{"created":"2021-03-01T06:34:19.892859+00:00","id":26404,"links":{},"metadata":{"_buckets":{"deposit":"31ed69b3-5a67-44ae-8e60-05ae41b4b4fd"},"_deposit":{"id":"26404","owners":[],"pid":{"revision_id":0,"type":"depid","value":"26404"},"status":"published"},"_oai":{"id":"oai:nagoya.repo.nii.ac.jp:00026404","sets":["320:321:322"]},"author_link":["86763","86764"],"item_10_biblio_info_6":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2018-09-20","bibliographicIssueDateType":"Issued"},"bibliographicPageEnd":"70","bibliographicPageStart":"66","bibliographicVolumeNumber":"553","bibliographic_titles":[{"bibliographic_title":"Colloids and Surfaces A: Physicochemical and Engineering Aspects","bibliographic_titleLang":"en"}]}]},"item_10_description_4":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"To synthesize polystyrene-silica core-shell particles and silica hollow particles, soap-free emulsion polymerization was carried out using styrene and N-vinylacetamide (NVA), and the Stöber method using tetraethyl orthosilicate (TEOS) was performed on the polymer particle surfaces. Here, NVA acts as a stabilizer for the polymer colloids, maintaining dispersion stability by synthesizing hydration layers even when the electrostatic adsorption of TEOS had occurred, and as a catalyst for the sol-gel reaction. NVA was polymerized by the cationic initiator located on the surface of the polystyrene particles to maintain dispersion stability by a steric effect. Therefore, the sol-gel reactions proceeded more efficiently on the surface of polymer particles, facilitated by the much larger surface area. Finally, the polymer core was removed by heating to prepare highly monodisperse silica hollow particles.","subitem_description_language":"en","subitem_description_type":"Abstract"}]},"item_10_description_5":{"attribute_name":"内容記述","attribute_value_mlt":[{"subitem_description":"ファイル公開：2020-09-20","subitem_description_language":"ja","subitem_description_type":"Other"}]},"item_10_publisher_32":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"Elsevier","subitem_publisher_language":"en"}]},"item_10_relation_11":{"attribute_name":"DOI","attribute_value_mlt":[{"subitem_relation_type":"isVersionOf","subitem_relation_type_id":{"subitem_relation_type_id_text":"https://doi.org/10.1016/j.colsurfa.2018.05.036","subitem_relation_type_select":"DOI"}}]},"item_10_rights_12":{"attribute_name":"権利","attribute_value_mlt":[{"subitem_rights":"© 2018. This manuscript version is made available under the CC-BY-NC-ND 4.0 license http://creativecommons.org/licenses/by-nc-nd/4.0/","subitem_rights_language":"en"}]},"item_10_select_15":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_select_item":"author"}]},"item_10_source_id_61":{"attribute_name":"ISSN（print）","attribute_value_mlt":[{"subitem_source_identifier":"0927-7757","subitem_source_identifier_type":"PISSN"}]},"item_1615787544753":{"attribute_name":"出版タイプ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_ab4af688f83e57aa","subitem_version_type":"AM"}]},"item_access_right":{"attribute_name":"アクセス権","attribute_value_mlt":[{"subitem_access_right":"open access","subitem_access_right_uri":"http://purl.org/coar/access_right/c_abf2"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Yamamoto, Tetsuya","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"86763","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Takahashi, Yuya","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"86764","nameIdentifierScheme":"WEKO"}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2020-09-20"}],"displaytype":"detail","filename":"YManu-VA044.pdf","filesize":[{"value":"655.5 kB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"YManu-VA044","objectType":"fulltext","url":"https://nagoya.repo.nii.ac.jp/record/26404/files/YManu-VA044.pdf"},"version_id":"214a33ba-0672-4a4a-b88a-844eb7afc844"}]},"item_keyword":{"attribute_name":"キーワード","attribute_value_mlt":[{"subitem_subject":"Core-shell particle","subitem_subject_scheme":"Other"},{"subitem_subject":"Silica","subitem_subject_scheme":"Other"},{"subitem_subject":"Dispersion stability","subitem_subject_scheme":"Other"},{"subitem_subject":"Stöber method","subitem_subject_scheme":"Other"},{"subitem_subject":"Surface reaction","subitem_subject_scheme":"Other"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Design of polymer particles maintaining dispersion stability for the synthesis of hollow silica particles through sol-gel reaction on polymer surfaces","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Design of polymer particles maintaining dispersion stability for the synthesis of hollow silica particles through sol-gel reaction on polymer surfaces","subitem_title_language":"en"}]},"item_type_id":"10","owner":"1","path":["322"],"pubdate":{"attribute_name":"PubDate","attribute_value":"2018-10-09"},"publish_date":"2018-10-09","publish_status":"0","recid":"26404","relation_version_is_last":true,"title":["Design of polymer particles maintaining dispersion stability for the synthesis of hollow silica particles through sol-gel reaction on polymer surfaces"],"weko_creator_id":"1","weko_shared_id":-1},"updated":"2023-01-16T04:17:00.563088+00:00"}