{"created":"2021-03-01T06:32:22.732494+00:00","id":24432,"links":{},"metadata":{"_buckets":{"deposit":"763b71bb-db10-423c-86a1-64d6af5ab5d3"},"_deposit":{"id":"24432","owners":[],"pid":{"revision_id":0,"type":"depid","value":"24432"},"status":"published"},"_oai":{"id":"oai:nagoya.repo.nii.ac.jp:00024432","sets":["336:695:696"]},"author_link":["72401","72402","72403","72404","72405","72406"],"item_10_biblio_info_6":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2017-02-27","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"6","bibliographicPageEnd":"1184","bibliographicPageStart":"1179","bibliographicVolumeNumber":"8","bibliographic_titles":[{"bibliographic_title":"Journal of Physical Chemistry Letters","bibliographic_titleLang":"en"}]}]},"item_10_description_4":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"In initial events of the photosynthesis by higher plants, the photosystem II (PSII) generates photoinduced primary charge-separated (CS) state composed of reduced pheophytin (PheoD1–•) and oxidized special pair (P+•) in chlorophyll a (Chla) PD1/PD2 in the D1/D2 heterodimer, ultimately leading to the water oxidation at the oxygen-evolving Mn4CaO5 cluster by P+•. To understand the mechanism of the efficient generation of initially localized CS state (PD1+• PheoD1–•), we have characterized cofactor geometries and electronic coupling of the photoinduced primary CS state in quinone prereduced membrane of PSII from spinach using the time-resolved electron paramagnetic resonance method. It has been revealed that the electronic coupling between the charges is significantly weak in the CS state separated by 1.5 nm, showing the importance of regulated cofactor–cofactor electronic interaction between a vinyl substituent in PheoD1 and an accessory chlorophyll to inhibit the energy-wasting charge recombination after the primary electron-transfer processes.","subitem_description_language":"en","subitem_description_type":"Abstract"}]},"item_10_identifier_60":{"attribute_name":"URI","attribute_value_mlt":[{"subitem_identifier_type":"DOI","subitem_identifier_uri":"http://doi.org/10.1021/acs.jpclett.7b00044"},{"subitem_identifier_type":"HDL","subitem_identifier_uri":"http://hdl.handle.net/2237/26649"}]},"item_10_publisher_32":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"ACS Publications","subitem_publisher_language":"en"}]},"item_10_relation_11":{"attribute_name":"DOI","attribute_value_mlt":[{"subitem_relation_type":"isVersionOf","subitem_relation_type_id":{"subitem_relation_type_id_text":"https://doi.org/10.1021/acs.jpclett.7b00044","subitem_relation_type_select":"DOI"}}]},"item_10_rights_12":{"attribute_name":"権利","attribute_value_mlt":[{"subitem_rights":"“This document is the Accepted Manuscript version of a Published Work that appeared in final form in [Journal of Physical Chemistry Letters], copyright © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see [http://pubs.acs.org/articlesonrequest/AOR-IUe5XQWw7CEKarE2gaVa].”","subitem_rights_language":"en"}]},"item_10_select_15":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_select_item":"author"}]},"item_10_source_id_7":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"1948-7185","subitem_source_identifier_type":"EISSN"}]},"item_1615787544753":{"attribute_name":"出版タイプ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_ab4af688f83e57aa","subitem_version_type":"AM"}]},"item_access_right":{"attribute_name":"アクセス権","attribute_value_mlt":[{"subitem_access_right":"open access","subitem_access_right_uri":"http://purl.org/coar/access_right/c_abf2"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Hasegawa, Masashi","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"72401","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Nagashima, Hiroki","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"72402","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Minobe, Reina","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"72403","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Tachikawa, Takashi","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"72404","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Mino, Hiroyuki","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"72405","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Kobori, Yasuhiro","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"72406","nameIdentifierScheme":"WEKO"}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2018-02-27"}],"displaytype":"detail","filename":"JPCLPSII_0104MS-6.pdf","filesize":[{"value":"630.5 kB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"JPCLPSII_0104MS-6.pdf ファイル公開：2018/02/27","objectType":"fulltext","url":"https://nagoya.repo.nii.ac.jp/record/24432/files/JPCLPSII_0104MS-6.pdf"},"version_id":"c0f37f64-941d-46e8-8243-8835de0982c4"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Regulated Electron Tunneling of Photoinduced Primary Charge-Separated State in the Photosystem II Reaction Center","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Regulated Electron Tunneling of Photoinduced Primary Charge-Separated State in the Photosystem II Reaction Center","subitem_title_language":"en"}]},"item_type_id":"10","owner":"1","path":["696"],"pubdate":{"attribute_name":"PubDate","attribute_value":"2017-06-12"},"publish_date":"2017-06-12","publish_status":"0","recid":"24432","relation_version_is_last":true,"title":["Regulated Electron Tunneling of Photoinduced Primary Charge-Separated State in the Photosystem II Reaction Center"],"weko_creator_id":"1","weko_shared_id":-1},"updated":"2023-01-16T04:14:25.752822+00:00"}