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  1. D400 創薬科学研究科
  2. D400a 雑誌掲載論文
  3. 学術雑誌

Electrophilic Derivatization of Trifluoromethyl-Substituted Semisquarate Using Unsaturated Organosilanes and Subsequent Ring Transformations

http://hdl.handle.net/2237/26757
http://hdl.handle.net/2237/26757
bbdcff2b-59ec-40cb-af5b-8b9fe6f50a1d
名前 / ファイル ライセンス アクション
ASC_update_MS_Rev.pdf ASC_update_MS_Rev.pdf ファイル公開:2018/04/17 (1.2 MB)
Item type 学術雑誌論文 / Journal Article(1)
公開日 2017-07-04
タイトル
タイトル Electrophilic Derivatization of Trifluoromethyl-Substituted Semisquarate Using Unsaturated Organosilanes and Subsequent Ring Transformations
言語 en
著者 Kurohara, Takashi

× Kurohara, Takashi

WEKO 72635

en Kurohara, Takashi

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Shibuya, Masatoshi

× Shibuya, Masatoshi

WEKO 72636

en Shibuya, Masatoshi

Search repository
Yamamoto, Yoshihiko

× Yamamoto, Yoshihiko

WEKO 72637

en Yamamoto, Yoshihiko

Search repository
アクセス権
アクセス権 open access
アクセス権URI http://purl.org/coar/access_right/c_abf2
権利
言語 en
権利情報 This is the peer reviewed version of the following article: [T. Kurohara, M. Shibuya, Y. Yamamoto, Adv. Synth. Catal. 2017, 359, 1413.], which has been published in final form at [http://doi.org/10.1002/adsc.201601297]. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Self-Archiving.
抄録
内容記述 To extend the synthetic potential of trifluoromethyl-substituted semisquarate (CF3-semisquarate) previously synthesized by us as a pluripotent building block, its electrophilic derivatization was investigated. The electrophilic addition of allylic silanes and silyl enolates to CF3-semisquarate afforded the corresponding 4-hydroxycyclobutenones. Subsequent ring expansion of these products via thermolysis or oxidation using lead tetraacetate afforded trifluoromethylated bicyclo[3.2.0]heptenones or (Z)-γ-alkylidenetetronates.
言語 en
内容記述タイプ Abstract
出版者
言語 en
出版者 Wiley
言語
言語 eng
資源タイプ
資源タイプresource http://purl.org/coar/resource_type/c_6501
タイプ journal article
出版タイプ
出版タイプ AM
出版タイプResource http://purl.org/coar/version/c_ab4af688f83e57aa
DOI
関連タイプ isVersionOf
識別子タイプ DOI
関連識別子 https://doi.org/10.1002/adsc.201601297
ISSN
収録物識別子タイプ PISSN
収録物識別子 1615-4150
書誌情報 en : Advanced Synthesis & Catalysis

巻 359, 号 8, p. 1413-1419, 発行日 2017-04-17
著者版フラグ
値 author
URI
識別子 http://doi.org/10.1002/adsc.201601297
識別子タイプ DOI
URI
識別子 http://hdl.handle.net/2237/26757
識別子タイプ HDL
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