{"created":"2021-03-01T06:33:44.853936+00:00","id":25698,"links":{},"metadata":{"_buckets":{"deposit":"ee98425f-3b66-4db3-a89c-429edab323e1"},"_deposit":{"id":"25698","owners":[],"pid":{"revision_id":0,"type":"depid","value":"25698"},"status":"published"},"_oai":{"id":"oai:nagoya.repo.nii.ac.jp:00025698","sets":["320:321:322"]},"author_link":["76105","76106","76107"],"item_10_biblio_info_6":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2017-12-13","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"49","bibliographicPageEnd":"17766","bibliographicPageStart":"17763","bibliographicVolumeNumber":"139","bibliographic_titles":[{"bibliographic_title":"Journal of the American Chemical Society","bibliographic_titleLang":"en"}]}]},"item_10_description_4":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"Aluminabenzene–rhodium and −iridium complexes were synthesized, in which the aluminum atom played as a proximal Lewis acidic site. Based on their structural analysis, aluminabenzene ligand could coordinate to Rh and Ir as a η^5-pentadienyl ligand. The Lewis acidic character of aluminum atom in aluminabenzene ligand was confirmed by treatment with 4-dimethylaminopyridine to form the corresponding Lewis acid–base complexes. In addition, the α-selective C–H borylation of triethylamine with the aluminabenzene-ligated iridium catalyst was demonstrated.","subitem_description_language":"en","subitem_description_type":"Abstract"}]},"item_10_description_5":{"attribute_name":"内容記述","attribute_value_mlt":[{"subitem_description":"ファイル公開日: 2018/12/13","subitem_description_language":"ja","subitem_description_type":"Other"}]},"item_10_publisher_32":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"ACS Publications","subitem_publisher_language":"en"}]},"item_10_relation_11":{"attribute_name":"DOI","attribute_value_mlt":[{"subitem_relation_type":"isVersionOf","subitem_relation_type_id":{"subitem_relation_type_id_text":"https://doi.org/10.1021/jacs.7b11127","subitem_relation_type_select":"DOI"}}]},"item_10_rights_12":{"attribute_name":"権利","attribute_value_mlt":[{"subitem_rights":"“This document is the unedited Author’s version of a Submitted Work that was subsequently accepted for publication in [Journal of the American Chemical Society], copyright © American Chemical Society after peer review. To access the final edited and published work see [http://pubs.acs.org/articlesonrequest/AOR-XCtnGvXYnRwcED3Tdwgg].” ","subitem_rights_language":"en"}]},"item_10_select_15":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_select_item":"author"}]},"item_10_source_id_7":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"0002-7863","subitem_source_identifier_type":"PISSN"}]},"item_1615787544753":{"attribute_name":"出版タイプ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_ab4af688f83e57aa","subitem_version_type":"AM"}]},"item_access_right":{"attribute_name":"アクセス権","attribute_value_mlt":[{"subitem_access_right":"open access","subitem_access_right_uri":"http://purl.org/coar/access_right/c_abf2"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Nakamura, Taichi","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"76105","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Suzuki, Katsunori","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"76106","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Yamashita, Makoto","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"76107","nameIdentifierScheme":"WEKO"}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2018-12-13"}],"displaytype":"detail","filename":"ja-2017-11127n_R1_main_text_submit.pdf","filesize":[{"value":"503.1 kB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"ja-2017-11127n_R1_main_text_submit","objectType":"fulltext","url":"https://nagoya.repo.nii.ac.jp/record/25698/files/ja-2017-11127n_R1_main_text_submit.pdf"},"version_id":"38f59ab6-f977-41ab-b203-2ce5b06abc11"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Aluminabenzene–Rh and −Ir Complexes: Synthesis, Structure, and Application toward Catalytic C–H Borylation","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Aluminabenzene–Rh and −Ir Complexes: Synthesis, Structure, and Application toward Catalytic C–H Borylation","subitem_title_language":"en"}]},"item_type_id":"10","owner":"1","path":["322"],"pubdate":{"attribute_name":"PubDate","attribute_value":"2018-04-17"},"publish_date":"2018-04-17","publish_status":"0","recid":"25698","relation_version_is_last":true,"title":["Aluminabenzene–Rh and −Ir Complexes: Synthesis, Structure, and Application toward Catalytic C–H Borylation"],"weko_creator_id":"1","weko_shared_id":-1},"updated":"2023-01-16T04:16:20.080173+00:00"}