{"_buckets": {"deposit": "869e30da-6591-47f9-9019-14fb3379b934"}, "_deposit": {"id": "26228", "owners": [], "pid": {"revision_id": 0, "type": "depid", "value": "26228"}, "status": "published"}, "_oai": {"id": "oai:nagoya.repo.nii.ac.jp:00026228"}, "item_10_biblio_info_6": {"attribute_name": "\u66f8\u8a8c\u60c5\u5831", "attribute_value_mlt": [{"bibliographicIssueDates": {"bibliographicIssueDate": "2018-04-15", "bibliographicIssueDateType": "Issued"}, "bibliographicIssueNumber": "4", "bibliographicPageStart": "044701", "bibliographicVolumeNumber": "87", "bibliographic_titles": [{"bibliographic_title": "Journal of the Physical Society of Japan"}]}]}, "item_10_description_4": {"attribute_name": "\u6284\u9332", "attribute_value_mlt": [{"subitem_description": "The valence-band electronic structures of high-pressure-phase PdF2-type (HP-PdF2-type) platinum-group metal dioxides MO2 (M = Ru, Rh, Ir, and Pt) were studied by synchrotron radiation photoelectron spectroscopy and first-principles calculations. The obtained photoelectron spectra for HP-PdF2-type RuO2, RhO2, and IrO2 agree well with the calculated valence-band densities of states (DOSs) for these compounds, indicating their metallic properties, whereas the DOS of HP-PdF2-type PtO2 (calculated in the presence and absence of spin\u2013orbit interactions) predicts that this material may be metallic or semimetallic, which is inconsistent with the electric conductivity reported to date and the charging effect observed in current photoelectron measurements. Compared with the calculated results, the valence-band spectrum of PtO2 appears to have shifted toward the high-binding-energy side and reveals a gradual intensity decrease toward the Fermi energy EF, implying a semiconductor-like electronic structure. Spin-dependent calculations predict a ferromagnetic ground state with a magnetization of 0.475 \u03bcB per formula unit for HP-PdF2-type RhO2.", "subitem_description_type": "Abstract"}]}, "item_10_description_5": {"attribute_name": "\u5185\u5bb9\u8a18\u8ff0", "attribute_value_mlt": [{"subitem_description": "\u30d5\u30a1\u30a4\u30eb\u516c\u958b\uff1a2019/04/15", "subitem_description_type": "Other"}]}, "item_10_publisher_32": {"attribute_name": "\u51fa\u7248\u8005", "attribute_value_mlt": [{"subitem_publisher": "\u65e5\u672c\u7269\u7406\u5b66\u4f1a"}]}, "item_10_relation_11": {"attribute_name": "DOI", "attribute_value_mlt": [{"subitem_relation_type_id": {"subitem_relation_type_id_text": "https://doi.org/10.7566/JPSJ.87.044701", "subitem_relation_type_select": "DOI"}}]}, "item_10_rights_12": {"attribute_name": "\u6a29\u5229", "attribute_value_mlt": [{"subitem_rights": "Copyright \u00a92018 The Physical Society of Japan \u65e5\u672c\u7269\u7406\u5b66\u4f1a "}]}, "item_10_select_15": {"attribute_name": "\u8457\u8005\u7248\u30d5\u30e9\u30b0", "attribute_value_mlt": [{"subitem_select_item": "author"}]}, "item_10_source_id_7": {"attribute_name": "ISSN", "attribute_value_mlt": [{"subitem_source_identifier": "0031-9015", "subitem_source_identifier_type": "ISSN"}]}, "item_creator": {"attribute_name": "\u8457\u8005", "attribute_type": "creator", "attribute_value_mlt": [{"creatorNames": [{"creatorName": "Soda, Kazuo"}], "nameIdentifiers": [{"nameIdentifier": "78668", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Kobayashi, Daichi"}], "nameIdentifiers": [{"nameIdentifier": "78669", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Mizui, Tatsuya"}], "nameIdentifiers": [{"nameIdentifier": "78670", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Kato, Masahiko"}], "nameIdentifiers": [{"nameIdentifier": "78671", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Shirako, Yuichi"}], "nameIdentifiers": [{"nameIdentifier": "78672", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Niwa, Ken"}], "nameIdentifiers": [{"nameIdentifier": "78673", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Hasegawa, Masashi"}], "nameIdentifiers": [{"nameIdentifier": "78674", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Akaogi, Masaki"}], "nameIdentifiers": [{"nameIdentifier": "78675", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Kojitani, Hiroshi"}], "nameIdentifiers": [{"nameIdentifier": "78676", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Ikenaga, Eiji"}], "nameIdentifiers": [{"nameIdentifier": "78677", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Muro, Takayuki"}], "nameIdentifiers": [{"nameIdentifier": "78678", "nameIdentifierScheme": "WEKO"}]}]}, "item_files": {"attribute_name": "\u30d5\u30a1\u30a4\u30eb\u60c5\u5831", "attribute_type": "file", "attribute_value_mlt": [{"accessrole": "open_date", "date": [{"dateType": "Available", "dateValue": "2019-04-15"}], "displaytype": "detail", "download_preview_message": "", "file_order": 0, "filename": "JPSJ_HAXPESMO2_soda_NUrepository.pdf", "filesize": [{"value": "696.4 kB"}], "format": "application/pdf", "future_date_message": "", "is_thumbnail": false, "licensetype": "license_free", "mimetype": "application/pdf", "size": 696400.0, "url": {"label": "JPSJ_HAXPESMO2_soda_NUrepository", "url": "https://nagoya.repo.nii.ac.jp/record/26228/files/JPSJ_HAXPESMO2_soda_NUrepository.pdf"}, "version_id": "00955b7e-e0b1-4de9-a438-5e9d503269d6"}]}, "item_language": {"attribute_name": "\u8a00\u8a9e", "attribute_value_mlt": [{"subitem_language": "eng"}]}, "item_resource_type": {"attribute_name": "\u8cc7\u6e90\u30bf\u30a4\u30d7", "attribute_value_mlt": [{"resourcetype": "journal article", "resourceuri": "http://purl.org/coar/resource_type/c_6501"}]}, "item_title": "Valence-Band Electronic Structures of High-Pressure-Phase PdF2-type Platinum-Group Metal Dioxides MO2 (M = Ru, Rh, Ir, and Pt)", "item_titles": {"attribute_name": "\u30bf\u30a4\u30c8\u30eb", "attribute_value_mlt": [{"subitem_title": "Valence-Band Electronic Structures of High-Pressure-Phase PdF2-type Platinum-Group Metal Dioxides MO2 (M = Ru, Rh, Ir, and Pt)"}]}, "item_type_id": "10", "owner": "1", "path": ["320/321/322"], "permalink_uri": "http://hdl.handle.net/2237/00028432", "pubdate": {"attribute_name": "\u516c\u958b\u65e5", "attribute_value": "2018-08-07"}, "publish_date": "2018-08-07", "publish_status": "0", "recid": "26228", "relation": {}, "relation_version_is_last": true, "title": ["Valence-Band Electronic Structures of High-Pressure-Phase PdF2-type Platinum-Group Metal Dioxides MO2 (M = Ru, Rh, Ir, and Pt)"], "weko_shared_id": null}