{"_buckets": {"deposit": "835e4f01-2c90-447e-8bfe-f8a22cb5ca8d"}, "_deposit": {"id": "25740", "owners": [], "pid": {"revision_id": 0, "type": "depid", "value": "25740"}, "status": "published"}, "_oai": {"id": "oai:nagoya.repo.nii.ac.jp:00025740"}, "item_10_biblio_info_6": {"attribute_name": "\u66f8\u8a8c\u60c5\u5831", "attribute_value_mlt": [{"bibliographicIssueDates": {"bibliographicIssueDate": "2018-03-05", "bibliographicIssueDateType": "Issued"}, "bibliographicIssueNumber": "11", "bibliographicPageEnd": "2878", "bibliographicPageStart": "2874", "bibliographicVolumeNumber": "57", "bibliographic_titles": [{"bibliographic_title": "Angewandte Chemie International Edition"}]}]}, "item_10_description_4": {"attribute_name": "\u6284\u9332", "attribute_value_mlt": [{"subitem_description": "Nanographene, a small piece of graphene, has attracted unprecedented interest across diverse scientific disciplines particularly in organic electronics. The biological applications of nanographenes, such as bioimaging, cancer therapies and drug delivery, provide significant opportunities for breakthroughs in the field. However, the intrinsic aggregation behavior and low solubility of nanographenes, which stem from their flat structures, hamper their development for bioapplications. Herein, we report a water\u2010soluble warped nanographene (WNG) that can be easily synthesized by sequential regioselective C\u2212H borylation and cross\u2010coupling reactions of the saddle\u2010shaped WNG core structure. The saddle\u2010shaped structure and hydrophilic tetraethylene glycol chains impart high water solubility to the WNG. The water\u2010soluble WNG possesses a range of promising properties including good photostability and low cytotoxicity. Moreover, the water\u2010soluble WNG was successfully internalized into HeLa cells and promoted photoinduced cell death.", "subitem_description_type": "Abstract"}]}, "item_10_description_5": {"attribute_name": "\u5185\u5bb9\u8a18\u8ff0", "attribute_value_mlt": [{"subitem_description": "\u30d5\u30a1\u30a4\u30eb\u516c\u958b\uff1a2019-03-05", "subitem_description_type": "Other"}]}, "item_10_publisher_32": {"attribute_name": "\u51fa\u7248\u8005", "attribute_value_mlt": [{"subitem_publisher": "Wiley"}]}, "item_10_relation_11": {"attribute_name": "DOI", "attribute_value_mlt": [{"subitem_relation_type_id": {"subitem_relation_type_id_text": "https://doi.org/10.1002/anie.201713387", "subitem_relation_type_select": "DOI"}}]}, "item_10_rights_12": {"attribute_name": "\u6a29\u5229", "attribute_value_mlt": [{"subitem_rights": "\"This is the peer reviewed version of the following article: [H.-A. Lin, Y. Sato, Y. Segawa, T. Nishihara, N. Sugimoto, L. T. Scott, T. Higashiyama, K. Itami, Angew. Chem. Int. Ed. 2018, 57, 2874.], which has been published in final form at [https://doi.org/10.1002/anie.201713387]. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Self-Archiving.\""}]}, "item_10_select_15": {"attribute_name": "\u8457\u8005\u7248\u30d5\u30e9\u30b0", "attribute_value_mlt": [{"subitem_select_item": "author"}]}, "item_10_source_id_7": {"attribute_name": "ISSN", "attribute_value_mlt": [{"subitem_source_identifier": "14337851", "subitem_source_identifier_type": "ISSN"}]}, "item_creator": {"attribute_name": "\u8457\u8005", "attribute_type": "creator", "attribute_value_mlt": [{"creatorNames": [{"creatorName": "Lin, Hsing-An"}], "nameIdentifiers": [{"nameIdentifier": "76310", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Sato, Yoshikatsu"}], "nameIdentifiers": [{"nameIdentifier": "76311", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Segawa, Yasutomo"}], "nameIdentifiers": [{"nameIdentifier": "76312", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Nishihara, Taishi"}], "nameIdentifiers": [{"nameIdentifier": "76313", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Sugimoto, Nagisa"}], "nameIdentifiers": [{"nameIdentifier": "76314", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Scott, Lawrence T."}], "nameIdentifiers": [{"nameIdentifier": "76315", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Higashiyama, Tetsuya"}], "nameIdentifiers": [{"nameIdentifier": "76316", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Itami, Kenichiro"}], "nameIdentifiers": [{"nameIdentifier": "76317", "nameIdentifierScheme": "WEKO"}]}]}, "item_files": {"attribute_name": "\u30d5\u30a1\u30a4\u30eb\u60c5\u5831", "attribute_type": "file", "attribute_value_mlt": [{"accessrole": "open_date", "date": [{"dateType": "Available", "dateValue": "2019-03-05"}], "displaytype": "detail", "download_preview_message": "", "file_order": 0, "filename": "Lin20180122.pdf", "filesize": [{"value": "2.6 MB"}], "format": "application/pdf", "future_date_message": "", "is_thumbnail": false, "licensetype": "license_free", "mimetype": "application/pdf", "size": 2600000.0, "url": {"label": "Lin20180122", "url": "https://nagoya.repo.nii.ac.jp/record/25740/files/Lin20180122.pdf"}, "version_id": "e66eb760-3d59-4b3c-92b8-b0926c8d565d"}]}, "item_keyword": {"attribute_name": "\u30ad\u30fc\u30ef\u30fc\u30c9", "attribute_value_mlt": [{"subitem_subject": "arenes", "subitem_subject_scheme": "Other"}, {"subitem_subject": "cell death", "subitem_subject_scheme": "Other"}, {"subitem_subject": "chromophores", "subitem_subject_scheme": "Other"}, {"subitem_subject": "fluorescence", "subitem_subject_scheme": "Other"}, {"subitem_subject": "polycycles", "subitem_subject_scheme": "Other"}, {"subitem_subject": "warped nanographenes", "subitem_subject_scheme": "Other"}]}, "item_language": {"attribute_name": "\u8a00\u8a9e", "attribute_value_mlt": [{"subitem_language": "eng"}]}, "item_resource_type": {"attribute_name": "\u8cc7\u6e90\u30bf\u30a4\u30d7", "attribute_value_mlt": [{"resourcetype": "journal article", "resourceuri": "http://purl.org/coar/resource_type/c_6501"}]}, "item_title": "A Water-Soluble Warped Nanographene: Synthesis and Applications for Photoinduced Cell Death", "item_titles": {"attribute_name": "\u30bf\u30a4\u30c8\u30eb", "attribute_value_mlt": [{"subitem_title": "A Water-Soluble Warped Nanographene: Synthesis and Applications for Photoinduced Cell Death"}]}, "item_type_id": "10", "owner": "1", "path": ["336/695/696"], "permalink_uri": "http://hdl.handle.net/2237/00027945", "pubdate": {"attribute_name": "\u516c\u958b\u65e5", "attribute_value": "2018-05-08"}, "publish_date": "2018-05-08", "publish_status": "0", "recid": "25740", "relation": {}, "relation_version_is_last": true, "title": ["A Water-Soluble Warped Nanographene: Synthesis and Applications for Photoinduced Cell Death"], "weko_shared_id": null}