{"_buckets": {"deposit": "fd208de9-f1a3-484f-a6cd-9665dc7fabde"}, "_deposit": {"id": "24730", "owners": [], "pid": {"revision_id": 0, "type": "depid", "value": "24730"}, "status": "published"}, "_oai": {"id": "oai:nagoya.repo.nii.ac.jp:00024730", "sets": ["696"]}, "author_link": ["73397", "73398", "73399", "73400", "73401", "73402"], "item_10_biblio_info_6": {"attribute_name": "書誌情報", "attribute_value_mlt": [{"bibliographicIssueDates": {"bibliographicIssueDate": "2017-06-07", "bibliographicIssueDateType": "Issued"}, "bibliographicIssueNumber": "21", "bibliographicPageEnd": "4703", "bibliographicPageStart": "4697", "bibliographicVolumeNumber": "15", "bibliographic_titles": [{"bibliographic_title": "Organic \u0026 Biomolecular Chemistry", "bibliographic_titleLang": "en"}]}]}, "item_10_description_4": {"attribute_name": "抄録", "attribute_value_mlt": [{"subitem_description": "The synthesis and properties of a new π-extended double [6]helicene 2 and a dithia[6]helicene 3 are described. Compared to the previously reported parent double-helicene molecule 1, the introduction of n-butyl groups successfully improved the solubility, which allowed an experimental investigation into the electronic structure of 2 and 3 by photophysical measurements and cyclic voltammetry. The characteristic two-blade propeller structures of 2 and 3 were unambiguously determined by single-crystal X-ray diffraction analysis. The crystal packing structure of 2 exhibited a contorted two-dimensional stacking, whereby molecules of n-pentane were incorporated in the stacks. Despite the presence of n-butyl groups, 3 formed a unique three-dimensional stacking lattice in the crystal. Time-resolved microwave conductivity measurements revealed that the double helicenes (1–3) exhibited transient conductivities. An organic field-effect transistor fabricated using 3 was found to function as a p-type transistor.", "subitem_description_language": "en", "subitem_description_type": "Abstract"}]}, "item_10_identifier_60": {"attribute_name": "URI", "attribute_value_mlt": [{"subitem_identifier_type": "DOI", "subitem_identifier_uri": "http://doi.org/10.1039/C7OB00987A"}, {"subitem_identifier_type": "HDL", "subitem_identifier_uri": "http://hdl.handle.net/2237/26952"}]}, "item_10_publisher_32": {"attribute_name": "出版者", "attribute_value_mlt": [{"subitem_publisher": "Royal Society of Chemistry", "subitem_publisher_language": "en"}]}, "item_10_relation_11": {"attribute_name": "DOI", "attribute_value_mlt": [{"subitem_relation_type": "isVersionOf", "subitem_relation_type_id": {"subitem_relation_type_id_text": "https://doi.org/10.1039/C7OB00987A", "subitem_relation_type_select": "DOI"}}]}, "item_10_select_15": {"attribute_name": "著者版フラグ", "attribute_value_mlt": [{"subitem_select_item": "author"}]}, "item_10_source_id_7": {"attribute_name": "ISSN", "attribute_value_mlt": [{"subitem_source_identifier": "1477-0520", "subitem_source_identifier_type": "PISSN"}]}, "item_1615787544753": {"attribute_name": "出版タイプ", "attribute_value_mlt": [{"subitem_version_resource": "http://purl.org/coar/version/c_ab4af688f83e57aa", "subitem_version_type": "AM"}]}, "item_access_right": {"attribute_name": "アクセス権", "attribute_value_mlt": [{"subitem_access_right": "open access", "subitem_access_right_uri": "http://purl.org/coar/access_right/c_abf2"}]}, "item_creator": {"attribute_name": "著者", "attribute_type": "creator", "attribute_value_mlt": [{"creatorNames": [{"creatorName": "Fujikawa, Takao", "creatorNameLang": "en"}], "nameIdentifiers": [{"nameIdentifier": "73397", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Mitoma, Nobuhiko", "creatorNameLang": "en"}], "nameIdentifiers": [{"nameIdentifier": "73398", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Wakamiya, Atsushi", "creatorNameLang": "en"}], "nameIdentifiers": [{"nameIdentifier": "73399", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Saeki, Akinori", "creatorNameLang": "en"}], "nameIdentifiers": [{"nameIdentifier": "73400", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Segawa, Yasutomo", "creatorNameLang": "en"}], "nameIdentifiers": [{"nameIdentifier": "73401", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Itami, Kenichiro", "creatorNameLang": "en"}], "nameIdentifiers": [{"nameIdentifier": "73402", "nameIdentifierScheme": "WEKO"}]}]}, "item_files": {"attribute_name": "ファイル情報", "attribute_type": "file", "attribute_value_mlt": [{"accessrole": "open_date", "date": [{"dateType": "Available", "dateValue": "2018-06-07"}], "displaytype": "detail", "download_preview_message": "", "file_order": 0, "filename": "Fujikawa_OBC.pdf", "filesize": [{"value": "4.2 MB"}], "format": "application/pdf", "future_date_message": "", "is_thumbnail": false, "licensetype": "license_note", "mimetype": "application/pdf", "size": 4200000.0, "url": {"label": "Fujikawa_OBC.pdf ファイル公開：2018/06/07", "objectType": "fulltext", "url": "https://nagoya.repo.nii.ac.jp/record/24730/files/Fujikawa_OBC.pdf"}, "version_id": "58a852c6-8f3f-440d-97e3-fd8ebe1c91f6"}]}, "item_language": {"attribute_name": "言語", "attribute_value_mlt": [{"subitem_language": "eng"}]}, "item_resource_type": {"attribute_name": "資源タイプ", "attribute_value_mlt": [{"resourcetype": "journal article", "resourceuri": "http://purl.org/coar/resource_type/c_6501"}]}, "item_title": "Synthesis, properties, and crystal structures of π-extended double [6]helicenes: contorted multi-dimensional stacking lattice", "item_titles": {"attribute_name": "タイトル", "attribute_value_mlt": [{"subitem_title": "Synthesis, properties, and crystal structures of π-extended double [6]helicenes: contorted multi-dimensional stacking lattice", "subitem_title_language": "en"}]}, "item_type_id": "10", "owner": "1", "path": ["696"], "permalink_uri": "http://hdl.handle.net/2237/26952", "pubdate": {"attribute_name": "PubDate", "attribute_value": "2017-09-05"}, "publish_date": "2017-09-05", "publish_status": "0", "recid": "24730", "relation": {}, "relation_version_is_last": true, "title": ["Synthesis, properties, and crystal structures of π-extended double [6]helicenes: contorted multi-dimensional stacking lattice"], "weko_shared_id": -1}