{"created":"2021-03-01T06:34:16.431649+00:00","id":26354,"links":{},"metadata":{"_buckets":{"deposit":"13290a87-715b-4a80-ab4f-af0ac2899875"},"_deposit":{"id":"26354","owners":[],"pid":{"revision_id":0,"type":"depid","value":"26354"},"status":"published"},"_oai":{"id":"oai:nagoya.repo.nii.ac.jp:00026354","sets":["320:2111:2112"]},"item_21_biblio_info_6":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2018","bibliographicIssueDateType":"Issued"},"bibliographicPageEnd":"120","bibliographicPageStart":"91","bibliographicVolumeNumber":"62"}]},"item_21_description_4":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"Recent progress on our Brønsted acid/Lewis base hybrid complexes in some asymmetric catalyses is reviewed. Based on the rational design of conjugated acid–base catalysts, tailor-made supramolecular catalysts can show remarkable catalytic activity and higher-ordered selectivities that cannot be realized by ready-made single-molecule catalysts. The chiral supramolecular magnesium(II) binaphtholate complexes trigger the highly enantioselective 1,4-hydrophosphinylation and 1,2-hydrophosphonylation of α,β-unsaturated carbonyl compounds, direct Mannich-type reaction, and hetero-Diels–Alder reaction. Moreover, the advanced supramolecular catalysts are prepared in situ from chiral 3,3′-disubstituted binaphthols and biphenols, arylboronic acid, and B(C6F5)3, for promoting the anomalous endo-/exo-selective Diels–Alder reaction. The specific mechanism and deep insights into the possible key intermediates are discussed on the basis of rational design of chiral supramolecular Brønsted acid/Lewis base hybrid catalysts as artificial enzymes.","subitem_description_type":"Abstract"}]},"item_21_description_5":{"attribute_name":"内容記述","attribute_value_mlt":[{"subitem_description":"First Online: 11 August 2015.","subitem_description_type":"Other"}]},"item_21_publisher_32":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"Springer"}]},"item_21_record_name_61":{"attribute_name":"図書名","attribute_value_mlt":[{"subitem_source_title":"Chiral Lewis Acids"}]},"item_21_relation_11":{"attribute_name":"DOI","attribute_value_mlt":[{"subitem_relation_type_id":{"subitem_relation_type_id_text":"https://doi.org/10.1007/3418_2015_143","subitem_relation_type_select":"DOI"}}]},"item_21_relation_40":{"attribute_name":"シリーズ","attribute_value_mlt":[{"subitem_relation_name":[{"subitem_relation_name_text":"Topics in Organometallic Chemistry book series (TOPORGAN, volume 62)"}]}]},"item_21_relation_7":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_relation_type":"isPartOf","subitem_relation_type_id":{"subitem_relation_type_id_text":"1436-6002","subitem_relation_type_select":"ISSN"}}]},"item_21_relation_8":{"attribute_name":"ISBN","attribute_value_mlt":[{"subitem_relation_type":"isIdenticalTo","subitem_relation_type_id":{"subitem_relation_type_id_text":"978-3-319-70804-1","subitem_relation_type_select":"ISBN"}}]},"item_21_select_15":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_select_item":"author"}]},"item_access_right":{"attribute_name":"アクセス権","attribute_value_mlt":[{"subitem_access_right":"open access","subitem_access_right_uri":"http://purl.org/coar/access_right/c_abf2"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Hatano, Manabu"}],"nameIdentifiers":[{"nameIdentifier":"85219","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Ishihara, Kazuaki"}],"nameIdentifiers":[{"nameIdentifier":"85220","nameIdentifierScheme":"WEKO"}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2018-09-11"}],"displaytype":"detail","filename":"chapter.pdf","filesize":[{"value":"3.7 MB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"chapter","url":"https://nagoya.repo.nii.ac.jp/record/26354/files/chapter.pdf"},"version_id":"b6a79d36-b6f5-4302-af0f-e7ed530e2694"}]},"item_keyword":{"attribute_name":"キーワード","attribute_value_mlt":[{"subitem_subject":"Acid–base catalyst","subitem_subject_scheme":"Other"},{"subitem_subject":"BINOL","subitem_subject_scheme":"Other"},{"subitem_subject":"Boron","subitem_subject_scheme":"Other"},{"subitem_subject":"Magnesium","subitem_subject_scheme":"Other"},{"subitem_subject":"Supramolecular catalyst","subitem_subject_scheme":"Other"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"book part","resourceuri":"http://purl.org/coar/resource_type/c_3248"}]},"item_title":"Brønsted Acid/Lewis Base Hybrid Complexes","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Brønsted Acid/Lewis Base Hybrid Complexes","subitem_title_language":"en"}]},"item_type_id":"21","owner":"1","path":["2112"],"pubdate":{"attribute_name":"PubDate","attribute_value":"2018-09-11"},"publish_date":"2018-09-11","publish_status":"0","recid":"26354","relation_version_is_last":true,"title":["Brønsted Acid/Lewis Base Hybrid Complexes"],"weko_creator_id":"1","weko_shared_id":null},"updated":"2023-01-16T05:01:43.870818+00:00"}