@article{oai:nagoya.repo.nii.ac.jp:00024762,
 author = {Omori, Hiroto and Hiroto, Satoru and Shinokubo, Hiroshi},
 issue = {33},
 journal = {CHEMISTRY-A EUROPEAN JOURNAL},
 month = {Jun},
 note = {10-Silacorroles were obtained from the Pd-catalyzed silylative cyclization of a bis(α,α′-dibromodipyrrin) Ni^II precursor with dihydrosilanes. These 10-silacorroles show substantially red-shifted absorption bands relative to those of normal porphyrins and isocorroles. Notably, the corresponding free base and Zn^II 10-silacorroles exhibit emissions in the NIR region. Theoretical calculations on these 10-silacorroles revealed the presence of σ*–π* conjugation between the silyl group and the tetrapyrrole π system, which significantly lowers their LUMO energy levels.},
 pages = {7866--7870},
 title = {10-Silacorroles Exhibiting NIR Absorption and Emission},
 volume = {22},
 year = {2017}
}