{"created":"2021-03-01T06:32:36.092606+00:00","id":24636,"links":{},"metadata":{"_buckets":{"deposit":"84db885f-a895-4bca-8957-2b0ada966d17"},"_deposit":{"id":"24636","owners":[],"pid":{"revision_id":0,"type":"depid","value":"24636"},"status":"published"},"_oai":{"id":"oai:nagoya.repo.nii.ac.jp:00024636","sets":["1903:1904:1905"]},"author_link":["72943","72944","72945"],"item_10_biblio_info_6":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2017-05-17","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"10","bibliographicPageEnd":"1751","bibliographicPageStart":"1747","bibliographicVolumeNumber":"359","bibliographic_titles":[{"bibliographic_title":"ADVANCED SYNTHESIS & CATALYSIS","bibliographic_titleLang":"en"}]}]},"item_10_description_4":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"The copper-catalyzed hydroarylation of (trifluoromethyl)alkynes with (o-nitrophenyl)boronic acids selectively afforded trisubstituted (trifluoromethyl)alkenes bearing an o-nitrophenyl group. The obtained hydroarylation products were converted into 3-aryl-2-(trifluoromethyl)indoles in high yields via molybdenum-catalyzed Cadogan cyclization. Similarly, the hydroarylation product prepared from (o-nitrophenyl)(trifluoromethyl)alkyne and (p-anisyl)boronic acid also underwent Cadogan cyclization, albeit with a longer reaction time, affording the desired indole product in a high yield.","subitem_description_language":"en","subitem_description_type":"Abstract"}]},"item_10_identifier_60":{"attribute_name":"URI","attribute_value_mlt":[{"subitem_identifier_type":"DOI","subitem_identifier_uri":"http://doi.org/10.1002/adsc.201700122"},{"subitem_identifier_type":"HDL","subitem_identifier_uri":"http://hdl.handle.net/2237/26854"}]},"item_10_publisher_32":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"Wiley","subitem_publisher_language":"en"}]},"item_10_relation_11":{"attribute_name":"DOI","attribute_value_mlt":[{"subitem_relation_type":"isVersionOf","subitem_relation_type_id":{"subitem_relation_type_id_text":"https://doi.org/10.1002/adsc.201700122","subitem_relation_type_select":"DOI"}}]},"item_10_rights_12":{"attribute_name":"権利","attribute_value_mlt":[{"subitem_rights":"This is the peer reviewed version of the following article: [Y. Yamamoto, E. Ohkubo, M. Shibuya, Adv. Synth. Catal. 2017, 359, 1747.], which has been published in final form at [http://doi.org/10.1002/adsc.201700122]. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Self-Archiving.","subitem_rights_language":"en"}]},"item_10_select_15":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_select_item":"author"}]},"item_10_source_id_7":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"1615-4150","subitem_source_identifier_type":"PISSN"}]},"item_1615787544753":{"attribute_name":"出版タイプ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_ab4af688f83e57aa","subitem_version_type":"AM"}]},"item_access_right":{"attribute_name":"アクセス権","attribute_value_mlt":[{"subitem_access_right":"open access","subitem_access_right_uri":"http://purl.org/coar/access_right/c_abf2"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Yamamoto, Yoshihiko","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"72943","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Ohkubo, Erina","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"72944","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Shibuya, Masatoshi","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"72945","nameIdentifierScheme":"WEKO"}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2018-05-17"}],"displaytype":"detail","filename":"ASC_MS.pdf","filesize":[{"value":"431.5 kB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"ASC_MS.pdf ファイル公開：2018/05/17","objectType":"fulltext","url":"https://nagoya.repo.nii.ac.jp/record/24636/files/ASC_MS.pdf"},"version_id":"53e33b07-136f-44f3-9acf-985e432d8ea9"}]},"item_keyword":{"attribute_name":"キーワード","attribute_value_mlt":[{"subitem_subject":"copper","subitem_subject_scheme":"Other"},{"subitem_subject":"molybdenum","subitem_subject_scheme":"Other"},{"subitem_subject":"fluorine","subitem_subject_scheme":"Other"},{"subitem_subject":"alkyne","subitem_subject_scheme":"Other"},{"subitem_subject":"indole","subitem_subject_scheme":"Other"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Synthesis of 3-Aryl-2-(trifluoromethyl)indoles via Copper-Catalyzed Hydroarylation and Subsequent Cadogan Cyclization","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Synthesis of 3-Aryl-2-(trifluoromethyl)indoles via Copper-Catalyzed Hydroarylation and Subsequent Cadogan Cyclization","subitem_title_language":"en"}]},"item_type_id":"10","owner":"1","path":["1905"],"pubdate":{"attribute_name":"PubDate","attribute_value":"2017-08-01"},"publish_date":"2017-08-01","publish_status":"0","recid":"24636","relation_version_is_last":true,"title":["Synthesis of 3-Aryl-2-(trifluoromethyl)indoles via Copper-Catalyzed Hydroarylation and Subsequent Cadogan Cyclization"],"weko_creator_id":"1","weko_shared_id":-1},"updated":"2023-01-16T05:03:43.354121+00:00"}