indenylidene moiety. The reaction mechanism is proposed on the basis of the results of control experiments and density functional calculations. The transformations of the obtained cyclization products were also investigated to demonstrate the synthetic potential of this method.","subitem_description_language":"en","subitem_description_type":"Abstract"}]},"item_10_identifier_60":{"attribute_name":"URI","attribute_value_mlt":[{"subitem_identifier_type":"DOI","subitem_identifier_uri":"http://doi.org/10.1021/acscatal.6b03322"},{"subitem_identifier_type":"HDL","subitem_identifier_uri":"http://hdl.handle.net/2237/26253"}]},"item_10_publisher_32":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"ACS Publications","subitem_publisher_language":"en"}]},"item_10_relation_11":{"attribute_name":"DOI","attribute_value_mlt":[{"subitem_relation_type":"isVersionOf","subitem_relation_type_id":{"subitem_relation_type_id_text":"https://doi.org/10.1021/acscatal.6b03322","subitem_relation_type_select":"DOI"}}]},"item_10_rights_12":{"attribute_name":"権利","attribute_value_mlt":[{"subitem_rights":"“This document is the Accepted Manuscript version of a Published Work that appeared in final form in [ACS Catalysis], copyright © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see [http://pubs.acs.org/articlesonrequest/AOR-aitDP7XGZQ7EvxB3zTx3].”","subitem_rights_language":"en"}]},"item_10_select_15":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_select_item":"author"}]},"item_10_source_id_7":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"2155-5435","subitem_source_identifier_type":"EISSN"}]},"item_1615787544753":{"attribute_name":"出版タイプ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_ab4af688f83e57aa","subitem_version_type":"AM"}]},"item_access_right":{"attribute_name":"アクセス権","attribute_value_mlt":[{"subitem_access_right":"open access","subitem_access_right_uri":"http://purl.org/coar/access_right/c_abf2"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Yamamoto, Yoshihiko","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"71355","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Nishimura, Kei-ichiro","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"71356","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Shibuya, Masatoshi","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"71357","nameIdentifierScheme":"WEKO"}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2017-12-22"}],"displaytype":"detail","filename":"ACS_Cat_MS_RevMarked.pdf","filesize":[{"value":"4.8 MB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"ACS_Cat_MS_RevMarked.pdf ファイル公開：2017/12/22","objectType":"fulltext","url":"https://nagoya.repo.nii.ac.jp/record/24038/files/ACS_Cat_MS_RevMarked.pdf"},"version_id":"1e1a4c19-e966-4704-b7ce-b9b86068b9f8"}]},"item_keyword":{"attribute_name":"キーワード","attribute_value_mlt":[{"subitem_subject":"cycloisomerization","subitem_subject_scheme":"Other"},{"subitem_subject":"enediyne","subitem_subject_scheme":"Other"},{"subitem_subject":"indenylidenecycloalkane","subitem_subject_scheme":"Other"},{"subitem_subject":"ruthenium catalyst","subitem_subject_scheme":"Other"},{"subitem_subject":"spirocycle","subitem_subject_scheme":"Other"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Ruthenium-Catalyzed Cycloisomerization of 1,6-Diynes with Styryl Terminals Leading to Indenylidene Cycloalkanes","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Ruthenium-Catalyzed Cycloisomerization of 1,6-Diynes with Styryl Terminals Leading to Indenylidene Cycloalkanes","subitem_title_language":"en"}]},"item_type_id":"10","owner":"1","path":["1905"],"pubdate":{"attribute_name":"PubDate","attribute_value":"2017-05-09"},"publish_date":"2017-05-09","publish_status":"0","recid":"24038","relation_version_is_last":true,"title":["Ruthenium-Catalyzed Cycloisomerization of 1,6-Diynes with Styryl Terminals Leading to Indenylidene Cycloalkanes"],"weko_creator_id":"1","weko_shared_id":-1},"updated":"2023-01-16T05:03:43.742767+00:00"}