{"created":"2021-03-01T06:32:42.282655+00:00","id":24730,"links":{},"metadata":{"_buckets":{"deposit":"fd208de9-f1a3-484f-a6cd-9665dc7fabde"},"_deposit":{"id":"24730","owners":[],"pid":{"revision_id":0,"type":"depid","value":"24730"},"status":"published"},"_oai":{"id":"oai:nagoya.repo.nii.ac.jp:00024730","sets":["336:695:696"]},"author_link":["73397","73398","73399","73400","73401","73402"],"item_10_biblio_info_6":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2017-06-07","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"21","bibliographicPageEnd":"4703","bibliographicPageStart":"4697","bibliographicVolumeNumber":"15","bibliographic_titles":[{"bibliographic_title":"Organic & Biomolecular Chemistry","bibliographic_titleLang":"en"}]}]},"item_10_description_4":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"The synthesis and properties of a new π-extended double [6]helicene 2 and a dithia[6]helicene 3 are described. Compared to the previously reported parent double-helicene molecule 1, the introduction of n-butyl groups successfully improved the solubility, which allowed an experimental investigation into the electronic structure of 2 and 3 by photophysical measurements and cyclic voltammetry. The characteristic two-blade propeller structures of 2 and 3 were unambiguously determined by single-crystal X-ray diffraction analysis. The crystal packing structure of 2 exhibited a contorted two-dimensional stacking, whereby molecules of n-pentane were incorporated in the stacks. Despite the presence of n-butyl groups, 3 formed a unique three-dimensional stacking lattice in the crystal. Time-resolved microwave conductivity measurements revealed that the double helicenes (1–3) exhibited transient conductivities. An organic field-effect transistor fabricated using 3 was found to function as a p-type transistor.","subitem_description_language":"en","subitem_description_type":"Abstract"}]},"item_10_identifier_60":{"attribute_name":"URI","attribute_value_mlt":[{"subitem_identifier_type":"DOI","subitem_identifier_uri":"http://doi.org/10.1039/C7OB00987A"},{"subitem_identifier_type":"HDL","subitem_identifier_uri":"http://hdl.handle.net/2237/26952"}]},"item_10_publisher_32":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"Royal Society of Chemistry","subitem_publisher_language":"en"}]},"item_10_relation_11":{"attribute_name":"DOI","attribute_value_mlt":[{"subitem_relation_type":"isVersionOf","subitem_relation_type_id":{"subitem_relation_type_id_text":"https://doi.org/10.1039/C7OB00987A","subitem_relation_type_select":"DOI"}}]},"item_10_select_15":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_select_item":"author"}]},"item_10_source_id_7":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"1477-0520","subitem_source_identifier_type":"PISSN"}]},"item_1615787544753":{"attribute_name":"出版タイプ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_ab4af688f83e57aa","subitem_version_type":"AM"}]},"item_access_right":{"attribute_name":"アクセス権","attribute_value_mlt":[{"subitem_access_right":"open access","subitem_access_right_uri":"http://purl.org/coar/access_right/c_abf2"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Fujikawa, Takao","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"73397","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Mitoma, Nobuhiko","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"73398","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Wakamiya, Atsushi","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"73399","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Saeki, Akinori","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"73400","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Segawa, Yasutomo","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"73401","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Itami, Kenichiro","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"73402","nameIdentifierScheme":"WEKO"}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2018-06-07"}],"displaytype":"detail","filename":"Fujikawa_OBC.pdf","filesize":[{"value":"4.2 MB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"Fujikawa_OBC.pdf ファイル公開：2018/06/07","objectType":"fulltext","url":"https://nagoya.repo.nii.ac.jp/record/24730/files/Fujikawa_OBC.pdf"},"version_id":"58a852c6-8f3f-440d-97e3-fd8ebe1c91f6"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Synthesis, properties, and crystal structures of π-extended double [6]helicenes: contorted multi-dimensional stacking lattice","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Synthesis, properties, and crystal structures of π-extended double [6]helicenes: contorted multi-dimensional stacking lattice","subitem_title_language":"en"}]},"item_type_id":"10","owner":"1","path":["696"],"pubdate":{"attribute_name":"PubDate","attribute_value":"2017-09-05"},"publish_date":"2017-09-05","publish_status":"0","recid":"24730","relation_version_is_last":true,"title":["Synthesis, properties, and crystal structures of π-extended double [6]helicenes: contorted multi-dimensional stacking lattice"],"weko_creator_id":"1","weko_shared_id":-1},"updated":"2023-01-16T04:15:12.909357+00:00"}