{"_buckets": {"deposit": "c4fa2d82-d745-4886-891f-778e12a0d645"}, "_deposit": {"id": "24770", "owners": [], "pid": {"revision_id": 0, "type": "depid", "value": "24770"}, "status": "published"}, "_oai": {"id": "oai:nagoya.repo.nii.ac.jp:00024770"}, "item_10_biblio_info_6": {"attribute_name": "\u66f8\u8a8c\u60c5\u5831", "attribute_value_mlt": [{"bibliographicIssueDates": {"bibliographicIssueDate": "2017-07-07", "bibliographicIssueDateType": "Issued"}, "bibliographicIssueNumber": "13", "bibliographicPageEnd": "2462", "bibliographicPageStart": "2457", "bibliographicVolumeNumber": "9", "bibliographic_titles": [{"bibliographic_title": "ChemCatChem"}]}]}, "item_10_description_4": {"attribute_name": "\u6284\u9332", "attribute_value_mlt": [{"subitem_description": "A long-tethered boron-containing (P-B-P) pincer ligand with an aliphatic backbone was synthesized. Oxidative addition of the B\u2212H bond in the ligand to [Ir(coe)2Cl]2 (coe=cyclooctene) afforded the (P-B-P)Ir(H)Cl complex. A catalyst system comprising the iridium complex and KOtBu showed excellent performance in the dehydrocoupling of N,N-dimethylamine\u2013borane (DMAB), releasing 1\u2005equivalent of dihydrogen gas from a concentrated solution of DMAB at a low catalyst loading of 0.05\u2005mol\u2009% and with an initial turnover frequency of approximately 3400h^\u22121. The dihydride (P-B-P)Ir(H)2 complex also catalyzed the dehydrogenation of DMAB and was postulated as one of the intermediates in the catalytic cycle.", "subitem_description_type": "Abstract"}]}, "item_10_identifier_60": {"attribute_name": "URI", "attribute_value_mlt": [{"subitem_identifier_type": "DOI", "subitem_identifier_uri": "http://doi.org/10.1002/cctc.201700384"}, {"subitem_identifier_type": "HDL", "subitem_identifier_uri": "http://hdl.handle.net/2237/26992"}]}, "item_10_publisher_32": {"attribute_name": "\u51fa\u7248\u8005", "attribute_value_mlt": [{"subitem_publisher": "Wiley"}]}, "item_10_rights_12": {"attribute_name": "\u6a29\u5229", "attribute_value_mlt": [{"subitem_rights": "\"This is the peer reviewed version of the following article: [E. H. Kwan, H. Ogawa, M. Yamashita, ChemCatChem 2017, 9, 2457.], which has been published in final form at [http://doi.org/10.1002/cctc.201700384]. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Self-Archiving.\""}]}, "item_10_select_15": {"attribute_name": "\u8457\u8005\u7248\u30d5\u30e9\u30b0", "attribute_value_mlt": [{"subitem_select_item": "author"}]}, "item_10_source_id_7": {"attribute_name": "ISSN", "attribute_value_mlt": [{"subitem_source_identifier": "1867-3880", "subitem_source_identifier_type": "ISSN"}]}, "item_creator": {"attribute_name": "\u8457\u8005", "attribute_type": "creator", "attribute_value_mlt": [{"creatorNames": [{"creatorName": "Kwan, Enrique Huang"}], "nameIdentifiers": [{"nameIdentifier": "73622", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Ogawa, Hayato"}], "nameIdentifiers": [{"nameIdentifier": "73623", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Yamashita, Makoto"}], "nameIdentifiers": [{"nameIdentifier": "73624", "nameIdentifierScheme": "WEKO"}]}]}, "item_files": {"attribute_name": "\u30d5\u30a1\u30a4\u30eb\u60c5\u5831", "attribute_type": "file", "attribute_value_mlt": [{"accessrole": "open_date", "date": [{"dateType": "Available", "dateValue": "2018-07-07"}], "displaytype": "detail", "download_preview_message": "", "file_order": 0, "filename": "Text_28Feb2017.pdf", "filesize": [{"value": "743.1 kB"}], "format": "application/pdf", "future_date_message": "", "is_thumbnail": false, "licensetype": "license_free", "mimetype": "application/pdf", "size": 743100.0, "url": {"label": "Text_28Feb2017.pdf \u30d5\u30a1\u30a4\u30eb\u516c\u958b\uff1a2018/07/07", "url": "https://nagoya.repo.nii.ac.jp/record/24770/files/Text_28Feb2017.pdf"}, "version_id": "2e4d5efc-d366-4e2f-8495-9f7e59eae95c"}]}, "item_language": {"attribute_name": "\u8a00\u8a9e", "attribute_value_mlt": [{"subitem_language": "eng"}]}, "item_resource_type": {"attribute_name": "\u8cc7\u6e90\u30bf\u30a4\u30d7", "attribute_value_mlt": [{"resourcetype": "journal article", "resourceuri": "http://purl.org/coar/resource_type/c_6501"}]}, "item_title": "A Highly Active PBP-Iridium Catalyst for the Dehydrogenation of Dimethylamine-Borane: Catalytic Performance and Mechanism", "item_titles": {"attribute_name": "\u30bf\u30a4\u30c8\u30eb", "attribute_value_mlt": [{"subitem_title": "A Highly Active PBP-Iridium Catalyst for the Dehydrogenation of Dimethylamine-Borane: Catalytic Performance and Mechanism"}]}, "item_type_id": "10", "owner": "1", "path": ["320/321/322"], "permalink_uri": "http://hdl.handle.net/2237/26992", "pubdate": {"attribute_name": "\u516c\u958b\u65e5", "attribute_name_i18n": "\u516c\u958b\u65e5", "attribute_value": "2017-10-05"}, "publish_date": "2017-10-05", "publish_status": "0", "recid": "24770", "relation": {}, "relation_version_is_last": true, "title": ["A Highly Active PBP-Iridium Catalyst for the Dehydrogenation of Dimethylamine-Borane: Catalytic Performance and Mechanism"], "weko_shared_id": null}