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  1. B100 理学部/理学研究科
  2. B100a 雑誌掲載論文
  3. 学術雑誌

Synthesis and Characterization of Bioinspired [Mo2Fe2]–Hydride Cluster Complexes and Their Application in the Catalytic Silylation of N2

http://hdl.handle.net/2237/27236
http://hdl.handle.net/2237/27236
7475b40d-0a3a-4547-b0cd-81d89cc119d3
名前 / ファイル ライセンス アクション
manuscript.pdf manuscript.pdf ファイル公開日:2018/09/21 (1.9 MB)
Item type 学術雑誌論文 / Journal Article(1)
公開日 2018-01-09
タイトル
タイトル Synthesis and Characterization of Bioinspired [Mo2Fe2]–Hydride Cluster Complexes and Their Application in the Catalytic Silylation of N2
言語 en
著者 Ohki, Yasuhiro

× Ohki, Yasuhiro

WEKO 74520

en Ohki, Yasuhiro

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Araki, Yuna

× Araki, Yuna

WEKO 74521

en Araki, Yuna

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Tada, Mizuki

× Tada, Mizuki

WEKO 74522

en Tada, Mizuki

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Sakai, Yoichi

× Sakai, Yoichi

WEKO 74523

en Sakai, Yoichi

Search repository
アクセス権
アクセス権 open access
アクセス権URI http://purl.org/coar/access_right/c_abf2
権利
言語 en
権利情報 This is the peer reviewed version of the following article: [Ohki, Y; Araki, Y; Tada, M; Sakai, Y. (2017), Synthesis and Characterization of Bioinspired [Mo2Fe2]-Hydride Cluster Complexes and Their Application in the Catalytic Silylation of N-2. CHEMISTRY-A EUROPEAN JOURNAL, 2017: 13240–13248], which has been published in final form at [http://doi.org/10.1002/chem.201702925]. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Self-Archiving.
キーワード
主題Scheme Other
主題 Mo
キーワード
主題Scheme Other
主題 Fe
キーワード
主題Scheme Other
主題 Hydride
キーワード
主題Scheme Other
主題 Clusters
キーワード
主題Scheme Other
主題 N2 reduction
抄録
内容記述 The hydride-supported [Mo2Fe2] cluster complex {Cp*Mo(PMe3)}2{FeN(SiMe3)2}2(H)8 (2 a; Cp*=η^5-C5Me5) and its [Mo2Mn2] congener 2 b were synthesized from the reactions of Cp*Mo(PMe3)(H)5 (1) with M{N(SiMe3)2}2 (M=Fe, Mn). The amide-to-thiolate ligand-exchange reactions of complex 2 a with bulky thiol reagents (HSR; R=2,4,6-iPr3C6H2 (Tip), 2,6-(SiMe3)2C6H3 (Btp)) furnished the corresponding hydride-supported [Mo2Fe2](SR)2 cluster complexes. The [Mo2Fe2] clusters served as catalyst precursors for the reductive silylation of N2 and yielded ≈65–69 equivalents of N(SiMe3)3 relative to the [Mo2Fe2] clusters. Treatment of complexes 2 a and b with an excess of CNtBu resulted in the formation of dinuclear Mo−Fe and Mo−Mn complexes, which indicated that the [Mo2M2] cores (M=Fe, Mn) split into two dinuclear species upon accommodation of substrates.
言語 en
内容記述タイプ Abstract
出版者
言語 en
出版者 Wiley
言語
言語 eng
資源タイプ
資源タイプresource http://purl.org/coar/resource_type/c_6501
タイプ journal article
出版タイプ
出版タイプ AM
出版タイプResource http://purl.org/coar/version/c_ab4af688f83e57aa
DOI
関連タイプ isVersionOf
識別子タイプ DOI
関連識別子 https://doi.org/10.1002/chem.201702925
ISSN
収録物識別子タイプ PISSN
収録物識別子 0947-6539
書誌情報 en : CHEMISTRY-A EUROPEAN JOURNAL

巻 23, 号 53, p. 13240-13248, 発行日 2017-09-21
著者版フラグ
値 author
URI
識別子 http://doi.org/10.1002/chem.201702925
識別子タイプ DOI
URI
識別子 http://hdl.handle.net/2237/27236
識別子タイプ HDL
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