@article{oai:nagoya.repo.nii.ac.jp:00026909, author = {Mahara, Yuji and Murata, Kazumasa and Ueda, Kakuya and Ohyama, Junya and Kato, Kazuo and Satsuma, Atsushi}, issue = {16}, journal = {ChemCatChem}, month = {Aug}, note = {The highly active species of Pd/Al2O3 catalysts for methane combustion was revealed by in situ time‐resolved dispersive X‐ray absorption fine structure (DXAFS) spectroscopy. By using CH4 as a reduction agent, PdO in Pd/Al2O3 is reduced in a 2‐step model involving Pd0 nucleation and growth of Pd0 domain in a PdO particle. Kinetic analysis of the 2‐step model reduction of PdO nanoparticles leads to a suggestion that partial formation of Pd^0 in a PdO particle accelerates methane combustion., ファイル公開:2019-08-21}, pages = {3384--3387}, title = {Time Resolved in situ DXAFS Revealing Highly Active Species of PdO Nanoparticle Catalyst for CH4 Oxidation}, volume = {10}, year = {2018} }