{"created":"2021-03-01T06:32:21.821477+00:00","id":24418,"links":{},"metadata":{"_buckets":{"deposit":"fd8c8554-754b-4d61-8ffe-9b8ee333b5ac"},"_deposit":{"id":"24418","owners":[],"pid":{"revision_id":0,"type":"depid","value":"24418"},"status":"published"},"_oai":{"id":"oai:nagoya.repo.nii.ac.jp:00024418","sets":["320:321:322"]},"author_link":["72343","72344","72345","72346","72347"],"item_10_biblio_info_6":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2017-02-01","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"6","bibliographicPageEnd":"1662","bibliographicPageStart":"1658","bibliographicVolumeNumber":"56","bibliographic_titles":[{"bibliographic_title":"ANGEWANDTE CHEMIE-INTERNATIONAL EDITION","bibliographic_titleLang":"en"}]}]},"item_10_description_4":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"Radical anions of a diphosphene with two boryl substituents were isolated and characterized by single-crystal X-ray diffraction, electron spin resonance (ESR), and UV/Vis absorption spectroscopy as well as DFT calculations. Structural analysis of the radical anions revealed an elongation of the P=P bond and a contraction of the B−P bonds relative to the neutral diphosphene. The UV/Vis spectra of these radical anions showed a strong absorption in the visible region, which was assigned to SOMO-related transitions on the basis of DFT calculations. The ESR spectra revealed that the hyperfine coupling constant with the phosphorus nuclei is the smallest that has been reported thus far. The results of the DFT calculations furthermore suggest that this should be attributed to a soaking of electron spin to the vacant p orbitals of the boryl substituents.","subitem_description_language":"en","subitem_description_type":"Abstract"}]},"item_10_identifier_60":{"attribute_name":"URI","attribute_value_mlt":[{"subitem_identifier_type":"DOI","subitem_identifier_uri":"http://doi.org/10.1002/anie.201611762"},{"subitem_identifier_type":"HDL","subitem_identifier_uri":"http://hdl.handle.net/2237/26630"}]},"item_10_publisher_32":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"Wiley","subitem_publisher_language":"en"}]},"item_10_relation_11":{"attribute_name":"DOI","attribute_value_mlt":[{"subitem_relation_type":"isVersionOf","subitem_relation_type_id":{"subitem_relation_type_id_text":"https://doi.org/10.1002/anie.201611762","subitem_relation_type_select":"DOI"}}]},"item_10_rights_12":{"attribute_name":"権利","attribute_value_mlt":[{"subitem_rights":"This is the peer reviewed version of the following article: [S.-s. Asami, S. Ishida, T. Iwamoto, K. Suzuki, M. Yamashita, Angew. Chem. Int. Ed. 2017, 56, 1658.<br/>], which has been published in final form at [http://doi.org/10.1002/anie.201611762]. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Self-Archiving.","subitem_rights_language":"en"}]},"item_10_select_15":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_select_item":"author"}]},"item_10_source_id_7":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"1433-7851","subitem_source_identifier_type":"PISSN"}]},"item_1615787544753":{"attribute_name":"出版タイプ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_ab4af688f83e57aa","subitem_version_type":"AM"}]},"item_access_right":{"attribute_name":"アクセス権","attribute_value_mlt":[{"subitem_access_right":"open access","subitem_access_right_uri":"http://purl.org/coar/access_right/c_abf2"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Asami, Shun-suke","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"72343","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Ishida, Shintaro","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"72344","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Iwamoto, Takeaki","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"72345","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Suzuki, Katsunori","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"72346","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Yamashita, Makoto","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"72347","nameIdentifierScheme":"WEKO"}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2018-02-01"}],"displaytype":"detail","filename":"ACIE.pdf","filesize":[{"value":"802.9 kB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"ACIE.pdf ファイル公開：2018/02/01","objectType":"fulltext","url":"https://nagoya.repo.nii.ac.jp/record/24418/files/ACIE.pdf"},"version_id":"a964a625-0140-43aa-8bbb-9a40e25fb244"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Isolation and Characterization of Radical Anions Derived from a Boryl-Substituted Diphosphene","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Isolation and Characterization of Radical Anions Derived from a Boryl-Substituted Diphosphene","subitem_title_language":"en"}]},"item_type_id":"10","owner":"1","path":["322"],"pubdate":{"attribute_name":"PubDate","attribute_value":"2017-06-09"},"publish_date":"2017-06-09","publish_status":"0","recid":"24418","relation_version_is_last":true,"title":["Isolation and Characterization of Radical Anions Derived from a Boryl-Substituted Diphosphene"],"weko_creator_id":"1","weko_shared_id":-1},"updated":"2023-01-16T04:59:46.092966+00:00"}