{"created":"2021-03-01T06:35:08.342478+00:00","id":27165,"links":{},"metadata":{"_buckets":{"deposit":"f3a6c416-ff0c-4314-b6cf-67a607a8307f"},"_deposit":{"id":"27165","owners":[],"pid":{"revision_id":0,"type":"depid","value":"27165"},"status":"published"},"_oai":{"id":"oai:nagoya.repo.nii.ac.jp:00027165","sets":["320:321:322"]},"author_link":["89033","89034","89035","89036","89037","89038","89039"],"item_10_biblio_info_6":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2018-12","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"23","bibliographicPageEnd":"4590","bibliographicPageStart":"4577","bibliographicVolumeNumber":"50","bibliographic_titles":[{"bibliographic_title":"Synthesis","bibliographic_titleLang":"en"}]}]},"item_10_description_4":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"Chiral BINOL-derived pyrophosphoric acid catalysts were developed and used for the regio- and enantioselective aza-Friedel–Crafts reaction of phenols with aldimines. ortho/para-Directing phenols could react at the para-position selectively with moderate to good enantioselectivities. Moreover, the gram-scale transformation of a product into the key intermediate for the antifungal agent (R)-bifonazole was demonstrated.","subitem_description_language":"en","subitem_description_type":"Abstract"}]},"item_10_description_5":{"attribute_name":"内容記述","attribute_value_mlt":[{"subitem_description":"ファイル公開：2019/12/01","subitem_description_language":"ja","subitem_description_type":"Other"}]},"item_10_publisher_32":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"Georg Thieme Verlag","subitem_publisher_language":"en"}]},"item_10_relation_11":{"attribute_name":"DOI","attribute_value_mlt":[{"subitem_relation_type":"isVersionOf","subitem_relation_type_id":{"subitem_relation_type_id_text":"https://doi.org/10.1055/s-0037-1610250","subitem_relation_type_select":"DOI"}}]},"item_10_select_15":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_select_item":"author"}]},"item_10_source_id_61":{"attribute_name":"ISSN（print）","attribute_value_mlt":[{"subitem_source_identifier":"0039-7881","subitem_source_identifier_type":"PISSN"}]},"item_1615787544753":{"attribute_name":"出版タイプ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_ab4af688f83e57aa","subitem_version_type":"AM"}]},"item_access_right":{"attribute_name":"アクセス権","attribute_value_mlt":[{"subitem_access_right":"open access","subitem_access_right_uri":"http://purl.org/coar/access_right/c_abf2"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Okamoto, Haruka","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"89033","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Toh, Kohei","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"89034","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Mochizuki, Takuya","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"89035","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Nakatsuji, Hidefumi","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"89036","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Sakakura, Akira","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"89037","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Hatano, Manabu","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"89038","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Ishihara, Kazuaki","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"89039","nameIdentifierScheme":"WEKO"}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2019-12-01"}],"displaytype":"detail","filename":"Revision.pdf","filesize":[{"value":"7.4 MB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"Revision","objectType":"fulltext","url":"https://nagoya.repo.nii.ac.jp/record/27165/files/Revision.pdf"},"version_id":"2f01d6d4-5942-4542-8e2e-91bcd21c10b4"}]},"item_keyword":{"attribute_name":"キーワード","attribute_value_mlt":[{"subitem_subject":"Brønsted acid","subitem_subject_scheme":"Other"},{"subitem_subject":"phosphoric acid","subitem_subject_scheme":"Other"},{"subitem_subject":"pyrophosphoric acid","subitem_subject_scheme":"Other"},{"subitem_subject":"organocatalyst","subitem_subject_scheme":"Other"},{"subitem_subject":"aza-Friedel–Crafts reaction","subitem_subject_scheme":"Other"},{"subitem_subject":"phenol","subitem_subject_scheme":"Other"},{"subitem_subject":"regio-selectivity","subitem_subject_scheme":"Other"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Chiral Pyrophosphoric Acid Catalysts for the para-Selective and Enantioselective Aza-Friedel–Crafts Reaction of Phenols","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Chiral Pyrophosphoric Acid Catalysts for the para-Selective and Enantioselective Aza-Friedel–Crafts Reaction of Phenols","subitem_title_language":"en"}]},"item_type_id":"10","owner":"1","path":["322"],"pubdate":{"attribute_name":"PubDate","attribute_value":"2019-03-05"},"publish_date":"2019-03-05","publish_status":"0","recid":"27165","relation_version_is_last":true,"title":["Chiral Pyrophosphoric Acid Catalysts for the para-Selective and Enantioselective Aza-Friedel–Crafts Reaction of Phenols"],"weko_creator_id":"1","weko_shared_id":-1},"updated":"2023-01-16T04:18:24.029730+00:00"}