{"created":"2021-03-01T06:34:20.023243+00:00","id":26406,"links":{},"metadata":{"_buckets":{"deposit":"d62167b5-cd55-4955-b919-7f685515b87e"},"_deposit":{"id":"26406","owners":[],"pid":{"revision_id":0,"type":"depid","value":"26406"},"status":"published"},"_oai":{"id":"oai:nagoya.repo.nii.ac.jp:00026406","sets":["320:321:322"]},"author_link":["86774","86775","86776"],"item_10_biblio_info_6":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2018-07-06","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"7","bibliographicPageEnd":"6366","bibliographicPageStart":"6362","bibliographicVolumeNumber":"8","bibliographic_titles":[{"bibliographic_title":"ACS Catalysis","bibliographic_titleLang":"en"}]}]},"item_10_description_4":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"Thiourea–I2 as Lewis base–Lewis acid cooperative catalysts are developed for the iodochlorination of alkenes with in situ-generated iodine monochloride (I–Cl). The Lewis base–Lewis acid cooperative system is sufficient to generate I–Cl from I2 with a chlorinating reagent at low temperature. Based on the solid-state structure of the active species, thiourea–I2 cooperatively captures I–Cl. By taking advantage of I–Cl generation and the control of I–Cl at low temperature, the thiourea–I2 cooperative system suppresses side reactions that arise from highly reactive free I–Cl.","subitem_description_language":"en","subitem_description_type":"Abstract"}]},"item_10_description_5":{"attribute_name":"内容記述","attribute_value_mlt":[{"subitem_description":"ファイル公開：2019-07-06","subitem_description_language":"ja","subitem_description_type":"Other"}]},"item_10_publisher_32":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"ACS Publications","subitem_publisher_language":"en"}]},"item_10_relation_11":{"attribute_name":"DOI","attribute_value_mlt":[{"subitem_relation_type":"isVersionOf","subitem_relation_type_id":{"subitem_relation_type_id_text":"https://doi.org/10.1021/acscatal.8b01565","subitem_relation_type_select":"DOI"}}]},"item_10_rights_12":{"attribute_name":"権利","attribute_value_mlt":[{"subitem_rights":"“This document is the Accepted Manuscript version of a Published Work that appeared in final form in [ACS Catalysis], copyright © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see [https://pubs.acs.org/articlesonrequest/AOR-cqTEiVpmavIM99AvrKhH].”","subitem_rights_language":"en"}]},"item_10_select_15":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_select_item":"author"}]},"item_10_source_id_62":{"attribute_name":"ISSN（Online）","attribute_value_mlt":[{"subitem_source_identifier":"2155-5435","subitem_source_identifier_type":"EISSN"}]},"item_1615787544753":{"attribute_name":"出版タイプ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_ab4af688f83e57aa","subitem_version_type":"AM"}]},"item_access_right":{"attribute_name":"アクセス権","attribute_value_mlt":[{"subitem_access_right":"open access","subitem_access_right_uri":"http://purl.org/coar/access_right/c_abf2"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Horibe, Takahiro","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"86774","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Tsuji, Yasutaka","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"86775","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Ishihara, Kazuaki","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"86776","nameIdentifierScheme":"WEKO"}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2019-07-06"}],"displaytype":"detail","filename":"Manuscript.pdf","filesize":[{"value":"1.3 MB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"Manuscript","objectType":"fulltext","url":"https://nagoya.repo.nii.ac.jp/record/26406/files/Manuscript.pdf"},"version_id":"de27df3d-a706-4058-8c4d-04c2a9c425be"}]},"item_keyword":{"attribute_name":"キーワード","attribute_value_mlt":[{"subitem_subject":"dihalogenation","subitem_subject_scheme":"Other"},{"subitem_subject":"halogen-bonding","subitem_subject_scheme":"Other"},{"subitem_subject":"iodine","subitem_subject_scheme":"Other"},{"subitem_subject":"iodochlorination","subitem_subject_scheme":"Other"},{"subitem_subject":"Lewis base−Lewis acid catalysis","subitem_subject_scheme":"Other"},{"subitem_subject":"thiourea","subitem_subject_scheme":"Other"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Thiourea–I2 as Lewis Base–Lewis Acid Cooperative Catalysts for Iodochlorination of Alkene with In Situ-Generated I–Cl","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Thiourea–I2 as Lewis Base–Lewis Acid Cooperative Catalysts for Iodochlorination of Alkene with In Situ-Generated I–Cl","subitem_title_language":"en"}]},"item_type_id":"10","owner":"1","path":["322"],"pubdate":{"attribute_name":"PubDate","attribute_value":"2018-10-10"},"publish_date":"2018-10-10","publish_status":"0","recid":"26406","relation_version_is_last":true,"title":["Thiourea–I2 as Lewis Base–Lewis Acid Cooperative Catalysts for Iodochlorination of Alkene with In Situ-Generated I–Cl"],"weko_creator_id":"1","weko_shared_id":-1},"updated":"2023-01-16T04:17:00.672615+00:00"}