@article{oai:nagoya.repo.nii.ac.jp:00026128, author = {Hatano, Manabu and Tabata, Yuji and Yoshida, Yurika and Toh, Kohei and Yamashita, Kenji and Ogura, Yoshihiro and Ishihara, Kazuaki}, issue = {6}, journal = {Green Chemistry}, month = {Mar}, note = {Environmentally benign metal-free tetramethylammonium methyl carbonate is effective as a catalyst for the chemoselective, scalable, and reusable transesterification of various esters and alcohols in common organic solvents. In situ-generated highly active species, tetramethylammonium alkoxides, can greatly avoid self-decomposition at ≤110 °C, and are reusable. In particular, chelating substrates, such as amino alcohols, diols, triols, sugar derivatives, alkaloids, α-amino acid esters, etc., which deactivate conventional metal salt catalysts, can be used. A 100 gram scale biodiesel production was also demonstrated., ファイル公開:2019/03/21}, pages = {1193--1198}, title = {Metal-free transesterification catalyzed by tetramethylammonium methyl carbonate}, volume = {20}, year = {2018} }