@article{oai:nagoya.repo.nii.ac.jp:00026100, author = {Yoshida, Takuya and Takahashi, Kohtaro and Ide, Yuki and Kishi, Ryohei and Fujiyoshi, Jun-ya and Lee, Sangsu and Hiraoka, Yuya and Kim, Dongho and Nakano, Masayoshi and Ikeue, Takahisa and Yamada, Hiroko and Shinokubo, Hiroshi}, issue = {8}, journal = {Angewandte Chemie International Edition}, month = {Feb}, note = {Fused benzene rings to antiaromatic compounds generally improve their stability but attenuate their antiaromaticity. The opposite case is now reported. Ni^II benzonorcorroles were synthesized and the effect of benzo‐fusion on the antiaromaticity was elucidated. The benzo‐fusion resulted in significant decrease of the HOMO–LUMO gaps and enhancement of the paratropic ring current effect. Furthermore, the introduction of the benzo groups induced singlet diradical character in the antiaromatic porphyrinoid., ファイル公開:2019-02-19}, pages = {2209--2213}, title = {Benzonorcorrole Ni^II Complexes : Enhancement of Paratropic Ring Current and Singlet Diradical Character by Benzo-Fusion}, volume = {57}, year = {2018} }