{"created":"2021-03-01T06:34:55.792403+00:00","id":26963,"links":{},"metadata":{"_buckets":{"deposit":"24488260-7905-4d6b-a478-79b872e19a03"},"_deposit":{"id":"26963","owners":[],"pid":{"revision_id":0,"type":"depid","value":"26963"},"status":"published"},"_oai":{"id":"oai:nagoya.repo.nii.ac.jp:00026963","sets":["336:695:696"]},"author_link":["88339","88340","88341","88342","88343"],"item_10_biblio_info_6":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2018-08-08","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"31","bibliographicPageEnd":"10059","bibliographicPageStart":"10054","bibliographicVolumeNumber":"140","bibliographic_titles":[{"bibliographic_title":"Journal of the American Chemical Society","bibliographic_titleLang":"en"}]}]},"item_10_description_4":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"The synthesis and X-ray crystal structure of the first member of the carbon nanobelt family is reported. [12]Carbon nanobelt ([12]CNB) was originally obtained from a nickel-mediated reductive coupling reaction of a dodecabrominated macrocyclic precursor, albeit only in 1% yield. The present article reports on the development of this synthetic strategy and its extension to the preparation of the [16] and [24]CNB analogues. In particular, our extensive investigations on the final belt-forming, nickel-mediated reaction led to the development of a new ligand system that provides [12]CNB in up to 7% yield, contributing to the commercialization of [12]CNB. The belt structures of [12], [16], and [24]CNB were characterized by NMR, UV–vis, and Raman spectroscopy as well as mass spectrometry and X-ray crystallography. The fluorescence of the CNBs in solution displayed a remarkable dependence on the ring size, ranging from a broad red emission ([12]CNB) to a narrow-band blue emission ([24]CNB), while both features are observed for [16]CNB.","subitem_description_language":"en","subitem_description_type":"Abstract"}]},"item_10_description_5":{"attribute_name":"内容記述","attribute_value_mlt":[{"subitem_description":"ファイル公開：2019-08-08","subitem_description_language":"ja","subitem_description_type":"Other"}]},"item_10_publisher_32":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"ACS Publications","subitem_publisher_language":"en"}]},"item_10_relation_11":{"attribute_name":"DOI","attribute_value_mlt":[{"subitem_relation_type":"isVersionOf","subitem_relation_type_id":{"subitem_relation_type_id_text":"https://doi.org/10.1021/jacs.8b06842","subitem_relation_type_select":"DOI"}}]},"item_10_rights_12":{"attribute_name":"権利","attribute_value_mlt":[{"subitem_rights":"“This document is the Accepted Manuscript version of a Published Work that appeared in final form in [Journal of the American Chemical Society], copyright © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see [https://pubs.acs.org/articlesonrequest/AOR-theYbndIbpzz5WHtnBUi].”","subitem_rights_language":"en"}]},"item_10_select_15":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_select_item":"author"}]},"item_10_source_id_61":{"attribute_name":"ISSN（print）","attribute_value_mlt":[{"subitem_source_identifier":"0002-7863","subitem_source_identifier_type":"PISSN"}]},"item_1615787544753":{"attribute_name":"出版タイプ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_ab4af688f83e57aa","subitem_version_type":"AM"}]},"item_access_right":{"attribute_name":"アクセス権","attribute_value_mlt":[{"subitem_access_right":"open access","subitem_access_right_uri":"http://purl.org/coar/access_right/c_abf2"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Povie, Guillaume","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"88339","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Segawa, Yasutomo","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"88340","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Nishihara, Taishi","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"88341","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Miyauchi, Yuhei","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"88342","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Itami, Kenichiro","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"88343","nameIdentifierScheme":"WEKO"}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2019-08-08"}],"displaytype":"detail","filename":"LargeBelt_revision.pdf","filesize":[{"value":"2.0 MB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"LargeBelt_revision","objectType":"fulltext","url":"https://nagoya.repo.nii.ac.jp/record/26963/files/LargeBelt_revision.pdf"},"version_id":"262d22ef-a1b7-42b2-adfb-54f51953202e"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Synthesis and Size-Dependent Properties of [12], [16], and [24]Carbon Nanobelts","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Synthesis and Size-Dependent Properties of [12], [16], and [24]Carbon Nanobelts","subitem_title_language":"en"}]},"item_type_id":"10","owner":"1","path":["696"],"pubdate":{"attribute_name":"PubDate","attribute_value":"2018-12-27"},"publish_date":"2018-12-27","publish_status":"0","recid":"26963","relation_version_is_last":true,"title":["Synthesis and Size-Dependent Properties of [12], [16], and [24]Carbon Nanobelts"],"weko_creator_id":"1","weko_shared_id":-1},"updated":"2023-01-16T04:17:42.688995+00:00"}