{"created":"2021-03-01T06:33:08.726294+00:00","id":25138,"links":{},"metadata":{"_buckets":{"deposit":"139de3f9-0ec7-4157-b9bd-21235db8f068"},"_deposit":{"id":"25138","owners":[],"pid":{"revision_id":0,"type":"depid","value":"25138"},"status":"published"},"_oai":{"id":"oai:nagoya.repo.nii.ac.jp:00025138","sets":["336:695:696"]},"author_link":["75017","75018","75019","75020","75021","75022","75023","75024"],"item_10_biblio_info_6":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2017-08-21","bibliographicIssueDateType":"Issued"},"bibliographicPageEnd":"10329","bibliographicPageStart":"10324","bibliographicVolumeNumber":"56","bibliographic_titles":[{"bibliographic_title":"Angewandte Chemie International Edition","bibliographic_titleLang":"en"}]}]},"item_10_description_4":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"The selective hydroxylation of benzene to phenol, without the formation of side products resulting from overoxidation, is catalyzed by cytochrome P450BM3 with the assistance of amino acid derivatives as decoy molecules. The catalytic turnover rate and the total turnover number reached 259 min−1 P450BM3−1 and 40 200 P450BM3−1 when N-heptyl-l-proline modified with l-phenylalanine (C7-l-Pro-l-Phe) was used as the decoy molecule. This work shows that amino acid derivatives with a totally different structure from fatty acids can be used as decoy molecules for aromatic hydroxylation by wild-type P450BM3. This method for non-native substrate hydroxylation by wild-type P450BM3 has the potential to expand the utility of P450BM3 for biotransformations.","subitem_description_language":"en","subitem_description_type":"Abstract"}]},"item_10_identifier_60":{"attribute_name":"URI","attribute_value_mlt":[{"subitem_identifier_type":"DOI","subitem_identifier_uri":"http://doi.org/10.1002/anie.201703461"},{"subitem_identifier_type":"HDL","subitem_identifier_uri":"http://hdl.handle.net/2237/27358"}]},"item_10_publisher_32":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"Wiley","subitem_publisher_language":"en"}]},"item_10_relation_11":{"attribute_name":"DOI","attribute_value_mlt":[{"subitem_relation_type":"isVersionOf","subitem_relation_type_id":{"subitem_relation_type_id_text":"https://doi.org/10.1002/anie.201703461","subitem_relation_type_select":"DOI"}}]},"item_10_rights_12":{"attribute_name":"権利","attribute_value_mlt":[{"subitem_rights":"This is the peer reviewed version of the following article: [O. Shoji, S. Yanagisawa, J. K. Stanfield, K. Suzuki, Z. Cong, H. Sugimoto, Y. Shiro, Y. Watanabe.(2017), Direct Hydroxylation of Benzene to Phenol by Cytochrome P450BM3 Triggered by Amino Acid Derivatives.Angewandte Chemie International Edition.,56: 10324–10329. doi:10.1002/anie.201703461], which has been published in final form at [http://doi.org/10.1002/anie.201703461]. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Self-Archiving.","subitem_rights_language":"en"}]},"item_10_select_15":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_select_item":"author"}]},"item_10_source_id_7":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"1433-7851","subitem_source_identifier_type":"PISSN"}]},"item_1615787544753":{"attribute_name":"出版タイプ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_ab4af688f83e57aa","subitem_version_type":"AM"}]},"item_access_right":{"attribute_name":"アクセス権","attribute_value_mlt":[{"subitem_access_right":"open access","subitem_access_right_uri":"http://purl.org/coar/access_right/c_abf2"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Shoji, Osami","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"75017","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Yanagisawa, Sota","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"75018","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Kyle, Stanfield  Joshua","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"75019","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Suzuki, Kazuto","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"75020","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Cong, Zhiqi","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"75021","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Sugimoto, Hiroshi","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"75022","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Shiro, Yoshitsugu","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"75023","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Watanabe, Yoshihito","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"75024","nameIdentifierScheme":"WEKO"}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2018-08-21"}],"displaytype":"detail","filename":"Sota_paper_final20170522.pdf","filesize":[{"value":"1.3 MB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"Sota_paper_final20170522.pdf ファイル公開日:2018/08/21","objectType":"fulltext","url":"https://nagoya.repo.nii.ac.jp/record/25138/files/Sota_paper_final20170522.pdf"},"version_id":"ad7d2079-f88b-476a-a56f-e4f4cfa598e7"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Direct Hydroxylation of Benzene to Phenol by Cytochrome P450BM3 Triggered by Amino Acid Derivatives","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Direct Hydroxylation of Benzene to Phenol by Cytochrome P450BM3 Triggered by Amino Acid Derivatives","subitem_title_language":"en"}]},"item_type_id":"10","owner":"1","path":["696"],"pubdate":{"attribute_name":"PubDate","attribute_value":"2018-02-05"},"publish_date":"2018-02-05","publish_status":"0","recid":"25138","relation_version_is_last":true,"title":["Direct Hydroxylation of Benzene to Phenol by Cytochrome P450BM3 Triggered by Amino Acid Derivatives"],"weko_creator_id":"1","weko_shared_id":-1},"updated":"2023-01-16T04:14:28.165719+00:00"}