@article{oai:nagoya.repo.nii.ac.jp:00024636, author = {Yamamoto, Yoshihiko and Ohkubo, Erina and Shibuya, Masatoshi}, issue = {10}, journal = {ADVANCED SYNTHESIS & CATALYSIS}, month = {May}, note = {The copper-catalyzed hydroarylation of (trifluoromethyl)alkynes with (o-nitrophenyl)boronic acids selectively afforded trisubstituted (trifluoromethyl)alkenes bearing an o-nitrophenyl group. The obtained hydroarylation products were converted into 3-aryl-2-(trifluoromethyl)indoles in high yields via molybdenum-catalyzed Cadogan cyclization. Similarly, the hydroarylation product prepared from (o-nitrophenyl)(trifluoromethyl)alkyne and (p-anisyl)boronic acid also underwent Cadogan cyclization, albeit with a longer reaction time, affording the desired indole product in a high yield.}, pages = {1747--1751}, title = {Synthesis of 3-Aryl-2-(trifluoromethyl)indoles via Copper-Catalyzed Hydroarylation and Subsequent Cadogan Cyclization}, volume = {359}, year = {2017} }