{"_buckets": {"deposit": "828003b8-ec02-44d3-9bd3-14a10f7438f6"}, "_deposit": {"id": "25012", "owners": [], "pid": {"revision_id": 0, "type": "depid", "value": "25012"}, "status": "published"}, "_oai": {"id": "oai:nagoya.repo.nii.ac.jp:00025012"}, "item_10_biblio_info_6": {"attribute_name": "\u66f8\u8a8c\u60c5\u5831", "attribute_value_mlt": [{"bibliographicIssueDates": {"bibliographicIssueDate": "2017-09-21", "bibliographicIssueDateType": "Issued"}, "bibliographicIssueNumber": "53", "bibliographicPageEnd": "13248", "bibliographicPageStart": "13240", "bibliographicVolumeNumber": "23", "bibliographic_titles": [{"bibliographic_title": "CHEMISTRY-A EUROPEAN JOURNAL"}]}]}, "item_10_description_4": {"attribute_name": "\u6284\u9332", "attribute_value_mlt": [{"subitem_description": "The hydride-supported [Mo2Fe2] cluster complex {Cp*Mo(PMe3)}2{FeN(SiMe3)2}2(H)8 (2\u2009a; Cp*=\u03b7^5-C5Me5) and its [Mo2Mn2] congener 2\u2009b were synthesized from the reactions of Cp*Mo(PMe3)(H)5 (1) with M{N(SiMe3)2}2 (M=Fe, Mn). The amide-to-thiolate ligand-exchange reactions of complex 2\u2009a with bulky thiol reagents (HSR; R=2,4,6-iPr3C6H2 (Tip), 2,6-(SiMe3)2C6H3 (Btp)) furnished the corresponding hydride-supported [Mo2Fe2](SR)2 cluster complexes. The [Mo2Fe2] clusters served as catalyst precursors for the reductive silylation of N2 and yielded \u224865\u201369\u2005equivalents of N(SiMe3)3 relative to the [Mo2Fe2] clusters. Treatment of complexes 2\u2009a and b with an excess of CNtBu resulted in the formation of dinuclear Mo\u2212Fe and Mo\u2212Mn complexes, which indicated that the [Mo2M2] cores (M=Fe, Mn) split into two dinuclear species upon accommodation of substrates.", "subitem_description_type": "Abstract"}]}, "item_10_identifier_60": {"attribute_name": "URI", "attribute_value_mlt": [{"subitem_identifier_type": "DOI", "subitem_identifier_uri": "http://doi.org/10.1002/chem.201702925"}, {"subitem_identifier_type": "HDL", "subitem_identifier_uri": "http://hdl.handle.net/2237/27236"}]}, "item_10_publisher_32": {"attribute_name": "\u51fa\u7248\u8005", "attribute_value_mlt": [{"subitem_publisher": "Wiley"}]}, "item_10_rights_12": {"attribute_name": "\u6a29\u5229", "attribute_value_mlt": [{"subitem_rights": "This is the peer reviewed version of the following article: [Ohki, Y; Araki, Y; Tada, M; Sakai, Y. (2017), Synthesis and Characterization of Bioinspired [Mo2Fe2]-Hydride Cluster Complexes and Their Application in the Catalytic Silylation of N-2. CHEMISTRY-A EUROPEAN JOURNAL, 2017: 13240\u201313248], which has been published in final form at [http://doi.org/10.1002/chem.201702925]. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Self-Archiving."}]}, "item_10_select_15": {"attribute_name": "\u8457\u8005\u7248\u30d5\u30e9\u30b0", "attribute_value_mlt": [{"subitem_select_item": "author"}]}, "item_10_source_id_7": {"attribute_name": "ISSN", "attribute_value_mlt": [{"subitem_source_identifier": "0947-6539", "subitem_source_identifier_type": "ISSN"}]}, "item_creator": {"attribute_name": "\u8457\u8005", "attribute_type": "creator", "attribute_value_mlt": [{"creatorNames": [{"creatorName": "Ohki, Yasuhiro"}], "nameIdentifiers": [{"nameIdentifier": "74520", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Araki, Yuna"}], "nameIdentifiers": [{"nameIdentifier": "74521", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Tada, Mizuki"}], "nameIdentifiers": [{"nameIdentifier": "74522", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Sakai, Yoichi"}], "nameIdentifiers": [{"nameIdentifier": "74523", "nameIdentifierScheme": "WEKO"}]}]}, "item_files": {"attribute_name": "\u30d5\u30a1\u30a4\u30eb\u60c5\u5831", "attribute_type": "file", "attribute_value_mlt": [{"accessrole": "open_date", "date": [{"dateType": "Available", "dateValue": "2018-09-21"}], "displaytype": "detail", "download_preview_message": "", "file_order": 0, "filename": "manuscript.pdf", "filesize": [{"value": "1.9 MB"}], "format": "application/pdf", "future_date_message": "", "is_thumbnail": false, "licensetype": "license_free", "mimetype": "application/pdf", "size": 1900000.0, "url": {"label": "manuscript.pdf \u30d5\u30a1\u30a4\u30eb\u516c\u958b\u65e5:2018/09/21", "url": "https://nagoya.repo.nii.ac.jp/record/25012/files/manuscript.pdf"}, "version_id": "4da9eaa7-6d81-4246-9c86-181582380711"}]}, "item_keyword": {"attribute_name": "\u30ad\u30fc\u30ef\u30fc\u30c9", "attribute_value_mlt": [{"subitem_subject": "Mo", "subitem_subject_scheme": "Other"}, {"subitem_subject": "Fe", "subitem_subject_scheme": "Other"}, {"subitem_subject": "Hydride", "subitem_subject_scheme": "Other"}, {"subitem_subject": "Clusters", "subitem_subject_scheme": "Other"}, {"subitem_subject": "N2 reduction", "subitem_subject_scheme": "Other"}]}, "item_language": {"attribute_name": "\u8a00\u8a9e", "attribute_value_mlt": [{"subitem_language": "eng"}]}, "item_resource_type": {"attribute_name": "\u8cc7\u6e90\u30bf\u30a4\u30d7", "attribute_value_mlt": [{"resourcetype": "journal article", "resourceuri": "http://purl.org/coar/resource_type/c_6501"}]}, "item_title": "Synthesis and Characterization of Bioinspired [Mo2Fe2]\u2013Hydride Cluster Complexes and Their Application in the Catalytic Silylation of N2", "item_titles": {"attribute_name": "\u30bf\u30a4\u30c8\u30eb", "attribute_value_mlt": [{"subitem_title": "Synthesis and Characterization of Bioinspired [Mo2Fe2]\u2013Hydride Cluster Complexes and Their Application in the Catalytic Silylation of N2"}]}, "item_type_id": "10", "owner": "1", "path": ["336/695/696"], "permalink_uri": "http://hdl.handle.net/2237/27236", "pubdate": {"attribute_name": "\u516c\u958b\u65e5", "attribute_value": "2018-01-09"}, "publish_date": "2018-01-09", "publish_status": "0", "recid": "25012", "relation": {}, "relation_version_is_last": true, "title": ["Synthesis and Characterization of Bioinspired [Mo2Fe2]\u2013Hydride Cluster Complexes and Their Application in the Catalytic Silylation of N2"], "weko_shared_id": null}