{"created":"2021-03-01T06:34:17.848747+00:00","id":26373,"links":{},"metadata":{"_buckets":{"deposit":"7b51158f-4949-46ee-97de-e167d3664e42"},"_deposit":{"id":"26373","owners":[],"pid":{"revision_id":0,"type":"depid","value":"26373"},"status":"published"},"_oai":{"id":"oai:nagoya.repo.nii.ac.jp:00026373","sets":["320:321:322"]},"author_link":["85307","85308","85309","85310","85311","85312"],"item_10_biblio_info_6":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2018-05-23","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"20","bibliographicPageEnd":"6342","bibliographicPageStart":"6336","bibliographicVolumeNumber":"140","bibliographic_titles":[{"bibliographic_title":"Journal of the American Chemical Society","bibliographic_titleLang":"en"}]}]},"item_10_description_4":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"We designed and synthesized molecular tweezers consisting of nitrogen-embedded buckybowl subunits. The judicious choice of the covalent linkers modulated their binding strength with C60 or C70 in solution. Titration studies by optical and 1H NMR analyses revealed a 1:1 composition of the resulting complexes. X-ray diffraction analysis elucidated their solid-state structures, in which two azabuckybowl units surround one fullerene molecule. The large association constants stabilize the complexes toward redox reactions and the purification process on silica-gel column chromatography. The linker enabled tuning of the cavity size for binding of fullerenes, achieving complementary fullerene hosts for C60 and C70: the carbazole-bridged dimer preferentially associates with C70 over C60, while the phenanthrene-bridged dimer interacts with C60 more strongly than C70. Electrochemical analysis in combination with density functional theory calculations indicated the existence of intermolecular charge-transfer interactions between the buckybowl units and the fullerenes. Nonlinear optical measurements showed that the two-photon absorption cross sections of the molecular tweezers are enhanced upon association with fullerenes.","subitem_description_language":"en","subitem_description_type":"Abstract"}]},"item_10_description_5":{"attribute_name":"内容記述","attribute_value_mlt":[{"subitem_description":"ファイル公開：2019-05-23","subitem_description_language":"ja","subitem_description_type":"Other"}]},"item_10_publisher_32":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"ACS Publications","subitem_publisher_language":"en"}]},"item_10_relation_11":{"attribute_name":"DOI","attribute_value_mlt":[{"subitem_relation_type":"isVersionOf","subitem_relation_type_id":{"subitem_relation_type_id_text":"https://doi.org/10.1021/jacs.8b02327","subitem_relation_type_select":"DOI"}}]},"item_10_rights_12":{"attribute_name":"権利","attribute_value_mlt":[{"subitem_rights":"“This document is the Accepted Manuscript version of a Published Work that appeared in final form in [Journal of the American Chemical Society], copyright © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see [http://pubs.acs.org/articlesonrequest/AOR-Af3K7B4ddX4FGds57Hw5].”","subitem_rights_language":"en"}]},"item_10_select_15":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_select_item":"author"}]},"item_10_source_id_61":{"attribute_name":"ISSN（print）","attribute_value_mlt":[{"subitem_source_identifier":"0002-7863","subitem_source_identifier_type":"PISSN"}]},"item_10_source_id_62":{"attribute_name":"ISSN（Online）","attribute_value_mlt":[{"subitem_source_identifier":"1520-5126","subitem_source_identifier_type":"EISSN"}]},"item_1615787544753":{"attribute_name":"出版タイプ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_ab4af688f83e57aa","subitem_version_type":"AM"}]},"item_access_right":{"attribute_name":"アクセス権","attribute_value_mlt":[{"subitem_access_right":"open access","subitem_access_right_uri":"http://purl.org/coar/access_right/c_abf2"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Takeda, Motoki","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"85307","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Hiroto, Satoru","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"85308","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Yokoi, Hiroki","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"85309","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Lee, Sangsu","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"85310","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Kim, Dongho","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"85311","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Shinokubo, Hiroshi","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"85312","nameIdentifierScheme":"WEKO"}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2019-05-23"}],"displaytype":"detail","filename":"8416_MT_rev.pdf","filesize":[{"value":"3.4 MB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"8416_MT_rev","objectType":"fulltext","url":"https://nagoya.repo.nii.ac.jp/record/26373/files/8416_MT_rev.pdf"},"version_id":"222cfd73-c874-44af-b2ba-f91d0f469f97"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Azabuckybowl-Based Molecular Tweezers as C60 and C70 Receptors","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Azabuckybowl-Based Molecular Tweezers as C60 and C70 Receptors","subitem_title_language":"en"}]},"item_type_id":"10","owner":"1","path":["322"],"pubdate":{"attribute_name":"PubDate","attribute_value":"2018-09-13"},"publish_date":"2018-09-13","publish_status":"0","recid":"26373","relation_version_is_last":true,"title":["Azabuckybowl-Based Molecular Tweezers as C60 and C70 Receptors"],"weko_creator_id":"1","weko_shared_id":-1},"updated":"2023-01-16T04:16:51.703982+00:00"}