{"created":"2021-03-01T06:32:20.393975+00:00","id":24396,"links":{},"metadata":{"_buckets":{"deposit":"c9321b4f-3760-4507-ad0c-2353b40abb44"},"_deposit":{"id":"24396","owners":[],"pid":{"revision_id":0,"type":"depid","value":"24396"},"status":"published"},"_oai":{"id":"oai:nagoya.repo.nii.ac.jp:00024396","sets":["1935:1936:1937"]},"author_link":["72274","72275"],"item_10_biblio_info_6":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2017-02-16","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"9","bibliographicPageEnd":"2170","bibliographicPageStart":"2164","bibliographicVolumeNumber":"121","bibliographic_titles":[{"bibliographic_title":"Journal of Physical Chemistry B","bibliographic_titleLang":"en"}]}]},"item_10_description_4":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"The control of radiative and nonradiative decay is important in the design of bioimaging molecules. Dimethylaminobenzonitrile (DMABN) is a suitable model molecule to study radiative and nonradiative decay processes and has been investigated by theoretical and experimental methods. However, an atomistic understanding of the nonradiative decay in solutions remains to be achieved. In this study, we investigated the potential-energy surfaces in excited states along the rotation of the dimethylamino group and found that the degeneration between S1 and T1 states is one of the key factors in the nonradiative decay in polar solvents. In addition, we found that the degeneration is precisely controlled by a fundamental physical property, exchange integral. Although DMABN is a simple molecule, the understanding of the nonradiative decay process on the basis of physical properties should be useful in the design of more complicated imaging molecules.","subitem_description_language":"en","subitem_description_type":"Abstract"}]},"item_10_identifier_60":{"attribute_name":"URI","attribute_value_mlt":[{"subitem_identifier_type":"DOI","subitem_identifier_uri":"http://doi.org/10.1021/acs.jpcb.6b11654"},{"subitem_identifier_type":"HDL","subitem_identifier_uri":"http://hdl.handle.net/2237/26608"}]},"item_10_publisher_32":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"ACS Publications","subitem_publisher_language":"en"}]},"item_10_relation_11":{"attribute_name":"DOI","attribute_value_mlt":[{"subitem_relation_type":"isVersionOf","subitem_relation_type_id":{"subitem_relation_type_id_text":"https://doi.org/10.1021/acs.jpcb.6b11654","subitem_relation_type_select":"DOI"}}]},"item_10_rights_12":{"attribute_name":"権利","attribute_value_mlt":[{"subitem_rights":"“This document is the Accepted Manuscript version of a Published Work that appeared in final form in [Macromolecules], copyright © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see [http://pubs.acs.org/articlesonrequest/AOR-ht66TMr53tuJgMICXDTQ].”","subitem_rights_language":"en"}]},"item_10_select_15":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_select_item":"author"}]},"item_10_source_id_7":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"1520-6106","subitem_source_identifier_type":"PISSN"}]},"item_1615787544753":{"attribute_name":"出版タイプ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_ab4af688f83e57aa","subitem_version_type":"AM"}]},"item_access_right":{"attribute_name":"アクセス権","attribute_value_mlt":[{"subitem_access_right":"open access","subitem_access_right_uri":"http://purl.org/coar/access_right/c_abf2"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Suda, Kayo","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"72274","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Yokogawa, Daisuke","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"72275","nameIdentifierScheme":"WEKO"}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2018-02-16"}],"displaytype":"detail","filename":"article_openAcess.pdf","filesize":[{"value":"1.6 MB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"article_openAcess.pdf ファイル公開：2018/02/16","objectType":"fulltext","url":"https://nagoya.repo.nii.ac.jp/record/24396/files/article_openAcess.pdf"},"version_id":"9585b321-def9-4764-888c-f0cf13f88098"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Theoretical Study on Nonradiative Decay of Dimethylaminobenzonitrile through Triplet State in Gas-Phase, Nonpolar, and Polar Solutions","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Theoretical Study on Nonradiative Decay of Dimethylaminobenzonitrile through Triplet State in Gas-Phase, Nonpolar, and Polar Solutions","subitem_title_language":"en"}]},"item_type_id":"10","owner":"1","path":["1937"],"pubdate":{"attribute_name":"PubDate","attribute_value":"2017-06-08"},"publish_date":"2017-06-08","publish_status":"0","recid":"24396","relation_version_is_last":true,"title":["Theoretical Study on Nonradiative Decay of Dimethylaminobenzonitrile through Triplet State in Gas-Phase, Nonpolar, and Polar Solutions"],"weko_creator_id":"1","weko_shared_id":-1},"updated":"2023-01-16T04:29:13.324676+00:00"}