{"created":"2021-03-01T06:32:21.756046+00:00","id":24417,"links":{},"metadata":{"_buckets":{"deposit":"a1b804f1-ff9c-4ba3-abcb-0425c1fda5f7"},"_deposit":{"id":"24417","owners":[],"pid":{"revision_id":0,"type":"depid","value":"24417"},"status":"published"},"_oai":{"id":"oai:nagoya.repo.nii.ac.jp:00024417","sets":["320:321:322"]},"author_link":["72338","72339","72340","72341","72342"],"item_10_biblio_info_6":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2017-02-22","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"7","bibliographicPageEnd":"2596","bibliographicPageStart":"2593","bibliographicVolumeNumber":"139","bibliographic_titles":[{"bibliographic_title":"Journal of the American Chemical Society","bibliographic_titleLang":"en"}]}]},"item_10_description_4":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"Tetra(o-tolyl)diborane(4), 1, was synthesized and characterized experimentally as well as theoretically by density functional theory (DFT) calculations. Exposure of 1 to H2 (1 bar) at room temperature afforded the corresponding di(o-tolyl)hydroborane through cleavage of the H–H and B–B bonds. DFT calculations suggested a diarylboryl anion character for the transition state.","subitem_description_language":"en","subitem_description_type":"Abstract"}]},"item_10_identifier_60":{"attribute_name":"URI","attribute_value_mlt":[{"subitem_identifier_type":"DOI","subitem_identifier_uri":"http://doi.org/10.1021/jacs.7b00924"},{"subitem_identifier_type":"HDL","subitem_identifier_uri":"http://hdl.handle.net/2237/26627"}]},"item_10_publisher_32":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"ACS Publications","subitem_publisher_language":"en"}]},"item_10_relation_11":{"attribute_name":"DOI","attribute_value_mlt":[{"subitem_relation_type":"isVersionOf","subitem_relation_type_id":{"subitem_relation_type_id_text":"https://doi.org/10.1021/jacs.7b00924","subitem_relation_type_select":"DOI"}}]},"item_10_rights_12":{"attribute_name":"権利","attribute_value_mlt":[{"subitem_rights":"“This document is the Accepted Manuscript version of a Published Work that appeared in final form in [Journal of the American Chemical Society], copyright © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see [http://pubs.acs.org/articlesonrequest/AOR-aTWSauz2HwYP55PtkXZP].”","subitem_rights_language":"en"}]},"item_10_select_15":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_select_item":"author"}]},"item_10_source_id_7":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"0002-7863","subitem_source_identifier_type":"PISSN"}]},"item_1615787544753":{"attribute_name":"出版タイプ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_ab4af688f83e57aa","subitem_version_type":"AM"}]},"item_access_right":{"attribute_name":"アクセス権","attribute_value_mlt":[{"subitem_access_right":"open access","subitem_access_right_uri":"http://purl.org/coar/access_right/c_abf2"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Tsukahara, Nana","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"72338","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Asakawa, Hiroki","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"72339","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Lee, Ka-Ho","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"72340","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Lin, Zhenyang","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"72341","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Yamashita, Makoto","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"72342","nameIdentifierScheme":"WEKO"}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2018-02-22"}],"displaytype":"detail","filename":"JACS.pdf","filesize":[{"value":"377.2 kB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"JACS.pdf ファイル公開：2018/02/22","objectType":"fulltext","url":"https://nagoya.repo.nii.ac.jp/record/24417/files/JACS.pdf"},"version_id":"f3744911-0ac7-4248-a38e-dd5c69165b15"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Cleaving Dihydrogen with Tetra(o-tolyl)diborane(4)","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Cleaving Dihydrogen with Tetra(o-tolyl)diborane(4)","subitem_title_language":"en"}]},"item_type_id":"10","owner":"1","path":["322"],"pubdate":{"attribute_name":"PubDate","attribute_value":"2017-06-09"},"publish_date":"2017-06-09","publish_status":"0","recid":"24417","relation_version_is_last":true,"title":["Cleaving Dihydrogen with Tetra(o-tolyl)diborane(4)"],"weko_creator_id":"1","weko_shared_id":-1},"updated":"2023-01-16T04:14:03.388790+00:00"}