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アイテム
Synthesis and Characterization of Bioinspired [Mo2Fe2]–Hydride Cluster Complexes and Their Application in the Catalytic Silylation of N2
http://hdl.handle.net/2237/27236
http://hdl.handle.net/2237/272367475b40d-0a3a-4547-b0cd-81d89cc119d3
| 名前 / ファイル | ライセンス | アクション |
|---|---|---|
manuscript.pdf ファイル公開日:2018/09/21 (1.9 MB)
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| アイテムタイプ | 学術雑誌論文 / Journal Article(1) | |||||
|---|---|---|---|---|---|---|
| 公開日 | 2018-01-09 | |||||
| タイトル | ||||||
| タイトル | Synthesis and Characterization of Bioinspired [Mo2Fe2]–Hydride Cluster Complexes and Their Application in the Catalytic Silylation of N2 | |||||
| 言語 | en | |||||
| 著者 |
Ohki, Yasuhiro
× Ohki, Yasuhiro× Araki, Yuna× Tada, Mizuki× Sakai, Yoichi |
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| アクセス権 | ||||||
| アクセス権 | open access | |||||
| アクセス権URI | http://purl.org/coar/access_right/c_abf2 | |||||
| 権利 | ||||||
| 権利情報 | This is the peer reviewed version of the following article: [Ohki, Y; Araki, Y; Tada, M; Sakai, Y. (2017), Synthesis and Characterization of Bioinspired [Mo2Fe2]-Hydride Cluster Complexes and Their Application in the Catalytic Silylation of N-2. CHEMISTRY-A EUROPEAN JOURNAL, 2017: 13240–13248], which has been published in final form at [http://doi.org/10.1002/chem.201702925]. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Self-Archiving. | |||||
| 言語 | en | |||||
| キーワード | ||||||
| 主題Scheme | Other | |||||
| 主題 | Mo | |||||
| キーワード | ||||||
| 主題Scheme | Other | |||||
| 主題 | Fe | |||||
| キーワード | ||||||
| 主題Scheme | Other | |||||
| 主題 | Hydride | |||||
| キーワード | ||||||
| 主題Scheme | Other | |||||
| 主題 | Clusters | |||||
| キーワード | ||||||
| 主題Scheme | Other | |||||
| 主題 | N2 reduction | |||||
| 抄録 | ||||||
| 内容記述タイプ | Abstract | |||||
| 内容記述 | The hydride-supported [Mo2Fe2] cluster complex {Cp*Mo(PMe3)}2{FeN(SiMe3)2}2(H)8 (2 a; Cp*=η^5-C5Me5) and its [Mo2Mn2] congener 2 b were synthesized from the reactions of Cp*Mo(PMe3)(H)5 (1) with M{N(SiMe3)2}2 (M=Fe, Mn). The amide-to-thiolate ligand-exchange reactions of complex 2 a with bulky thiol reagents (HSR; R=2,4,6-iPr3C6H2 (Tip), 2,6-(SiMe3)2C6H3 (Btp)) furnished the corresponding hydride-supported [Mo2Fe2](SR)2 cluster complexes. The [Mo2Fe2] clusters served as catalyst precursors for the reductive silylation of N2 and yielded ≈65–69 equivalents of N(SiMe3)3 relative to the [Mo2Fe2] clusters. Treatment of complexes 2 a and b with an excess of CNtBu resulted in the formation of dinuclear Mo−Fe and Mo−Mn complexes, which indicated that the [Mo2M2] cores (M=Fe, Mn) split into two dinuclear species upon accommodation of substrates. | |||||
| 言語 | en | |||||
| 出版者 | ||||||
| 出版者 | Wiley | |||||
| 言語 | en | |||||
| 言語 | ||||||
| 言語 | eng | |||||
| 資源タイプ | ||||||
| 資源タイプresource | http://purl.org/coar/resource_type/c_6501 | |||||
| タイプ | journal article | |||||
| 出版タイプ | ||||||
| 出版タイプ | AM | |||||
| 出版タイプResource | http://purl.org/coar/version/c_ab4af688f83e57aa | |||||
| DOI | ||||||
| 関連タイプ | isVersionOf | |||||
| 識別子タイプ | DOI | |||||
| 関連識別子 | https://doi.org/10.1002/chem.201702925 | |||||
| ISSN | ||||||
| 収録物識別子タイプ | PISSN | |||||
| 収録物識別子 | 0947-6539 | |||||
| 書誌情報 |
en : CHEMISTRY-A EUROPEAN JOURNAL 巻 23, 号 53, p. 13240-13248, 発行日 2017-09-21 |
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| 著者版フラグ | ||||||
| 値 | author | |||||
| URI | ||||||
| 識別子 | http://doi.org/10.1002/chem.201702925 | |||||
| 識別子タイプ | DOI | |||||
| URI | ||||||
| 識別子 | http://hdl.handle.net/2237/27236 | |||||
| 識別子タイプ | HDL | |||||
