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Transfer hydrogenation of nitrogen heterocycles using a recyclable rhodium catalyst immobilized on bipyridine-periodic mesoporous organosilica
http://hdl.handle.net/2237/00027953
http://hdl.handle.net/2237/000279535c14f69b-f6db-4801-b43b-7373c8d68917
名前 / ファイル | ライセンス | アクション |
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Item type | 学術雑誌論文 / Journal Article(1) | |||||
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公開日 | 2018-05-09 | |||||
タイトル | ||||||
タイトル | Transfer hydrogenation of nitrogen heterocycles using a recyclable rhodium catalyst immobilized on bipyridine-periodic mesoporous organosilica | |||||
言語 | en | |||||
著者 |
Matsui, Kazuma
× Matsui, Kazuma× Maegawa, Yoshifumi× Waki, Minoru× Inagaki, Shinji× Yamamoto, Yoshihiko |
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アクセス権 | ||||||
アクセス権 | open access | |||||
アクセス権URI | http://purl.org/coar/access_right/c_abf2 | |||||
抄録 | ||||||
内容記述 | Transfer hydrogenation of unsaturated nitrogen heterocycles using a rhodium catalyst immobilized on bipyridine-periodic mesoporous organosilica (BPy-PMO) is described. The immobilized catalyst was prepared by mixing [Cp*RhCl2]2 (Cp* = η5-C5Me5) with BPy-PMO powder in DMF at 60 °C and characterized by nitrogen adsorption measurements, solid-state NMR spectroscopy, X-ray diffraction, energy-dispersive X-ray spectroscopy, and transmission electron microscopy. In the presence of the catalyst, a wide variety of unsaturated nitrogen heterocycles underwent transfer hydrogenation to afford the corresponding products in good yields. The immobilized catalyst could be readily recovered by centrifugation and reused several times in the transfer hydrogenation process. | |||||
言語 | en | |||||
内容記述タイプ | Abstract | |||||
内容記述 | ||||||
内容記述 | ファイル公開:2019/01/21 | |||||
言語 | ja | |||||
内容記述タイプ | Other | |||||
出版者 | ||||||
言語 | en | |||||
出版者 | Royal Society of Chemistry | |||||
言語 | ||||||
言語 | eng | |||||
資源タイプ | ||||||
資源タイプresource | http://purl.org/coar/resource_type/c_6501 | |||||
タイプ | journal article | |||||
出版タイプ | ||||||
出版タイプ | AM | |||||
出版タイプResource | http://purl.org/coar/version/c_ab4af688f83e57aa | |||||
DOI | ||||||
関連タイプ | isVersionOf | |||||
識別子タイプ | DOI | |||||
関連識別子 | https://doi.org/10.1039/C7CY02167D | |||||
ISSN | ||||||
収録物識別子タイプ | PISSN | |||||
収録物識別子 | 2044-4753 | |||||
書誌情報 |
en : Catalysis Science & Technology 巻 8, 号 2, p. 534-539, 発行日 2018-01-21 |
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著者版フラグ | ||||||
値 | author |