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  1. B200 工学部/工学研究科
  2. B200a 雑誌掲載論文
  3. 学術雑誌

Shear Viscosity and Heterogeneous Structure of Alkylaminoethanol-Based CO2 Absorbents

http://hdl.handle.net/2237/00028428
caa26cc9-24e6-4b44-a5d0-e9d1328ca892
名前 / ファイル ライセンス アクション
amvis2.pdf amvis2 (390.1 kB)
Item type 学術雑誌論文 / Journal Article(1)
公開日 2018-08-06
タイトル
タイトル Shear Viscosity and Heterogeneous Structure of Alkylaminoethanol-Based CO2 Absorbents
著者 Yamaguchi, Tsuyoshi

× Yamaguchi, Tsuyoshi

WEKO 78644

Yamaguchi, Tsuyoshi

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Ando, Ryuya

× Ando, Ryuya

WEKO 78645

Ando, Ryuya

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Yoshida, Koji

× Yoshida, Koji

WEKO 78646

Yoshida, Koji

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Yamaguchi, Toshio

× Yamaguchi, Toshio

WEKO 78647

Yamaguchi, Toshio

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Machida, Hiroshi

× Machida, Hiroshi

WEKO 78648

Machida, Hiroshi

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権利
権利情報 “This document is the Accepted Manuscript version of a Published Work that appeared in final form in [The Journal of Physical Chemistry B], copyright © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see [https://pubs.acs.org/articlesonrequest/AOR-ID6YcVECvyF4ds7hUjtK].”
抄録
内容記述 Shear viscosity of concentrated aqueous solutions of alkylaminoethanols was determined with changing the length of the alkyl chain and the concentration of dissolved CO2. The viscosity increased with increasing the CO2 loading, reflecting the strengthening of the intermolecular electrostatic interaction. The dependence of the viscosity on both temperature and CO2 loading was described by a modified version of Vogel–Fulchar–Tammann equation. Compared at the same volume concentration of CO2, the viscosity increased with increasing the alkyl chain lengths, and the dependence on the alkyl chain length increased with the CO2 loading. At the same time, small-angle X-ray scattering profiles exhibited the presence of a prepeak when the alkyl chain was long, and the prepeak grew with the CO2 loading. It suggests that the presence of the heterogeneous structure increases the shear viscosity of the CO2 absorbents when the alkyl chain is long.
内容記述タイプ Abstract
内容記述
内容記述 ファイル公開:2019-04-12
内容記述タイプ Other
出版者
出版者 ACS Publications
言語
言語 eng
資源タイプ
資源タイプresource http://purl.org/coar/resource_type/c_6501
タイプ journal article
DOI
関連識別子
識別子タイプ DOI
関連識別子 http://doi.org/10.1021/acs.jpcb.8b00946
ISSN
収録物識別子タイプ ISSN
収録物識別子 1520-6106
書誌情報 The Journal of Physical Chemistry B

巻 122, 号 14, p. 4045-4050, 発行日 2018-04-12
著者版フラグ
値 author
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