{"_buckets": {"deposit": "99dd07ab-9071-4bad-9a86-0d2871a081bb"}, "_deposit": {"id": "24887", "owners": [], "pid": {"revision_id": 0, "type": "depid", "value": "24887"}, "status": "published"}, "_oai": {"id": "oai:nagoya.repo.nii.ac.jp:00024887", "sets": ["322"]}, "author_link": ["74037", "74038", "74039", "74040", "74041"], "item_10_biblio_info_6": {"attribute_name": "書誌情報", "attribute_value_mlt": [{"bibliographicIssueDates": {"bibliographicIssueDate": "2017-07-25", "bibliographicIssueDateType": "Issued"}, "bibliographicIssueNumber": "14", "bibliographicPageEnd": "6129", "bibliographicPageStart": "6122", "bibliographicVolumeNumber": "29", "bibliographic_titles": [{"bibliographic_title": "Chemistry of Materials", "bibliographic_titleLang": "en"}]}]}, "item_10_description_4": {"attribute_name": "抄録", "attribute_value_mlt": [{"subitem_description": "Light-emitting electrochemical cells (LECs) are composed of blends of semiconducting polymers and electrolytes, in which a unique cooperative action of ions and electrons induces a dynamic p–n junction for efficient emission. One of the crucial issues remaining in LECs is uniformity in blends of polymer and electrolyte; phase separation in between the two components results in poor performance or failure of operation. Here, we overcome this issue by developing an ionic liquid-based electrolyte of alkylphosphonium-phosphate that shows notable compatibility high enough to dissolve even light-emitting polymers. This exceptional compatibility enabled us to prepare uniform film blends with various blue to red emitting polymers, and offered bright and efficient LECs. Especially, a blue-emitting LEC showed excellent performance: the luminance reached ∼20 000 cd m^–2 with a high luminance efficiency of ∼5 cd A^–1, of which performances significantly exceed a light-emitting diode using the same polymer. The ionic liquid was further applied to the LECs with state-of-the-art light-emitting dendrimers showing thermally activated delayed fluorescence under electrical excitation, giving a high efficiency of 11 cd A^–1. These demonstrations remind us of the great importance of the polymer–electrolyte compatibility and the usefulness of ILs for electrolyte of LECs.", "subitem_description_language": "en", "subitem_description_type": "Abstract"}]}, "item_10_identifier_60": {"attribute_name": "URI", "attribute_value_mlt": [{"subitem_identifier_type": "DOI", "subitem_identifier_uri": "http://doi.org/10.1021/acs.chemmater.7b02128"}, {"subitem_identifier_type": "HDL", "subitem_identifier_uri": "http://hdl.handle.net/2237/27107"}]}, "item_10_publisher_32": {"attribute_name": "出版者", "attribute_value_mlt": [{"subitem_publisher": "ACS Publications", "subitem_publisher_language": "en"}]}, "item_10_relation_11": {"attribute_name": "DOI", "attribute_value_mlt": [{"subitem_relation_type": "isVersionOf", "subitem_relation_type_id": {"subitem_relation_type_id_text": "https://doi.org/10.1021/acs.chemmater.7b02128", "subitem_relation_type_select": "DOI"}}]}, "item_10_rights_12": {"attribute_name": "権利", "attribute_value_mlt": [{"subitem_rights": "“This document is the Accepted Manuscript version of a Published Work that appeared in final form in [Chemistry of Materials], copyright © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see[http://pubs.acs.org/articlesonrequest/AOR-YSXj7a26XAutfmbnqFKZ].”", "subitem_rights_language": "en"}]}, "item_10_select_15": {"attribute_name": "著者版フラグ", "attribute_value_mlt": [{"subitem_select_item": "author"}]}, "item_10_source_id_7": {"attribute_name": "ISSN", "attribute_value_mlt": [{"subitem_source_identifier": "0897-4756", "subitem_source_identifier_type": "PISSN"}]}, "item_1615787544753": {"attribute_name": "出版タイプ", "attribute_value_mlt": [{"subitem_version_resource": "http://purl.org/coar/version/c_ab4af688f83e57aa", "subitem_version_type": "AM"}]}, "item_access_right": {"attribute_name": "アクセス権", "attribute_value_mlt": [{"subitem_access_right": "open access", "subitem_access_right_uri": "http://purl.org/coar/access_right/c_abf2"}]}, "item_creator": {"attribute_name": "著者", "attribute_type": "creator", "attribute_value_mlt": [{"creatorNames": [{"creatorName": "Sakanoue, Tomo", "creatorNameLang": "en"}], "nameIdentifiers": [{"nameIdentifier": "74037", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Yonekawa, Fumihiro", "creatorNameLang": "en"}], "nameIdentifiers": [{"nameIdentifier": "74038", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Albrecht, Ken", "creatorNameLang": "en"}], "nameIdentifiers": [{"nameIdentifier": "74039", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Yamamoto, Kimihisa", "creatorNameLang": "en"}], "nameIdentifiers": [{"nameIdentifier": "74040", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Takenobu, Taishi", "creatorNameLang": "en"}], "nameIdentifiers": [{"nameIdentifier": "74041", "nameIdentifierScheme": "WEKO"}]}]}, "item_files": {"attribute_name": "ファイル情報", "attribute_type": "file", "attribute_value_mlt": [{"accessrole": "open_date", "date": [{"dateType": "Available", "dateValue": "2018-07-25"}], "displaytype": "detail", "download_preview_message": "", "file_order": 0, "filename": "manuscript_revised.pdf", "filesize": [{"value": "4.7 MB"}], "format": "application/pdf", "future_date_message": "", "is_thumbnail": false, "licensetype": "license_note", "mimetype": "application/pdf", "size": 4700000.0, "url": {"label": "manuscript_revised.pdf ファイル公開日:2017/07/25", "objectType": "fulltext", "url": "https://nagoya.repo.nii.ac.jp/record/24887/files/manuscript_revised.pdf"}, "version_id": "c5df7fa2-99c8-403e-883d-dca77328fa5f"}]}, "item_language": {"attribute_name": "言語", "attribute_value_mlt": [{"subitem_language": "eng"}]}, "item_resource_type": {"attribute_name": "資源タイプ", "attribute_value_mlt": [{"resourcetype": "journal article", "resourceuri": "http://purl.org/coar/resource_type/c_6501"}]}, "item_title": "An ionic liquid that dissolves semiconducting polymers: a Promising Electrolyte for Bright, Efficient, and Stable Light-Emitting Electrochemical Cells", "item_titles": {"attribute_name": "タイトル", "attribute_value_mlt": [{"subitem_title": "An ionic liquid that dissolves semiconducting polymers: a Promising Electrolyte for Bright, Efficient, and Stable Light-Emitting Electrochemical Cells", "subitem_title_language": "en"}]}, "item_type_id": "10", "owner": "1", "path": ["322"], "permalink_uri": "http://hdl.handle.net/2237/27107", "pubdate": {"attribute_name": "PubDate", "attribute_value": "2017-11-19"}, "publish_date": "2017-11-19", "publish_status": "0", "recid": "24887", "relation": {}, "relation_version_is_last": true, "title": ["An ionic liquid that dissolves semiconducting polymers: a Promising Electrolyte for Bright, Efficient, and Stable Light-Emitting Electrochemical Cells"], "weko_shared_id": -1}