@article{oai:nagoya.repo.nii.ac.jp:00025698, author = {Nakamura, Taichi and Suzuki, Katsunori and Yamashita, Makoto}, issue = {49}, journal = {Journal of the American Chemical Society}, month = {Dec}, note = {Aluminabenzene–rhodium and −iridium complexes were synthesized, in which the aluminum atom played as a proximal Lewis acidic site. Based on their structural analysis, aluminabenzene ligand could coordinate to Rh and Ir as a η^5-pentadienyl ligand. The Lewis acidic character of aluminum atom in aluminabenzene ligand was confirmed by treatment with 4-dimethylaminopyridine to form the corresponding Lewis acid–base complexes. In addition, the α-selective C–H borylation of triethylamine with the aluminabenzene-ligated iridium catalyst was demonstrated., ファイル公開日: 2018/12/13}, pages = {17763--17766}, title = {Aluminabenzene–Rh and −Ir Complexes: Synthesis, Structure, and Application toward Catalytic C–H Borylation}, volume = {139}, year = {2017} }