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  1. B200 工学部/工学研究科
  2. B200a 雑誌掲載論文
  3. 学術雑誌

A Highly Active PBP-Iridium Catalyst for the Dehydrogenation of Dimethylamine-Borane: Catalytic Performance and Mechanism

http://hdl.handle.net/2237/26992
http://hdl.handle.net/2237/26992
2e4b35a2-214f-4b38-b6a2-5a50881cb23a
名前 / ファイル ライセンス アクション
Text_28Feb2017.pdf Text_28Feb2017.pdf ファイル公開:2018/07/07 (743.1 kB)
Item type 学術雑誌論文 / Journal Article(1)
公開日 2017-10-05
タイトル
タイトル A Highly Active PBP-Iridium Catalyst for the Dehydrogenation of Dimethylamine-Borane: Catalytic Performance and Mechanism
言語 en
著者 Kwan, Enrique Huang

× Kwan, Enrique Huang

WEKO 73622

en Kwan, Enrique Huang

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Ogawa, Hayato

× Ogawa, Hayato

WEKO 73623

en Ogawa, Hayato

Search repository
Yamashita, Makoto

× Yamashita, Makoto

WEKO 73624

en Yamashita, Makoto

Search repository
アクセス権
アクセス権 open access
アクセス権URI http://purl.org/coar/access_right/c_abf2
権利
言語 en
権利情報 This is the peer reviewed version of the following article: [E. H. Kwan, H. Ogawa, M. Yamashita, ChemCatChem 2017, 9, 2457.], which has been published in final form at [http://doi.org/10.1002/cctc.201700384]. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Self-Archiving.
抄録
内容記述 A long-tethered boron-containing (P-B-P) pincer ligand with an aliphatic backbone was synthesized. Oxidative addition of the B−H bond in the ligand to [Ir(coe)2Cl]2 (coe=cyclooctene) afforded the (P-B-P)Ir(H)Cl complex. A catalyst system comprising the iridium complex and KOtBu showed excellent performance in the dehydrocoupling of N,N-dimethylamine–borane (DMAB), releasing 1 equivalent of dihydrogen gas from a concentrated solution of DMAB at a low catalyst loading of 0.05 mol % and with an initial turnover frequency of approximately 3400h^−1. The dihydride (P-B-P)Ir(H)2 complex also catalyzed the dehydrogenation of DMAB and was postulated as one of the intermediates in the catalytic cycle.
言語 en
内容記述タイプ Abstract
出版者
言語 en
出版者 Wiley
言語
言語 eng
資源タイプ
資源タイプresource http://purl.org/coar/resource_type/c_6501
タイプ journal article
出版タイプ
出版タイプ AM
出版タイプResource http://purl.org/coar/version/c_ab4af688f83e57aa
DOI
関連タイプ isVersionOf
識別子タイプ DOI
関連識別子 https://doi.org/10.1002/cctc.201700384
ISSN
収録物識別子タイプ PISSN
収録物識別子 1867-3880
書誌情報 en : ChemCatChem

巻 9, 号 13, p. 2457-2462, 発行日 2017-07-07
著者版フラグ
値 author
URI
識別子 http://doi.org/10.1002/cctc.201700384
識別子タイプ DOI
URI
識別子 http://hdl.handle.net/2237/26992
識別子タイプ HDL
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