{"created":"2021-03-01T06:32:44.421615+00:00","id":24762,"links":{},"metadata":{"_buckets":{"deposit":"5106cd4e-74a5-493b-b605-f24b09adfa3f"},"_deposit":{"id":"24762","owners":[],"pid":{"revision_id":0,"type":"depid","value":"24762"},"status":"published"},"_oai":{"id":"oai:nagoya.repo.nii.ac.jp:00024762","sets":["320:321:322"]},"author_link":["73598","73599","73600"],"item_10_biblio_info_6":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2017-06-12","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"33","bibliographicPageEnd":"7870","bibliographicPageStart":"7866","bibliographicVolumeNumber":"22","bibliographic_titles":[{"bibliographic_title":"CHEMISTRY-A EUROPEAN JOURNAL","bibliographic_titleLang":"en"}]}]},"item_10_description_4":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"10-Silacorroles were obtained from the Pd-catalyzed silylative cyclization of a bis(α,α′-dibromodipyrrin) Ni^II precursor with dihydrosilanes. These 10-silacorroles show substantially red-shifted absorption bands relative to those of normal porphyrins and isocorroles. Notably, the corresponding free base and Zn^II 10-silacorroles exhibit emissions in the NIR region. Theoretical calculations on these 10-silacorroles revealed the presence of σ*–π* conjugation between the silyl group and the tetrapyrrole π system, which significantly lowers their LUMO energy levels.","subitem_description_language":"en","subitem_description_type":"Abstract"}]},"item_10_identifier_60":{"attribute_name":"URI","attribute_value_mlt":[{"subitem_identifier_type":"DOI","subitem_identifier_uri":"http://doi.org/10.1002/chem.201701474"},{"subitem_identifier_type":"HDL","subitem_identifier_uri":"http://hdl.handle.net/2237/26985"}]},"item_10_publisher_32":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"Wiley","subitem_publisher_language":"en"}]},"item_10_relation_11":{"attribute_name":"DOI","attribute_value_mlt":[{"subitem_relation_type":"isVersionOf","subitem_relation_type_id":{"subitem_relation_type_id_text":"https://doi.org/10.1002/chem.201701474","subitem_relation_type_select":"DOI"}}]},"item_10_rights_12":{"attribute_name":"権利","attribute_value_mlt":[{"subitem_rights":"This is the peer reviewed version of the following article: [H.Omori,S.Hiroto, H.Shinokubo,Chem. Eur. J. 2017, 23, 7866.], which has been published in final form at [http://doi.org/10.1002/chem.201701474]. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Self-Archiving.","subitem_rights_language":"en"}]},"item_10_select_15":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_select_item":"author"}]},"item_10_source_id_7":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"0947-6539","subitem_source_identifier_type":"PISSN"}]},"item_1615787544753":{"attribute_name":"出版タイプ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_ab4af688f83e57aa","subitem_version_type":"AM"}]},"item_access_right":{"attribute_name":"アクセス権","attribute_value_mlt":[{"subitem_access_right":"open access","subitem_access_right_uri":"http://purl.org/coar/access_right/c_abf2"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Omori, Hiroto","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"73598","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Hiroto, Satoru","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"73599","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Shinokubo, Hiroshi","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"73600","nameIdentifierScheme":"WEKO"}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2018-06-12"}],"displaytype":"detail","filename":"CEJ_170424HO_rev.pdf","filesize":[{"value":"2.1 MB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"CEJ_170424HO_rev.pdf ファイル公開:2018/06/12","objectType":"fulltext","url":"https://nagoya.repo.nii.ac.jp/record/24762/files/CEJ_170424HO_rev.pdf"},"version_id":"7a25677c-d1b1-4dbc-a7f4-752c359d307b"}]},"item_keyword":{"attribute_name":"キーワード","attribute_value_mlt":[{"subitem_subject":"10-heterocorroles","subitem_subject_scheme":"Other"},{"subitem_subject":"dyes/pigments","subitem_subject_scheme":"Other"},{"subitem_subject":"silicon","subitem_subject_scheme":"Other"},{"subitem_subject":"porphyrinoids","subitem_subject_scheme":"Other"},{"subitem_subject":"NIR emission","subitem_subject_scheme":"Other"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"10-Silacorroles Exhibiting NIR Absorption and Emission","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"10-Silacorroles Exhibiting NIR Absorption and Emission","subitem_title_language":"en"}]},"item_type_id":"10","owner":"1","path":["322"],"pubdate":{"attribute_name":"PubDate","attribute_value":"2017-10-04"},"publish_date":"2017-10-04","publish_status":"0","recid":"24762","relation_version_is_last":true,"title":["10-Silacorroles Exhibiting NIR Absorption and Emission"],"weko_creator_id":"1","weko_shared_id":-1},"updated":"2023-01-16T04:14:10.592674+00:00"}