{"_buckets": {"deposit": "ee98425f-3b66-4db3-a89c-429edab323e1"}, "_deposit": {"id": "25698", "owners": [], "pid": {"revision_id": 0, "type": "depid", "value": "25698"}, "status": "published"}, "_oai": {"id": "oai:nagoya.repo.nii.ac.jp:00025698", "sets": ["322"]}, "author_link": ["76105", "76106", "76107"], "item_10_biblio_info_6": {"attribute_name": "書誌情報", "attribute_value_mlt": [{"bibliographicIssueDates": {"bibliographicIssueDate": "2017-12-13", "bibliographicIssueDateType": "Issued"}, "bibliographicIssueNumber": "49", "bibliographicPageEnd": "17766", "bibliographicPageStart": "17763", "bibliographicVolumeNumber": "139", "bibliographic_titles": [{"bibliographic_title": "Journal of the American Chemical Society", "bibliographic_titleLang": "en"}]}]}, "item_10_description_4": {"attribute_name": "抄録", "attribute_value_mlt": [{"subitem_description": "Aluminabenzene–rhodium and −iridium complexes were synthesized, in which the aluminum atom played as a proximal Lewis acidic site. Based on their structural analysis, aluminabenzene ligand could coordinate to Rh and Ir as a η^5-pentadienyl ligand. The Lewis acidic character of aluminum atom in aluminabenzene ligand was confirmed by treatment with 4-dimethylaminopyridine to form the corresponding Lewis acid–base complexes. In addition, the α-selective C–H borylation of triethylamine with the aluminabenzene-ligated iridium catalyst was demonstrated.", "subitem_description_language": "en", "subitem_description_type": "Abstract"}]}, "item_10_description_5": {"attribute_name": "内容記述", "attribute_value_mlt": [{"subitem_description": "ファイル公開日: 2018/12/13", "subitem_description_language": "ja", "subitem_description_type": "Other"}]}, "item_10_publisher_32": {"attribute_name": "出版者", "attribute_value_mlt": [{"subitem_publisher": "ACS Publications", "subitem_publisher_language": "en"}]}, "item_10_relation_11": {"attribute_name": "DOI", "attribute_value_mlt": [{"subitem_relation_type": "isVersionOf", "subitem_relation_type_id": {"subitem_relation_type_id_text": "https://doi.org/10.1021/jacs.7b11127", "subitem_relation_type_select": "DOI"}}]}, "item_10_rights_12": {"attribute_name": "権利", "attribute_value_mlt": [{"subitem_rights": "“This document is the unedited Author’s version of a Submitted Work that was subsequently accepted for publication in [Journal of the American Chemical Society], copyright © American Chemical Society after peer review. To access the final edited and published work see [http://pubs.acs.org/articlesonrequest/AOR-XCtnGvXYnRwcED3Tdwgg].” ", "subitem_rights_language": "en"}]}, "item_10_select_15": {"attribute_name": "著者版フラグ", "attribute_value_mlt": [{"subitem_select_item": "author"}]}, "item_10_source_id_7": {"attribute_name": "ISSN", "attribute_value_mlt": [{"subitem_source_identifier": "0002-7863", "subitem_source_identifier_type": "PISSN"}]}, "item_1615787544753": {"attribute_name": "出版タイプ", "attribute_value_mlt": [{"subitem_version_resource": "http://purl.org/coar/version/c_ab4af688f83e57aa", "subitem_version_type": "AM"}]}, "item_access_right": {"attribute_name": "アクセス権", "attribute_value_mlt": [{"subitem_access_right": "open access", "subitem_access_right_uri": "http://purl.org/coar/access_right/c_abf2"}]}, "item_creator": {"attribute_name": "著者", "attribute_type": "creator", "attribute_value_mlt": [{"creatorNames": [{"creatorName": "Nakamura, Taichi", "creatorNameLang": "en"}], "nameIdentifiers": [{"nameIdentifier": "76105", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Suzuki, Katsunori", "creatorNameLang": "en"}], "nameIdentifiers": [{"nameIdentifier": "76106", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Yamashita, Makoto", "creatorNameLang": "en"}], "nameIdentifiers": [{"nameIdentifier": "76107", "nameIdentifierScheme": "WEKO"}]}]}, "item_files": {"attribute_name": "ファイル情報", "attribute_type": "file", "attribute_value_mlt": [{"accessrole": "open_date", "date": [{"dateType": "Available", "dateValue": "2018-12-13"}], "displaytype": "detail", "download_preview_message": "", "file_order": 0, "filename": "ja-2017-11127n_R1_main_text_submit.pdf", "filesize": [{"value": "503.1 kB"}], "format": "application/pdf", "future_date_message": "", "is_thumbnail": false, "licensetype": "license_note", "mimetype": "application/pdf", "size": 503100.0, "url": {"label": "ja-2017-11127n_R1_main_text_submit", "objectType": "fulltext", "url": "https://nagoya.repo.nii.ac.jp/record/25698/files/ja-2017-11127n_R1_main_text_submit.pdf"}, "version_id": "38f59ab6-f977-41ab-b203-2ce5b06abc11"}]}, "item_language": {"attribute_name": "言語", "attribute_value_mlt": [{"subitem_language": "eng"}]}, "item_resource_type": {"attribute_name": "資源タイプ", "attribute_value_mlt": [{"resourcetype": "journal article", "resourceuri": "http://purl.org/coar/resource_type/c_6501"}]}, "item_title": "Aluminabenzene–Rh and −Ir Complexes: Synthesis, Structure, and Application toward Catalytic C–H Borylation", "item_titles": {"attribute_name": "タイトル", "attribute_value_mlt": [{"subitem_title": "Aluminabenzene–Rh and −Ir Complexes: Synthesis, Structure, and Application toward Catalytic C–H Borylation", "subitem_title_language": "en"}]}, "item_type_id": "10", "owner": "1", "path": ["322"], "permalink_uri": "http://hdl.handle.net/2237/00027909", "pubdate": {"attribute_name": "PubDate", "attribute_value": "2018-04-17"}, "publish_date": "2018-04-17", "publish_status": "0", "recid": "25698", "relation": {}, "relation_version_is_last": true, "title": ["Aluminabenzene–Rh and −Ir Complexes: Synthesis, Structure, and Application toward Catalytic C–H Borylation"], "weko_shared_id": -1}