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Synthesis and Size-Dependent Properties of [12], [16], and [24]Carbon Nanobelts
http://hdl.handle.net/2237/00029166
http://hdl.handle.net/2237/000291660d6cd4eb-3d44-46c1-a22c-e0e2054022a4
名前 / ファイル | ライセンス | アクション |
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LargeBelt_revision (2.0 MB)
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Item type | 学術雑誌論文 / Journal Article(1) | |||||
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公開日 | 2018-12-27 | |||||
タイトル | ||||||
タイトル | Synthesis and Size-Dependent Properties of [12], [16], and [24]Carbon Nanobelts | |||||
言語 | en | |||||
著者 |
Povie, Guillaume
× Povie, Guillaume× Segawa, Yasutomo× Nishihara, Taishi× Miyauchi, Yuhei× Itami, Kenichiro |
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アクセス権 | ||||||
アクセス権 | open access | |||||
アクセス権URI | http://purl.org/coar/access_right/c_abf2 | |||||
権利 | ||||||
言語 | en | |||||
権利情報 | “This document is the Accepted Manuscript version of a Published Work that appeared in final form in [Journal of the American Chemical Society], copyright © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see [https://pubs.acs.org/articlesonrequest/AOR-theYbndIbpzz5WHtnBUi].” | |||||
抄録 | ||||||
内容記述 | The synthesis and X-ray crystal structure of the first member of the carbon nanobelt family is reported. [12]Carbon nanobelt ([12]CNB) was originally obtained from a nickel-mediated reductive coupling reaction of a dodecabrominated macrocyclic precursor, albeit only in 1% yield. The present article reports on the development of this synthetic strategy and its extension to the preparation of the [16] and [24]CNB analogues. In particular, our extensive investigations on the final belt-forming, nickel-mediated reaction led to the development of a new ligand system that provides [12]CNB in up to 7% yield, contributing to the commercialization of [12]CNB. The belt structures of [12], [16], and [24]CNB were characterized by NMR, UV–vis, and Raman spectroscopy as well as mass spectrometry and X-ray crystallography. The fluorescence of the CNBs in solution displayed a remarkable dependence on the ring size, ranging from a broad red emission ([12]CNB) to a narrow-band blue emission ([24]CNB), while both features are observed for [16]CNB. | |||||
言語 | en | |||||
内容記述タイプ | Abstract | |||||
内容記述 | ||||||
内容記述 | ファイル公開:2019-08-08 | |||||
言語 | ja | |||||
内容記述タイプ | Other | |||||
出版者 | ||||||
言語 | en | |||||
出版者 | ACS Publications | |||||
言語 | ||||||
言語 | eng | |||||
資源タイプ | ||||||
資源タイプresource | http://purl.org/coar/resource_type/c_6501 | |||||
タイプ | journal article | |||||
出版タイプ | ||||||
出版タイプ | AM | |||||
出版タイプResource | http://purl.org/coar/version/c_ab4af688f83e57aa | |||||
DOI | ||||||
関連タイプ | isVersionOf | |||||
識別子タイプ | DOI | |||||
関連識別子 | https://doi.org/10.1021/jacs.8b06842 | |||||
ISSN(print) | ||||||
収録物識別子タイプ | PISSN | |||||
収録物識別子 | 0002-7863 | |||||
書誌情報 |
en : Journal of the American Chemical Society 巻 140, 号 31, p. 10054-10059, 発行日 2018-08-08 |
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著者版フラグ | ||||||
値 | author |