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Shear Viscosity and Heterogeneous Structure of Alkylaminoethanol-Based CO2 Absorbents
http://hdl.handle.net/2237/00028428
http://hdl.handle.net/2237/00028428caa26cc9-24e6-4b44-a5d0-e9d1328ca892
名前 / ファイル | ライセンス | アクション |
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amvis2 (390.1 kB)
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Item type | 学術雑誌論文 / Journal Article(1) | |||||
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公開日 | 2018-08-06 | |||||
タイトル | ||||||
タイトル | Shear Viscosity and Heterogeneous Structure of Alkylaminoethanol-Based CO2 Absorbents | |||||
言語 | en | |||||
著者 |
Yamaguchi, Tsuyoshi
× Yamaguchi, Tsuyoshi× Ando, Ryuya× Yoshida, Koji× Yamaguchi, Toshio× Machida, Hiroshi |
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アクセス権 | ||||||
アクセス権 | open access | |||||
アクセス権URI | http://purl.org/coar/access_right/c_abf2 | |||||
権利 | ||||||
言語 | en | |||||
権利情報 | “This document is the Accepted Manuscript version of a Published Work that appeared in final form in [The Journal of Physical Chemistry B], copyright © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see [https://pubs.acs.org/articlesonrequest/AOR-ID6YcVECvyF4ds7hUjtK].” | |||||
抄録 | ||||||
内容記述 | Shear viscosity of concentrated aqueous solutions of alkylaminoethanols was determined with changing the length of the alkyl chain and the concentration of dissolved CO2. The viscosity increased with increasing the CO2 loading, reflecting the strengthening of the intermolecular electrostatic interaction. The dependence of the viscosity on both temperature and CO2 loading was described by a modified version of Vogel–Fulchar–Tammann equation. Compared at the same volume concentration of CO2, the viscosity increased with increasing the alkyl chain lengths, and the dependence on the alkyl chain length increased with the CO2 loading. At the same time, small-angle X-ray scattering profiles exhibited the presence of a prepeak when the alkyl chain was long, and the prepeak grew with the CO2 loading. It suggests that the presence of the heterogeneous structure increases the shear viscosity of the CO2 absorbents when the alkyl chain is long. | |||||
言語 | en | |||||
内容記述タイプ | Abstract | |||||
内容記述 | ||||||
内容記述 | ファイル公開:2019-04-12 | |||||
言語 | ja | |||||
内容記述タイプ | Other | |||||
出版者 | ||||||
言語 | en | |||||
出版者 | ACS Publications | |||||
言語 | ||||||
言語 | eng | |||||
資源タイプ | ||||||
資源タイプresource | http://purl.org/coar/resource_type/c_6501 | |||||
タイプ | journal article | |||||
出版タイプ | ||||||
出版タイプ | AM | |||||
出版タイプResource | http://purl.org/coar/version/c_ab4af688f83e57aa | |||||
DOI | ||||||
関連タイプ | isVersionOf | |||||
識別子タイプ | DOI | |||||
関連識別子 | https://doi.org/10.1021/acs.jpcb.8b00946 | |||||
ISSN | ||||||
収録物識別子タイプ | PISSN | |||||
収録物識別子 | 1520-6106 | |||||
書誌情報 |
en : The Journal of Physical Chemistry B 巻 122, 号 14, p. 4045-4050, 発行日 2018-04-12 |
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著者版フラグ | ||||||
値 | author |