{"created":"2021-03-01T06:34:16.225387+00:00","id":26351,"links":{},"metadata":{"_buckets":{"deposit":"e7998980-ce1b-44e8-a07b-f9bf9b5bfed0"},"_deposit":{"id":"26351","owners":[],"pid":{"revision_id":0,"type":"depid","value":"26351"},"status":"published"},"_oai":{"id":"oai:nagoya.repo.nii.ac.jp:00026351","sets":["320:321:322"]},"author_link":["85207","85208","85209","85210","85211"],"item_10_biblio_info_6":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2018-05-22","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"21","bibliographicPageEnd":"6114","bibliographicPageStart":"6109","bibliographicVolumeNumber":"57","bibliographic_titles":[{"bibliographic_title":"Angewandte Chemie International Edition","bibliographic_titleLang":"en"}]}]},"item_10_description_4":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"The reaction of highly Lewis acidic tetra(o‐tolyl)diborane(4) with CO afforded a mixture of boraindane and boroxine by the cleavage of the C≡O triple bond. 13C labeling experiments confirmed that the carbon atom in the boraindane stems from CO. Simultaneously, formation of boroxine 3 could be considered as borylene transfer to capture the oxygen atom from CO. The reaction of diborane(4) with tBu−NC afforded an azaallene, while the reaction with Xyl−NC furnished cyclic compounds by direct C−H borylations. ","subitem_description_language":"en","subitem_description_type":"Abstract"}]},"item_10_description_5":{"attribute_name":"内容記述","attribute_value_mlt":[{"subitem_description":"ファイル公開：2019-05-22","subitem_description_language":"ja","subitem_description_type":"Other"}]},"item_10_publisher_32":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"Wiley","subitem_publisher_language":"en"}]},"item_10_relation_11":{"attribute_name":"DOI","attribute_value_mlt":[{"subitem_relation_type":"isVersionOf","subitem_relation_type_id":{"subitem_relation_type_id_text":"https://doi.org/10.1002/anie.201800878","subitem_relation_type_select":"DOI"}}]},"item_10_rights_12":{"attribute_name":"権利","attribute_value_mlt":[{"subitem_rights":"This is the peer reviewed version of the following article: [Y. Katsuma, N. Tsukahara, L. Wu, Z. Lin, M. Yamashita, Angew. Chem. Int. Ed. 2018, 57, 6109.], which has been published in final form at [https://doi.org/10.1002/anie.201800878]. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Use of Self-Archived Versions.","subitem_rights_language":"en"}]},"item_10_select_15":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_select_item":"author"}]},"item_10_source_id_61":{"attribute_name":"ISSN（print）","attribute_value_mlt":[{"subitem_source_identifier":"1433-7851","subitem_source_identifier_type":"PISSN"}]},"item_10_source_id_62":{"attribute_name":"ISSN（Online）","attribute_value_mlt":[{"subitem_source_identifier":"1521-3773","subitem_source_identifier_type":"EISSN"}]},"item_1615787544753":{"attribute_name":"出版タイプ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_ab4af688f83e57aa","subitem_version_type":"AM"}]},"item_access_right":{"attribute_name":"アクセス権","attribute_value_mlt":[{"subitem_access_right":"open access","subitem_access_right_uri":"http://purl.org/coar/access_right/c_abf2"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Katsuma, Yuhei","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"85207","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Tsukahara, Nana","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"85208","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Wu, Linlin","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"85209","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Lin, Zhenyang","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"85210","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Yamashita, Makoto","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"85211","nameIdentifierScheme":"WEKO"}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2019-05-22"}],"displaytype":"detail","filename":"20180314_Text.pdf","filesize":[{"value":"613.5 kB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"20180314_Text","objectType":"fulltext","url":"https://nagoya.repo.nii.ac.jp/record/26351/files/20180314_Text.pdf"},"version_id":"9ec4d792-e242-4b7c-a7d4-985eb239c8ca"}]},"item_keyword":{"attribute_name":"キーワード","attribute_value_mlt":[{"subitem_subject":"bond cleavage","subitem_subject_scheme":"Other"},{"subitem_subject":"carbon monoxide","subitem_subject_scheme":"Other"},{"subitem_subject":"diborane(4)","subitem_subject_scheme":"Other"},{"subitem_subject":"isocyanide","subitem_subject_scheme":"Other"},{"subitem_subject":"triple bonds","subitem_subject_scheme":"Other"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Reaction of B2(o-tol)4 with CO and Isocyanides: Cleavage of the C≡O Triple Bond and Direct C−H Borylations","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Reaction of B2(o-tol)4 with CO and Isocyanides: Cleavage of the C≡O Triple Bond and Direct C−H Borylations","subitem_title_language":"en"}]},"item_type_id":"10","owner":"1","path":["322"],"pubdate":{"attribute_name":"PubDate","attribute_value":"2018-09-11"},"publish_date":"2018-09-11","publish_status":"0","recid":"26351","relation_version_is_last":true,"title":["Reaction of B2(o-tol)4 with CO and Isocyanides: Cleavage of the C≡O Triple Bond and Direct C−H Borylations"],"weko_creator_id":"1","weko_shared_id":-1},"updated":"2023-01-16T04:16:45.630546+00:00"}