{"created":"2021-03-01T06:31:59.027806+00:00","id":24074,"links":{},"metadata":{"_buckets":{"deposit":"0fe266ca-953a-49e3-aa86-2a5170437cb4"},"_deposit":{"id":"24074","owners":[],"pid":{"revision_id":0,"type":"depid","value":"24074"},"status":"published"},"_oai":{"id":"oai:nagoya.repo.nii.ac.jp:00024074","sets":["643:666:667"]},"author_link":["71461","71462","71463"],"item_10_biblio_info_6":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2017-02-01","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"5","bibliographicPageEnd":"457","bibliographicPageStart":"455","bibliographicVolumeNumber":"58","bibliographic_titles":[{"bibliographic_title":"Tetrahedron Letters","bibliographic_titleLang":"en"}]}]},"item_10_description_4":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"A practical synthesis of ortho-silyl-substituted phenol from ortho-bromophenyl silyl ethers without using RLi is described. Various ortho-bromophenyl silyl ethers are treated with commercially available Mg turnings, which are easy to handle in air, and transfer of the silyl group to the ortho-position occurs in good to high yields. Selective mono-magnesiation of 2,6-dibromophenyl silyl ether is observed even in the presence of excess Mg, and ortho-bromo-6-silylphenol is obtained as the predominant product. The obtained ortho-silyl-substituted phenol is formylated with (CH2O)n/MgCl2/Et3N, and then condensation with a diamine leads to a silyl-substituted salen-type ligand in a good yield. This scheme is suitable for the large scale synthesis of silyl-substituted salen-type ligands bearing imine groups.","subitem_description_language":"en","subitem_description_type":"Abstract"}]},"item_10_identifier_60":{"attribute_name":"URI","attribute_value_mlt":[{"subitem_identifier_type":"DOI","subitem_identifier_uri":"https://doi.org/10.1016/j.tetlet.2016.12.052"},{"subitem_identifier_type":"HDL","subitem_identifier_uri":"http://hdl.handle.net/2237/26286"}]},"item_10_publisher_32":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"Elsevier","subitem_publisher_language":"en"}]},"item_10_relation_11":{"attribute_name":"DOI","attribute_value_mlt":[{"subitem_relation_type":"isVersionOf","subitem_relation_type_id":{"subitem_relation_type_id_text":"https://doi.org/10.1016/j.tetlet.2016.12.052","subitem_relation_type_select":"DOI"}}]},"item_10_rights_12":{"attribute_name":"権利","attribute_value_mlt":[{"subitem_rights":"© 2017. This manuscript version is made available under the CC-BY-NC-ND 4.0 license http://creativecommons.org/licenses/by-nc-nd/4.0/","subitem_rights_language":"en"}]},"item_10_select_15":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_select_item":"author"}]},"item_10_source_id_7":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"0040-4039","subitem_source_identifier_type":"PISSN"}]},"item_1615787544753":{"attribute_name":"出版タイプ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_ab4af688f83e57aa","subitem_version_type":"AM"}]},"item_access_right":{"attribute_name":"アクセス権","attribute_value_mlt":[{"subitem_access_right":"open access","subitem_access_right_uri":"http://purl.org/coar/access_right/c_abf2"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Hasegawa, Takashi","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"71461","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Kishida, Hisanori","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"71462","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Nomura, Nobuyoshi","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"71463","nameIdentifierScheme":"WEKO"}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2019-02-01"}],"displaytype":"detail","filename":"3_Manuscript.pdf","filesize":[{"value":"375.8 kB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"3_Manuscript.pdf ファイル公開：2019/02/01","objectType":"fulltext","url":"https://nagoya.repo.nii.ac.jp/record/24074/files/3_Manuscript.pdf"},"version_id":"c76438bb-bfff-4d3a-8e5d-a8fbe95fc775"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"A practical ortho-rearrangement of silyl group of ortho-bromophenyl silyl ethers using magnesium(0)","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"A practical ortho-rearrangement of silyl group of ortho-bromophenyl silyl ethers using magnesium(0)","subitem_title_language":"en"}]},"item_type_id":"10","owner":"1","path":["667"],"pubdate":{"attribute_name":"PubDate","attribute_value":"2017-05-11"},"publish_date":"2017-05-11","publish_status":"0","recid":"24074","relation_version_is_last":true,"title":["A practical ortho-rearrangement of silyl group of ortho-bromophenyl silyl ethers using magnesium(0)"],"weko_creator_id":"1","weko_shared_id":-1},"updated":"2023-01-16T04:54:43.590933+00:00"}